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What Is Superfund?
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May 10, 2008
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Aerial Images Of Picher
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Of The Five Supercells
May 10, 2008
Tornado Path Graphics

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May 10, 2008
Tornado Path Graphics

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May 10, 2008
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Aerial Images Of Picher
After Tornado

Check Out The Images
Of The Five Supercells
May 10, 2008
Tornado Path Graphics

Tornado Deadly Path
National Weather Service

In Memory Of
Red Cross
On-Line Donation

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& Formal Statements

Welcome To The
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Tornado Victim Information
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Dedicated To Picher

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Aerial Images Of Picher
After Tornado

Check Out The Images
Of The Five Supercells
May 10, 2008
Tornado Path Graphics

Tornado Deadly Path
National Weather Service

In Memory Of
Red Cross
On-Line Donation

Thanks!
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& Formal Statements

Welcome To The
Picher-Twister

Thought For Today
Tornado Victim Information
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Dedicated To Picher

Picher-Twister
Video Collection

Aerial Images Of Picher
After Tornado

Check Out The Images
Of The Five Supercells
May 10, 2008
Tornado Path Graphics

Tornado Deadly Path
National Weather Service

In Memory Of
Red Cross
On-Line Donation

Thanks!
Government Comments
& Formal Statements

Welcome To The
Picher-Twister

Thought For Today
Tornado Victim Information
Poems, Ballads, & Songs
Dedicated To Picher

Picher-Twister
Video Collection

Aerial Images Of Picher
After Tornado

Check Out The Images
Of The Five Supercells
May 10, 2008
Tornado Path Graphics

Tornado Deadly Path
National Weather Service

In Memory Of
Red Cross
On-Line Donation

Thanks!
Government Comments
& Formal Statements

Welcome To The
Picher-Twister

Thought For Today
Tornado Victim Information
Poems, Ballads, & Songs
Dedicated To Picher

Picher-Twister
Video Collection

Aerial Images Of Picher
After Tornado

Check Out The Images
Of The Five Supercells






NOTICE:
The following copy is as it was retrieved, I have added some graphics and breaks to make the copy more reader friendly
Thanks & Enjoy Some History & Behind The Door Information
Terry G. Hembree

Picher Quick-Links Picher Weather Right Now!
Please Consider To Make A Donation To The Red Cross On-Line
Your Official Picher-Twister Website
Picher Tornado Information Picher-Twister Immediate Debre Cleanup & Search
Tornado & Thunderstorm Information & Safety
Picher-Twister Funnel Shots Picher-Twister Just After (1-10)
Picher-Twister Tornado Photo Gallery (1-10) Picher-Twister Photos (1-7)
Picher-Twister Aerial Images (1-3) Picher-Twister Photos (1-3)
Tar Creek OU4 Superfund Site Record Of Decision Documents
Picher Buy Out Picher Superfund Site
Tar Creek Documents Picher Mining Field Picher-Twister
Tar Creek Documents: Letters, Picher Mining Field Evaluations, Mine Glossary
Picher Demographics The Creek Runs Red Documentary Lead Facts


Picher Documents, News, Articles & Press Releases By Year

2008 2007 2006 2005 2004 2003
2002 2001 2000 1982 1967


Picher's Own Joe Don Rooney of Rascal Flatts
Picher Editorial Cartoons Picher-Twister Videos


Books For Sale On Picher By Lynda Ramsey Martinez and Mary Ramsey Koutz

Town Meetings Volume 1
"Picher Schools"
"50 Years Of Memories"
"Hard Rock Legacy"
CD's Are Also Available
Mining Memories by Mark Kershner, "The Pain of Picher" Lyrics by Sara McCormic
Buck Rambo "Through It All"

"Tar Creek Voluntary Relocation Initiative"

As children from Picher and Cardin watch, Gov. Henry signs his Tar Creek voluntary relocation initiative into law


"Lead Exposure Problems In Picher?"

Gov. Henry discusses lead exposure problems in the towns of Picher and Cardin during a recent tour of the Tar Creek Superfund Site.


Echoes of Love Canal in Tar Creek Relocation

Everyone's Backyard v.22, n.2, Summer 2004 1jul04

Who would imagine that the New York Yankees and the Tar Creek Superfund site in northeast Oklahoma would have something in common? They do. Mickey Mantle. The childhood home of Mickey

Mantle, considered one of the most popular and feared sluggers to ever play baseball for the Yankees is located in Commerce, OK, which is part of the 40-square mile Superfund site that is heavily contaminated with lead, cadmium and other toxic metals.

Mantle was born in Spavinaw, Oklahoma but moved to Commerce at the age of three. His father was a lead miner and Mickey worked in the mines as well during the summers. Some credit his unusual strength to working in the mines as a "screen ape." This involved smashing large rocks into small stones with a sledgehammer. Today Mantle's childhood home and the barn where he honed many of his baseball skills are being renovated as a tourist attraction.

At the same time, many people in Commerce and other towns that are part of the 40-square mile Superfund site are anxious to leave. Some families will have this option beginning September 1st when $5 million approved by the Oklahoma state legislature to purchase homes is made available to families with children six years old or younger who live in the towns of Picher and Cardin located at the center of the Tar Creek Superfund site. The option to relocate using these funds is voluntary.

"It's time," Regena Carder, who lives in Picher with her 3 year-old granddaughter and plans to apply for the relocation funds, told reporters. "I'm just glad they're doing something," she added. For residents who have been given the option to leave, there are mixed feelings says Rebecca Jim, Executive Director of the local community group, Local Environmental Action Demanded (LEAD). Jim told CHEJ that "Some will take it and go, some may take it but continue to let their children attend the local school, some will come back in the evenings and weekends to see their children's grandparents, friends, etc."

Children under the age of six were targeted because they are especially vulnerable to the effects of exposure to lead and because there's strong scientific evidence linking chronic lead exposure to adverse health problems in children including permanent neurological damage and learning disabilities. Not surprisingly, there's a high incidence of learning disabilities among students in the Picher-Cardin school district.

Tar Creek was once the location of extensive lead and zinc mining operations that has left more than 50 million tons of mine tailings in hundreds of piles and ponds over a 40-square mile area. Some of these piles are hundreds of feet tall (see photos) while others are as wide as several football fields. There are sinkholes and abandoned mineshafts everywhere. These mountains of lead and zinc waste completely surround the towns of Picher and Cardin located at the center of the site. The nearby towns of Commerce and Quapaw are also affected as are portions of the Quapaw tribal reservation. The Quapaw tribe owns most of the land which has been leased to people who have built homes on the site.

Dust contaminated with lead, cadmium and other toxic metals blow off these huge storage piles onto streets, homes and school yards throughout these communities. Not realizing that there was any danger, residents used this dust, known locally as "chat," to make driveways, foundations for their homes, or as fill for home improvement projects. Children innocently played on these piles often riding their bikes up and down them.

According to the USEPA, approximately 25 percent of the children living on the site have elevated blood lead levels, compared to a state average of 2 percent; approximately 1,600 residential homes have been identified with unsafe soil lead levels (having more than 500 ppm lead in soil); and five public water supply wells have been impacted. An estimated 28 billion gallons of acid mine water is draining from the mines, contaminating groundwater and spreading contamination across a vast watershed. Portions of the site are so severely scarred and disrupted by past mining activities that it looks like a lunar landscape. All this despite the fact that the EPA has already spent $107 million on cleanup.

The relocation bill makes no provision for residents with older children whose health is similarly endangered. This decision is eerily reminiscent of the progressive stages in which the Love Canal community in Niagara Falls, New York was evacuated 25 years ago. First, those living immediately adjacent to the now-infamous dumpsite were relocated, followed by families with pregnant women and children under the age of two who lived on historically wet areas and swales that crossed the landfill, then it was those who got sick during the cleanup, and finally, all 900 families in the neighborhood were able to leave. The contaminants at Tar Creek are different from those at Love Canal, but the effect is the same — a whole community suffering from exposure to toxic chemicals.

After each evacuation at Love Canal, the state would tell the residents who remained that their risks were "low," no different than living anywhere else in Niagara Falls. But the residents persisted in their efforts to win relocation for everyone who wanted to leave and continued to ignore the state's constant reassurances "that everything was all right."

Similarly, the EPA has said that the health risk to the general public living on the Tar Creek site is "low." What does this mean to the children who are now 8, 10 or 12 who lived in Tar Creek when they were six and younger? What does it mean to adults who have lived there all their lives and who now suffer from neurological problems linked to lead exposure?

What does it mean to Quapaw tribal members who live on the site? Did the EPA's "risk assessment" take into account the cultural traditions of Native American people who are likely to gather herbs for medicinal use, consume more fish, and gather berries along Tar Creek?

Rebecca Jim told CHEJ that "we know that it's more than just the children and its more than just the families in the epicenter [of the site]." There are, says Jim, "... four other whole towns, the Quapaw tribal headquarters where tribal members have danced for 130 years, with two rivers that have fish advisories for metals that form Grand Lake which is a water source for another three counties of people." The Mayor of Picher agrees, "There are massive problems in this area and it's not just Picher and Cardin."

The LEAD group has done its own health study of the community using a grant from EPA. They found many health problems in adults including diabetes, kidney disease, Parkinson's disease, cancer and heart disease

How can the government turn its back on so many people who live on what the EPA describes as the "worst toxic waste site in the nation," an area described in the federal Tar Creek Restoration Act as a site that "...can never be made safe for human habitation?"

It took time at Love Canal and continued pressure from the community before the state and federal governments finally agreed to relocate the entire community. Rebecca Jim met with Lois Gibbs, CHEJ's Executive Director and the community leader at Love Canal, to learn from her experiences. They now know what they have to do — ignore the government's hollow reassurances and keep the pressure on.

Says Jim, "We'll continue to demand relocation for those who want to go and for clean up for those who want to stay. We need to find ways to make the area habitable for those who want to stay." Hopefully, in time, the people who live on the Tar Creek Superfund site will succeed in getting the state and federal governments to agree to relocate those in the entire affected community who want to leave, not just those who are most vulnerable.

Everyone's Backyard is a publication of the Center for Health, Environment and Justice

Click On The Tar Creek Superfund Juggler'To Go Back To The Top Of These Documents

Superfund Site ?????

Superfund is a fancy name thought up from some pencil pusher as he sat in his leather chair, behind his desk, and never seeing what he was trying to describe in name

Superfund is what the Federal Government calls the program they've initiated to clean up the nation's uncontrolled hazardous waste sites.

The handpuppets of our government say they are committed to insuring that they're National Priorities List of hazardous waste sites are cleaned up to protect the environment and the health of all Americans.

You ask... Picher was placed on that priority list many years ago, in fact listed as the nation's Number One Hazardous Waste Sites

Picher is still here, the chat piles are still here, the tainted waters and land remain unchanged since the formal recognition came to this once booming Mining Town located just outside of Miami, Oklahoma

In fact this little town that grew into the nation's largest mining area was responsible for suppling the bullets with they're mining efforts for both World War I and World War II...

The country that for years have turned they're heads on

In this site, I will attempt to provide topical information for the general public and for those involved in the Superfund program.

I will share with you information about our own Tar Creek Superfund Site

The health effects of Picher's rich heritage that left these sacred Indian grounds to many contaminants that yes... Remain today

Today you can drive to Picher, Oklahoma and see the damage left to the environment from the mining days and you can also see absolutely Nothing has been done to change the situation in Picher

Browse through the following documents and see the Millions Of Dollars wasted By All 3 Governments, local, state and federal.

You will see the most ridiculous attempts to pull the wool over the eyes of these residents of Picher and the way the governments have attempted to insult they're intellegence.

So, what's next you ask

Take a drive to Picher and see with your own 2 eyes, the most that has been done to Picher in years is the devistation of the May 10, 2008 tornado

Oh, I'm sure the government will take that credit as a coverup from what they have Not Done, yet spent millions of your tax dollars to achieve

I promise you that you will have a horrible gut feeling for the fine folks that have lived here, that's lived here for years with nothing but promises

Promises... That's what Picher has gotten for all the heritage this sleepy little town has contributed to in this great land we live in called the United States of America.

Thanks for your time, but most importantly say a prayer for the people of Picher, please consider to write or call your area Senators, Representatives, Attorney General Drew Edmondson and Governor Brad Henry!

Click On The Tar Creek Superfund Juggler'To Go Back To The Top Of These Documents

Just What Is This Superfund Site & What Does It Mean?

Picher, Oklahoma Superfund Site

Congress Made Public Aware Of Contamination & Established The Superfund Program In 1980 to locate, investigate, and clean up the worst sites nationwide.

Superfund is the name the federal government is calling it's program to clean up, or attempt to clean up the nation's uncontrolled hazardous waste sites.

The government states over and over again through print and vocal discussion, that they are committed to ensuring that remaining National Priorities List hazardous waste sites are cleaned up to protect the environment and the health of all Americans.

I have designed this website to try to explain to all of us... What's Going On, I will attempt to provide topical information for the general public and for those involved in the Superfund program.

I will try to be the referree or translater on this site, where you can find information about the Picher Superfund Site.

The health effects of common contaminants, cleanup efforts, and how you can become involved in cleanup activities in and around your home here in Picher.

Click On The Tar Creek Superfund Juggler'To Go Back To The Top Of These Documents

Basic Information

What is Superfund?

Superfund is the name the government has given to the environmental program established to address abandoned hazardous waste sites.

It is also the name of the fund established by the Comprehensive Environmental Response, Compensation and Liability Act of 1980, as amended (CERCLA statute, CERCLA overview). This law was enacted in the wake of the discovery of toxic waste dumps such as Love Canal and Times Beach in the 1970s.

It allows the EPA to clean up such sites and to compel responsible parties to perform cleanups or reimburse the government for EPA-lead cleanups.

How Superfund Works

The Superfund cleanup process is complex. It involves the steps taken to assess sites, place them on the National Priorities List, and establish and implement appropriate cleanup plans. This is the long-term cleanup process. In addition, the Agency has the authority

A) To conduct removal actions where immediate action needs to be taken;

Removal Actions at Long-Term Cleanup Sites

Prior to EPA's regulation of hazardous wastes, much of our country's hazardous wastes were often stored or disposed of improperly -- either in landfills not designed to protect the environment or simply abandoned in open fields or dumped along roadways. In addition, abandoned industrial facilities that used chemicals and other hazardous substances may not have stored or disposed of them properly prior to closing operations. Today, these sites are undergoing long-term cleanup actions which may take several years to fully study the problem, develop the right remedy, and clean up the hazardous waste. These are the sites most people think of when they hear about the Superfund program. As of August 1996, there were over 1200 of these Superfund sites on the National Priorities List and undergoing some form of long- term cleanup.

EPA does not ignore the possibility that serious immediate threats to the environment or to the people who live or work around these sites may need to be taken care of before the long-term action is complete, or even underway. If there are any immediate threats present at these sites, EPA may respond quickly to perform a removal action. EPA removal actions address a wide range of threats, including emergencies, where EPA arrives on-scene within hours, as well as time-critical situations, where a response is needed within 6 months.

A long-term clean-up site may ultimately have several removal actions, or it may have none. In some cases, removal actions eliminate the need for a long-term cleanup at certain portions of the site. As a result, removal actions may speed the cleanup of portions of the site and may lead to early elimination of the site from EPA's long-term clean-up program.

B) To enforce against potentially responsible parties;Superfund Enforcement

The Superfund Enforcement program gets Superfund sites cleaned up by finding the companies or people responsible for contamination at a site, and negotiating with them to do the clean up themselves, or to pay for the clean up done by another party (i.e., EPA, state, or other responsible parties).

If a responsible party does not agree to do the cleanup, EPA can issue an order to do certain work, or work with the Department of Justice to pursue the party through the federal court system.

If a party is out of compliance with an order or settlement, the Superfund enforcement program takes action to bring them into compliance.

Such action may include: referring the case to the Department of Justice for enforcement, assessing penalties, and/or taking over the work.

C) To ensure community involvement; Community Involvement

Community involvement is the process of engaging in dialogue and collaboration with community members.

The goal of Superfund community involvement is to advocate and strengthen early and meaningful community participation during Superfund cleanups. Superfund community involvement staff will strive to:

Keep the community well informed of ongoing and planned activities.

Encourage and enable community members to get involved.

Listen carefully to what the community is saying.

Take the time needed to deal with community concerns.

Change planned actions where community comments or concerns have merit.

Explain to the community what EPA has done and why.

Programs and Resources

Technical Assistance Grants (TAGs)

Provides money for activities that help your community participate in decision making at eligible Superfund sites.

Community Advisory Group (CAG)

Provides a public forum for community members to present and discuss their needs and concerns related to the Superfund decision-making process.

Superfund Job Training Initiative (SuperJTI)

Supports job training programs in communities affected by nearby Superfund sites and encourages the employment of trainees at local site cleanups.

Technical Assistance Services for Communities (TASC)

EPA awarded a contract in July 2007 to provide independent technical assistance to communities living near hazardous waste sites.

Superfund Redevelopment Program

Helps communities return some of the nation's worst hazardous waste sites to safe and productive uses.

Guidance and Publications

Community Involvement Guidance and Publications

Community Involvement Activities Diagram

Graphic that shows opportunities for Community Involvement during the Superfund cleanup process

Community Involvement Toolkit

Comprehensive and practical tool for promoting successful community participation in the Superfund process.

Community 101: An Overview of the Superfund Program

Presentation outlining the Superfund program, Emergency Response, the Community Involvement Program and Environmental Justice Initiative.

Other Resources

EPA's Public Involvement

Details the full range of activities that EPA uses to engage the American people in the Agency's decision-making process.

EPA Conflict Prevention and Resolution Center

Provides resources for consensus building, conflict prevention, and alternative dispute resolution (ADR).

EPA Office of Environmental Justice

Coordinates the Agency's efforts to integrate the fair treatment and meaningful involvement of all people regardless of race, color, national origin, or income with respect to the development, implementation, and enforcement of environmental laws, regulations, and policies into all policies, programs, and activities.

International Association for Public Participation

Helps organizations and communities around the world improve their decisions by involving those people who are affected by those decisions

D) To involve states;

(Deleted other states not involved)

Oklahoma

Oklahoma Conservation Commission

Oklahoma Department of Environmental Quality

E) and ensure long-term protectiveness.

Post Construction Completion

The goal of Post Construction Completion activities is to ensure that Superfund response actions provide for the long-term protection of human health and the environment. EPA's Post Construction Completion activities also involve optimizing remedies to increase effectiveness and/or reduce cost without sacrificing long-term protection of human health and the environment.

"National Strategy to Manage Post Construction Completion Activities at Superfund Sites" (October 2005)

"Post Construction Completion Considerations in Superfund State Contracts" (August 2008)

Fact Sheets

"Superfund Post Construction Completion: An Overview" (June 2001)

"Superfund Post Construction Completion Activities" (June 2001)

Post Construction Completion Topics

Construction Completions (CC) - Information on Superfund sites where physical construction of all cleanup actions are complete, all immediate threats have been addressed, and all long-term threats are under control.

Long-Term Response Actions (LTRA) - Information on Superfund-financed cleanup activities intended to restore ground or surface water to a level that assures protection of human health and the environment (e.g., restoring a contaminated aquifer to drinking water quality).

Bayou Bonfouca Superfund site ground water pump and treatment station where construction has been completed.

Operation and Maintenance (O&M) - Information on how the Superfund program conducts the activities required to maintain the effectiveness and integrity of a remedy.

Institutional Controls (ICs) - Information related to various administrative and legal controls that help minimize the potential for human exposure to contamination by ensuring appropriate land or resource use.

Five-Year Reviews - Information on periodic reviews which are generally required by Superfund law or policy when a cleanup action does not allow for unrestricted use and unlimited exposure at the site.

Remedy Optimization - Information on efforts to optimize remedy performance and cost effectiveness at Superfund-financed ground water pump and treat (P&T) remedies.

National Priority List (NPL) Deletions - Information on how Superfund sites, or portions of sites, are deleted from the NPL once all response actions are complete and all cleanup goals have been achieved.

Site Reuse - Information on how the Superfund program is working with communities and other partners to return hazardous waste sites to safe and productive use without adversely affecting the remedy.

The blueprint for these activities is the National Oil and Hazardous Substances Pollution Consistency Plan (NCP), a regulation applicable to all federal agencies involved in responding to hazardous substance releases.

For over 20 years, the government has made public that they have located and analyzed tens of thousands of hazardous waste sites, protected people and the environment from contamination at the worst sites, and involved others in cleanup.

Who Implements Superfund

EPA's Office of Solid Waste and Emergency Response (OSWER) in Washington, D.C. oversees the Superfund program. The Office of Emergency Management within OSWER is responsible for short term responses conducted under the authority of Superfund.

The Office of Superfund Remediation and Technology Innovation, and the Federal Facilities Response and Reuse Office, also within OSWER, have the lead for managing the long-term Superfund response program, the latter for responses involving Federal Facilities.

In addition I understand OSWER manages the federal Brownfields program.

Regions

EPA's 10 Regional offices around the nation are responsible for implementing many of EPA's programs, including Superfund.

For Superfund, EPA regions are the front line in responding to releases of hazardous substances and other emergencies.

(Regions other than Oklahoma were deleted)

Years ago, people were less aware of how dumping chemical wastes might affect public health and the environment. On thousands of properties where such practices were intensive or continuous, the result was uncontrolled or abandoned hazardous waste sites, such as abandoned warehouses and landfills.

Citizen concern over the extent of this problem led Congress to establish the Superfund Program in 1980 to locate, investigate, and clean up the worst sites nationwide. The EPA administers the Superfund program in cooperation with individual states and tribal governments.

In this section we'll try to provide an overview of the Superfund program, highlights key steps in the Superfund cleanup process, guides users to enforcement information, lists EPA's Superfund offices and partnership organizations, and provides answers to frequently asked questions.

The EPA Superfund cleanup process begins with site discovery or notification to the EPA of possible releases of hazardous substances. Sites are discovered by various parties, including citizens, State agencies and by Region 6 staff.

Once discovered, the government enters the site into our computerized inventory of potential hazardous substance release sites. This system is named the Comprehensive Environmental Response, Compensation and Liability Information System, or CERCLIS for short. We then evaluate the potential risk for a release of hazardous substances from the site through several steps in the Superfund cleanup process:

Preliminary Assessment/Site Inspection: we investigate site conditions

Hazard Ranking System scoring: a screening mechanism we use to place sites on the National Priorities List (NPL)

NPL Site Listing Process: our list of the most serious sites which may need a long-term cleanup

Remedial Investigation/Feasibility Study: we determine the nature and extent of contamination

Record of Decision (ROD: we explain which cleanup alternatives will be used at NPL sites

Remedial Design/Remedial Action (RD/RA): we prepare and implement plans and specifications for applying site remedies

Construction Completion: we identify completion of cleanup activities

Post Construction Completion: we ensure that the Superfund response actions provide long-term protection of human health and the environment

Cost Recovery: we seek reimbursement for our costs from those responsible for the contamination.

NOTE: The most recent mining companies were contacted and were asked... WERE ASKED... If they would consider helping on the testing costs in determining the degree of contamination and the estimated cost to correct the issues... They did not wish to participate"

The government uses these steps to determine and implement the appropriate response to threats posed by releases of hazardous substances.

We address releases that require immediate or short-term response actions through the emergency response program of Superfund.We have made great strides in cleaning up sites across our five-state Region. But equally important is returning a site to productive use in the community.

The Brownfields Program, the Ready for Reuse Program and the Land Revitalization Initiative are mechanisms the EPA uses to empower states and local governments to return sites to productive use after the sites have been cleaned up.

Region 6--NM TX OK AR LA

Regional Superfund Contacts

Here you will find contact information for the various EPA Regions’ Superfund Programs. The Superfund Program was created to eliminate the health and environmental threats posed by hazardous waste sites.

The U.S. Environmental Protection Agency (EPA) administers the Superfund Program through the Office of Solid Waste and Emergency Response’s (OSWER) Office of Superfund Remediation Technology Innovation (OSRTI) in cooperation with individual states and tribal governments.

South Central: Region 6

Serving Serving Louisiana, Arkansas, Oklahoma, New Mexico, Texas and 65 Tribes

Region 6 Emergency & Hot Line Phone Numbers

Emergency & Hot Line Phone Numbers - National Response Center 1-800-424-8802

To report an environmental emergency

Superfund Hot Line 1-800-533-3508 - For Superfund information

Environmental Emergencies - 1-866-EPASPILL (1-866-372-7745)

Reporting Emergencies in Arkansas, Louisiana, New Mexico, Oklahoma and Texas

General Information Addresses & Phone Numbers From the Region 6 states call 1-800-887-6063

Region 6 Public Information Center

For General Information: 214-665-6444 - Region 6 Mailing Addresses

Region 6 Organization Charts - General Information - 214-665-6444

Regional Administrator's Office - 214-665-2100

External Affairs - 214-665-2200

Regional Counsel - 214-665-2110

Compliance Assurance & Enforcement - 214-665-2210

EPA People Locator Superfund - 214-665-6701

Multimedia Planning & Permitting - 214-665-7200

Water Quality Protection - 214-665-7101

Management - 214-665-6500

Houston Laboratory - 281-983-2100

Click On The Tar Creek Superfund Juggler'To Go Back To The Top Of These Documents

Regional Public Liaisons

Partnerships

EPA's Superfund Program attempts to get interested parties and other stakeholders involved as much as possible, as early as possible.

Superfund Partners

While management of the Superfund program lies mainly within the Office of Superfund Remediation and Technology Innovation (OSRTI) within EPA's Office of Solid Waste and Emergency Response (OSWER), many responsibilities fall within other programs and agencies.

Within EPA

Office of Emergency Management

This OSWER office is responsible for short term responses under Superfund, as well as emergency responses to and preparedness for releases of hazardous substances.

Office of Site Remediation and Enforcement (OSRE)

This office is responsible for the enforcement component of Superfund. It resides within EPA's Office of Enforcement and Compliance Assurance.

Federal Facilities Enforcement Office (FFEO)

This office is responsible for ensuring that federal facilities take all necessary actions to prevent, control and abate environmental pollution.

Federal Facilities Restoration and Reuse (FFRRO)

This office resides in OSWER and is the interface between EPA and federal agencies, such as the Department of Energy and Department of Defense, as they conduct cleanups of their own facilities.

Brownfields

This office resides in OSWER and is responsible for implementing the Brownfields program, established by an amendment to Superfund's authorizing legislation, CERCLA. This program promotes the evaluation and development of less contaminated properties.

Office of Research and Development (ORD)

This office conducts research on contaminants and technologies to aid in cleanup decisions.

Other Federal Government Agencies

Agency for Toxic Substances and Disease Registry (ATSDR)

ATSDR is responsible for conducting health assessments of Superfund sites. It also maintains toxicological profiles of many contaminants.

National Institute of Environmental Health Sciences

This agency conducts research on health effects of hazardous substances that aid in Superfund assessment and cleanup decisions.

US Army Corps of Engineers

This construction-oriented agency conducts much of the construction and oversight of Superfund cleanups for which EPA is responsible.

States & Tribes

States & Tribes have roles in addressing Superfund sites in their areas, at every stage of the Superfund cleanup pipeline.

Office of Regional Operations

This EPA Office's Web site has links to State and Tribal organization sites

EPA Regional Offices

Regional Web sites carry links to State programs and issues, as well as information on specific sites.

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Superfund Site Information

DISCLAIMER:

Be advised that the data contained in these profiles are intended solely for informational purposes use by employees of the U.S. Environmental Protection Agency for management of the Superfund program. They are not intended for use in calculating Cost Recovery Statutes of Limitations and cannot be relied upon to create any rights, substantive or procedural, enforceable by any party in litigation with the United States. EPA reserves the right to change these data at any time without public notice.

Superfund Site Information contains information on hazardous waste sites, potentially hazardous waste sites and remedial activities across the nation, including sites that are on the National Priorities List (NPL) or being considered for the NPL.

To assist in locating the desired site or information, a variety of search criteria are available such as site name, state, ZIP code, contaminants and activities performed at a site.

Also, site-specific documents and records such as Records of Decision (RODs), Five-Year Reviews and fact sheets for many sites can be accessed through Superfund Site Information.

A search of sites that have been archived from the inventory of active sites can be performed. At the top of the Search page, select the "Archived Sites" radio button.

Site information for NPL sites (i.e., sites proposed to the NPL, currently on the final NPL or deleted from the final NPL) is displayed in a standardized site progress profile format.

The profile includes information such as the current status of cleanup efforts, what cleanup milestones have been reached and how much liquid and solid-based media have been treated. Additionally, the profile includes links to information found on EPA Regional Web sites.

All information is presented in easy to understand, non-technical language. Only NPL sites are displayed in the site progress profile format, non-NPL and archived sites are displayed in a less graphical format.

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NPL Site Narrative for Tar Creek (Ottawa County)

TAR CREEK (OTTAWA COUNTY)

Ottawa County, Oklahoma

Federal Register Notice: September 8, 1983

Conditions at listing (October 1981): The Tar Creek Site, near Picher, in Ottawa County, Oklahoma, covers 40 square miles. It is a portion of the Tri-State Mining District, which covers 100 square miles and extends into Missouri and Kansas. The area produced significant quantities of iron and zinc in the 1920s and 1930s.

When major mining operations ceased in the early 1970s, ground water accumulated in the mines. In 1979, acid mine water with high concentrations of heavy metals began to discharge to the surface, contaminating surface water. This problem, along with the potential for contaminating the drinking water aquifer under the mining area, prompted the U.S. Geological Survey and the State to investigate the site. In 1981, the State declared the site its number one pollution problem.

Status (July 1983): In June 1982,

EPA awarded a $435,368 Cooperative Agreement to Oklahoma for a remedial investigation to determine the type and extent of contamination at the site and a feasibility study to identify alternatives for remedial action. The work is scheduled to be completed in the fourth quarter of 1983.

For more information about the hazardous substances identified in this narrative summary, including general information regarding the effects of exposure to these substances on human health, please see the Agency for Toxic Substances and Disease Registry (ATSDR) ToxFAQs. ATSDR ToxFAQs can be found on the Internet at http://www.atsdr.cdc.gov/toxfaq.html or by telephone at 1-888-42-ATSDR or 1-888-422-8737.

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The Quapaw Tribe of Oklahoma and The Tar Creek Project

Project Description:

The Quapaw Indian Tribe of Oklahoma was originally located near the mouth of the Ohio River where they were part of a larger group known as the Dhegiha Sioux.

As a member of this group, they belonged to the same Siouan linguistic family as the Ponca, Osage, Omaha and Kansas tribes. In the early 1600s, the Quapaw began to move downstream to the Mississippi River and settle in what is now known as Arkansas. This move earned them the tribal name of Ugakhpa, which means "downstream people."

During the mid-1600s, the French explorers Robert De La Salle and Henri De Tonti encountered the Quapaw and began referring to them as Akansea or "Bow people of the south wind." The area in which the Akansea were located eventually became the State of Arkansas. Beginning in 1818, the United States government began obtaining land from the Quapaws until 1833 when, "the tribe was removed from Arkansas for the last time."

The 1833 move put them into Indian Territory in what is now known as Oklahoma. In 1867, they were yet again forced to sign over a large portion of their lands. "Today, the Quapaw retain only a small parcel of historic trust lands of less than 13,000 acres."

In 1919, lead and zinc deposits were found on tribal lands. This discovery brought a fifty year period of intense mining activity, which included the Tar Creek area, with the last mines closing in the 1970s. The mining activity took place in what has been designated as the Tri-State Mining area, which encompasses portions of Oklahoma, Kansas and Missouri.

Some of the mining operations were conducted at depths of 90 to 320 feet below ground surface in the Boone Aquifer. It should be emphasized that the Tar Creek site has become not only a state and federal issue, but also tribal. "The Quapaw Nation and a group of seven other small tribes in Ottawa County own 80 percent of the land that makes up the Tar Creek Superfund site."

Environmental problems began showing up in 1979 with the advent of acid mine drainage from the underground mines flowing into Tar Creek through abandoned mine shafts and bore-holes. Along with the acid drainage from the mines, lead-contaminated soil had become a major source of surface contamination. This contaminated soil was then deposited into "chat" piles, which constituted approximately 165 million tons of tailings, over 1,320 mine shafts and thousands of drill holes.

With these considerations in mind, the Quapaw Nation has been in the forefront of a cooperative effort to resolve these problems.

In 1980, the Governor of Oklahoma established the Tar Creek Task Force to investigate acid mine drainage into Tar Creek. In 1983, the Tar Creek Site was listed on the National Priorities List (NPL). This list is used to guide the Environmental Protection Agency (EPA) "in determining which sites warrant further investigation" as to releases of hazardous substances, pollutants or contaminants.

Remediation efforts by the EPA had begun addressing the acid mine drainage problem and the lead-contaminated residential yards; however, the Quapaw Tribe felt that one other area needed to be addressed, that of air quality. Leon Crow, Air Quality Manager, Quapaw Tribal Air Program, emphasized in a Tribal Case Study, that "Air quality is of primary concern to a majority of Tar Creek residents and tribal members." The tribe requested air monitoring equipment be placed within designated areas.

After discussions with EPA's Office of Air and Radiation (OAR), it was determined that monitoring for fine particulate matter PM2.5 and PM10 and lead was warranted. The tribe also requested that silica monitoring be included (this last was deemed necessary due to complaints from local residents).

Four air monitoring sites were selected: The Thomas Buffalo Allotment; the Whitebird Allotment; the Hum-bah-wat-tah Allotment and the Anna Beaver Allotment (which was also the quality assurance and quality control site). The tribal staff received training in several TAMS Center-sponsored courses (316KB PDF), which included: Quality Assurance; PM monitoring; TEOM Ambient Particulate Continuous Monitoring and Air Quality Systems (EPA database).

The tribe also participated in EPA's National Performance Audit Program (one site every quarter); an Independent Audit Program (one site every quarter) and a Self Audit Program, conducted on every sampler on a biweekly basis. In addition to the formal course training at the TAMS Learning Center, located in Las Vegas, Nevada, at EPA's Radiation and Indoor Environments National Laboratory (R&IE), two on-site training sessions were conducted in 2 March 2003 and January 2004 by Joe Hameed, Technical Specialist II, with the TAMS Center.

The training concentrated on the operation, maintenance and calibration of the equipment; auditing procedures; Quality Assurance/Quality Control checks; Data Management and Verification and Troubleshooting Processes.

With the expertise and training provided by the TAMS Center, the Quapaw Tribe of Oklahoma, has formed the groundwork for reaching its ultimate goal of finding a comprehensive solution to the Tar Creek dilemma.

Contacts:

If you have any questions concerning the training and on-site visits conducted by the TAMS staff, please call Joe Hameed at (702) 784-8269 or e-mail to Joe.Hameed@nau.edu. For questions involving the Tar Creek Project and the Quapaw Tribe, please call Leon Crow at (918) 542-1853 or e-mail to LCrow@Quapawtribe.com.

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Cleanup plan finalized for Tar Creek Superfund site

Release date: 02/22/2008

Contact Information: Dave Bary or Tressa Tillman at 214-665-2200 or r6press@epa.gov

(Dallas, Texas – February 22, 2008) The Environmental Protection Agency, in cooperation with the State of Oklahoma Environmental Secretary, Oklahoma Department of Environmental Quality, and the Quapaw Tribe of Oklahoma, has completed the final cleanup plan for the Tar Creek Superfund site in Ottawa County, Oklahoma.

Components of the cleanup plan include:

1) funding for the voluntary relocation of residents and businesses located in Picher, Cardin and Hockerville through the State of Oklahoma’s Lead-Impacted Communities Relocation Assistance Trust,

2) chat sales, and

3) disposal of source materials in a manner that will reduce the overall footprint of contamination and reduce the need for land use restrictions, institutional controls, and operation and maintenance.

The cost of the plan is approximately $167 million

"This master plan will ensure a coordinated commitment to permanently clean up the Tar Creek Superfund site,” said EPA Regional Administrator Richard E. Greene. “It is a long-awaited step in finalizing work to clean up one of the nation's largest Superfund sites, and I am pleased to be part of this monumental occasion."

The final cleanup plan reaffirms years of hard work by local, tribal, state and federal partners to permanently clean up the site. It addresses contamination posed by chat piles, other mine and mill waste, and smelter waste in the 40-square mile former lead and zinc mining area.

EPA based its decision on public comments, extensive studies of the extent of contamination, and human health and environmental risks caused by the contamination at the site. More details on the plan are described in the record of decision, which is available at http://www.epa.gov/earth1r6/6sf/6sf-decisiondocs.htm.

EPA has spent nearly $150 million addressing immediate threats to the residents near and around the site by removing lead and zinc waste, known as chat, from residential yards and from high access areas. After yard remediation and extensive health education efforts funded by EPA, a 50 percent reduction in the number of children with elevated blood lead levels has been achieved in local communities.

EPA listed the Tar Creek site on its National Priorities List in 1983. The site is located in northeastern Oklahoma and is part of the 1,188 square mile historic zinc and lead mines known as the Tri-State Mining District in Missouri, Kansas, and Oklahoma. Mining began in the early 1900s and continued until the 1960s.

Much of the land on the Tar Creek site is allotted Indian Land. The towns of Picher, Cardin, Commerce, North Miami and Quapaw are also part of the site. Approximately 19,000 people live in the communities surrounding the site.

Additional information on the Tar Creek site and the record of decision is available at http://www.epa.gov/earth1r6/6sf/6sf-decisiondocs.htm.

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EPA provides additional funding for Tar Creek voluntary buyout

Release date: 09/02/2008

Contact Information: Dave Bary or Tressa Tillman at 214-665-2200 or r6press@epa.gov

ODEQ to receive $9.55 million to continue buyout and relocation efforts

(Dallas, Texas – September 2, 2008) The Environmental Protection Agency is providing an additional $9.55 million in federal funding to the Oklahoma Department of Environment Quality (ODEQ) to assist with the buyout and relocation of residents of Cardin, Hockerville, and Picher, Oklahoma.

Previously, the agency provided $5 million in funds following a May 10 tornado that struck the former mining town of Picher, which is located in the center of the Tar Creek Superfund site.

“EPA has worked with federal, state and tribal partners at an unprecedented level of cooperation for more than two decades to clean up the Tar Creek site,” said EPA Regional Administrator Richard E. Greene. “We will continue to work with our many other partners to respond to the challenges at Tar Creek and protect the communities impacted by the site.”

The additional funding will be used to continue buying out residents and demolishing or relocating homes, businesses, and public use structures located in the disaster area.

EPA listed the Tar Creek Superfund site on its National Priorities List in 1983. The site is located in northeast Oklahoma and is part of the 1,188 square mile historic lead and zinc mines known as the Tri-State Mining District in Missouri, Kansas and Oklahoma.

Additional information on the Tar Creek site is located at http://www.epa.gov/region6/6sf/6sf-ok.htm

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Tar Creek Agreement Reached

Release date: 12/9/2003

Contact Information: For more information contact the Office of External Affairs at (214) 665-2200.

Today a new multi-million dollar agreement was reached between the U.S. Environmental Protection Agency (EPA), the Department of Interior and two mining companies to coordinate the process of cleaning up the large chat piles and mill pond mining waste at the Tar Creek Superfund site in Oklahoma.

Today's agreement is a long-awaited step forward in drawing the blueprint for cleanup at one of the nation's largest Superfund sites. The agreement, a legally binding Administrative Order on Consent, complements the recently announced compact among the federal partners to speed up efforts to clean up the site and a large scale plan put forward by U.S. Senator James Inhofe, the state of Oklahoma and tribal leaders.

"This agreement marks unprecedented cooperation between federal, state, tribal and local interests to respond to the challenges at Tar Creek. I am confident that working together to build a comprehensive approach is the only way we can accomplish our mission of cleaning up this huge mess," EPA Regional Administrator Richard E. Greene said.

The agreement focuses on identifying and selecting potential cleanup methods to address large chat piles and mill ponds.

Blood lead levels in area children were reduced by half as a result of the EPA residential cleanup that began in 1995.

Contaminated soil from about 2,000 residential properties, three day care centers and 20 public access areas in five communities has been removed and replaced with clean soil.

The Tar Creek Superfund site includes approximately 40 square miles in northern Ottowa County, Oklahoma, where lead and zinc were mined from 1891 until 1970. More information about Tar Creek is available at http://www.epa.gov/earth1r6/6sf/pdffiles/tarcreek.pdf. A copy of the agreement and other supporting documents is available at www.epa.gov/region6/6xa/tar_creek_aoc.pdf and www.epa.gov/region6/6xa/tar_creek_atch.pdf.

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Tar Creek Superfund Site Remediation

Combined Roles for Biomass, Poultry Litter, Fly Ash and Flu Gas Desulfurization Residues

EPA Grant Number: SU831866
Title: Tar Creek Superfund Site Remediation: Combined Roles for Biomass, Poultry Litter, Fly Ash and Flu Gas Desulfurization Residues
Investigators: Potter, William , Roberts, Ken , Settle, Chad , Tapp, Bryan
Current Investigators: Potter, William , Grayson, Britney , Hitt, Kristi , Iski, Erin , Moskal, Mark , Roberts, Ken , Settle, Chad , Tapp, Bryan , Williamson, Kenny
Institution: University of Tulsa
EPA Project Officer: Nolt-Helms, Cynthia
Project Period: September 30, 2004 through May 30, 2005
Project Amount: $10,000
RFA: P3 Awards: A National Student Design Competition for Sustainability Focusing on People, Prosperity, and the Planet (2004)
Research Category: Pollution Prevention/Sustainable Development

Description:

The Tar Creek Superfund site in Northeastern Oklahoma is a large area contaminated from 100 years of lead and zinc mining. In this proposal we focus on developing surface coverage and remediation methods for the 45 million cubic yards of mine tailings, known as chat. The chat has elevated levels of mineral sulfides which, when oxidized, promote runoff conditions with elevated levels of lead, cadmium and zinc. Water runoff and airborne dust blown from the chat gives rise to a persistent, slow release of toxic metals into The Grand Lake of the Cherokee's Watershed and contribute to both health and economic problems in the predominantly American Indian population living near the area.

Our student design challenge promotes cost effective remediation methods to restore the productivity and value of the land. The design is based on using municipal biosolid sludge with agricultural and coal combustion products waste to immobilize toxic metals in situ and regenerate the soil profile. The design involves mixing municipal biosolids/sludge with the high lignin agricultural waste product litter obtained from poultry confined animal feeding operations (CAFOs). The use of litter in the Tar Creek site removes an eutrophication burden from the adjacent watershed containing Lakes Eucha and Spavinaw, lakes which are the City of Tulsa's drinking water lakes.

The shift in litter burden should help immobilize metals in the Tar Creek area while reducing algal blooms related to excessive phosphates in the adjacent City of Tulsa's drinking water lakes area. The biomass is to be adjusted and enhanced for in situ metal stabilization using coal combustion products (CCPs).

The CCPs are produced locally at Shady Creek Power Plant, an Oklahoma-coal (high sulfur content) facility. The combustion byproducts include fly ash and flue gas desulfurization (FGD) residues (i.e., gypsum compounds). The project is designed to be tested on pilot scale lysimeters under open field conditions with: 1) analyses of metals, nutrients and other pollutants in runoff; 2) the analyses of soil profiles; and 3) evaluation of overall vegetation viability. The project is a student group project from courses in Geosciences, Analytical Chemistry, Environmental Chemistry and Environmental Economics.

Pedagogically, the project is taught as if the student groups are local consulting firms and have to contract out with specific specialties to determine the best methods of remediation, site characterization, analytical techniques, and economic basis for different remediation procedures.

Supplemental Keywords:
Air, watersheds, groundwater, land, soil, sediments, leachate, chemical transport, exposure, risk, population, susceptibility, cumulative effects, toxics, particulates, ODS, heavy metals, sulfates, effluent, ecosystem, restoration, alternatives, sustainable development, innovative technology, remediation, cleanup, cost benefit, public good, environmental chemistry, geology, analytical, south central, Oklahoma (OK), , Scientific Discipline, Waste, Remediation, Environmental Engineering, Environmental Chemistry, biomass, fly ash, flue gas desulferization, Tar Creek Superfund Site, lead, remediation technologies, mining waste, Zinc
Progress and Final Reports:
Final Report

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EPA Proposes Criteria for Using Chat from Tar Creek Areas

Release date: 03/24/2006

Contact Information: Cindy Fanning, (214) 665-2142, fanning.cynthia@epa.gov or Dave Bary, (214) 665-2208, bary.david@epa.gov

(Dallas, Texas, March 24, 2006) – The U.S. Environmental Protection Agency is proposing criteria for the beneficial use of chat from the Tri-state mining district in transportation construction projects and in non-transportation, non-residential concrete and cement projects. EPA believes the proposed uses of chat are protective of human health and the environment.

The proposed criteria involve safely encapsulating chat particles in asphalt or cement and concrete. Beneficially using chat according to the proposed criteria will both reduce chat piles and improve human health and the environment in the Tri-state area.

Chat is a gravel-like waste created from lead and zinc mining activities in the Oklahoma, Kansas and Missouri Tri-state district between the late 1800s and mid 1900s. Currently about 100 million tons of chat contaminated with lead, zinc and cadmium are located in the Tri-state mining district.

The district covers approximately 2,500 square miles and includes parts of Ottawa County, Okla.; Cherokee County, Kan.; and Jasper and Newton Counties, Mo. The area includes four Superfund National Priority List sites: Cherokee County, Tar Creek (Ottawa County), Newton County Mine and the Oronogo-Duenweg Mining Belt.

EPA is proposing these criteria in response to the Safe, Accountable, Flexible, and Efficient Transportation Equity Act of 2005. More information is available on EPA’s web page at http://www.epa.gov/epaoswer/other/mining/chat/.

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Cleanup plan finalized for Tar Creek Superfund site

Release date: 02/22/2008

Contact Information: Dave Bary or Tressa Tillman at 214-665-2200 or r6press@epa.gov

(Dallas, Texas – February 22, 2008) The Environmental Protection Agency, in cooperation with the State of Oklahoma Environmental Secretary, Oklahoma Department of Environmental Quality, and the Quapaw Tribe of Oklahoma, has completed the final cleanup plan for the Tar Creek Superfund site in Ottawa County, Oklahoma.

Components of the cleanup plan include:

funding for the voluntary relocation of residents and businesses located in Picher, Cardin and Hockerville through the State of Oklahoma’s Lead-Impacted Communities Relocation Assistance Trust,

chat sales, and

disposal of source materials in a manner that will reduce the overall footprint of contamination and reduce the need for land use restrictions, institutional controls, and operation and maintenance.

The cost of the plan is approximately $167 million.

"This master plan will ensure a coordinated commitment to permanently clean up the Tar Creek Superfund site,” said EPA Regional Administrator Richard E. Greene. “It is a long-awaited step in finalizing work to clean up one of the nation's largest Superfund sites, and I am pleased to be part of this monumental occasion."

The final cleanup plan reaffirms years of hard work by local, tribal, state and federal partners to permanently clean up the site. It addresses contamination posed by chat piles, other mine and mill waste, and smelter waste in the 40-square mile former lead and zinc mining area.

EPA based its decision on public comments, extensive studies of the extent of contamination, and human health and environmental risks caused by the contamination at the site. More details on the plan are described in the record of decision, which is available at http://www.epa.gov/earth1r6/6sf/6sf-decisiondocs.htm.

EPA has spent nearly $150 million addressing immediate threats to the residents near and around the site by removing lead and zinc waste, known as chat, from residential yards and from high access areas. After yard remediation and extensive health education efforts funded by EPA, a 50 percent reduction in the number of children with elevated blood lead levels has been achieved in local communities.

EPA listed the Tar Creek site on its National Priorities List in 1983. The site is located in northeastern Oklahoma and is part of the 1,188 square mile historic zinc and lead mines known as the Tri-State Mining District in Missouri, Kansas, and Oklahoma. Mining began in the early 1900s and continued until the 1960s.

Much of the land on the Tar Creek site is allotted Indian Land. The towns of Picher, Cardin, Commerce, North Miami and Quapaw are also part of the site. Approximately 19,000 people live in the communities surrounding the site.

Additional information on the Tar Creek site and the record of decision is available at http://www.epa.gov/earth1r6/6sf/6sf-decisiondocs.htm.

To learn more about activities in EPA Region 6, go to http://www.epa.gov/region6.

EPA audio file is available at http://www.epa.gov/region6/6xa/audio.htm#audio022208_tarcreek

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EPA proposes plan for next phase of Tar Creek cleanup

Release date: 07/25/2007

Contact Information: Dave Bary or Tressa Tillman at 214-665-2200 or r6press@epa.gov

Remedy to address chat, soil and water contamination from Superfund site

(Dallas, Texas – July 25, 2007) The Environmental Protection Agency has developed a plan for the next phase of cleanup at the Tar Creek Superfund site.

The proposed plan presents EPA’s preferred cleanup method for addressing environmental hazards from past mining operations at the site and calls for consolidating chat for commercial sale, on-site disposal, removing contaminated soils, and providing alternative water sources for affected residents.

“EPA and our many partners are working diligently to clean up Tar Creek and protect the people who live in the communities impacted by the site,” said EPA Regional Administrator Richard E. Greene. “It is a complex task, and we remain committed to finding solutions that will result in a safer, healthier environment for residents.”

The proposed plan, titled “Tar Creek Operable Unit 4 (OU4) - Chat Piles, Other Mine and Mill Waste, and Smelter Waste,” addresses source materials, smelter waste, rural residential yard contamination, transition zone soil contamination, and contamination in water drawn from rural residential wells. Source materials refers to mine and mill waste including chat, fines, overburden, development rock, and other tailings. The plan also allows for the continued sale of chat under guidelines established by a new EPA Chat Rule (40 Code of Federal Regulations 278) finalized this month.

EPA incorporated input from the Oklahoma Department of Environmental Quality, the Quapaw Tribe of Oklahoma and ten downstream Tribes into the plan. A 30-day public comment period on the proposed plan will begin July 30, 2007, and conclude August 30, 2007. The public is encouraged to comment on the alternatives presented in the proposed plan or suggest other alternatives. Individuals can email comments to EPA community involvement coordinator Janetta Coats at coats.janetta@epa.gov. EPA will select a final remedy after considering all information submitted during the comment period and may modify the plan based on new information or public comments.

More on the proposed plan: http://www.epa.gov/earth1r6/6sf/6sf-decisiondocs.htm

More on the chat rule: http://www.epa.gov/epaoswer/other/mining/chat/

More on activities in EPA Region 6: http://www.epa.gov/region6

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EPA, Interior, Army, Agree to Work Together in Removing Health Risks at Tar Creek, Oklahoma Superfund Site

Release date: 5/1/2003

Contact Information: For more information contact the Office of External Affairs at (214) 665-2200.

EPA today announced its signing of a Memorandum of Understanding (MOU) with the U.S. Dept. of the Interior and the U.S. Dept. of the Army to develop and implement solutions to the human health and environmental threats posed by the Tar Creek Superfund site located in northeastern Oklahoma and other states.

"This MOU will help ensure a coordinated, effective, federal commitment to clean up the Tar Creek Superfund site and protect the local communities plagued by contamination from the site. The MOU would not have been possible without the good faith efforts of the Department of Interior, Department of the Army, and the strong leadership of Senator Jim Inhofe of Oklahoma," said EPA Administrator Christie Whitman. "Senator Inhofe has been a longtime supporter of this effort and has been instrumental in facilitating this agreement."

The MOU gives the federal agencies the opportunity to coordinate with the affected Indian tribes, the State of Oklahoma, local communities, and other stakeholders in determining the most effective manner for resolving the issues at this site. No single authority under any of the agencies could address the full of range of issue at this site, which is why they decided to work collaboratively.

Even before today's MOU, EPA has spent nearly $100 million addressing immediate threats to the residents near and around the 40 square-mile site by removing lead and zinc waste, known as chat, from residential yards and from high access areas. After yard remediation and extensive health education efforts funded by EPA, a 50 percent reduction in the number of children with elevated blood lead levels has been achieved in local communities.

The 40 square-mile lead-and-zinc contaminated Tar Creek site was listed on the National Priorities List in 1983. The site encompasses the Oklahoma portion of the Tri-State Mining District of northeastern Oklahoma, southeastern Kansas, and southwestern Missouri, and includes communities in Ottawa County outside the mining area that are also contaminated with mining waste. The towns of Picher, Cardin, Commerce, North Miami and Quapaw are also part of the site. Much of the land on the Tar Creek site is allotted Indian Land. Approximately 30,000 people live in the communities surrounding the site

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Perspectives from the Regional Administrator

T A R C R E E K

Mayor Greene hosts Assistant Administrator Tom Dunne

Regional Administrator Richard Greene met with USEPA Acting Assistant Administrator TomDunne to highlight the Region's progress in restoring polluted land and protecting the security of America. Dunne oversees the EPA Office of Solid Waste and Emergency Response.

Special attention was given to the region's activities at the Tar Creek Superfund site. Good progress is being made toward completion of the fieldwork needed to complete the Remedial Investigation and Feasibility Study, and to address the chat piles in the area.

In addition to discussing Tar Creek, the group discussed regional progress and project status in many areas, including Superfund and Brownfields site revitalization, Ready-for-Reuse, Emergency Preparedness and Superfund response preparations, state capabilities in emergency response, managing removal projects, and Resource Conservation and Recovery Act (RCRA) activities.

Committee on Senate Environment and Public Works hearing on EPA 2006 Budget

Statement of Senator James M. Inhofe, February 9, 2005

The Tar Creek Superfund Site in northeastern Oklahoma has been a top priority for me and the EPA. When Administrator Leavitt visited the site with me, he became the first Cabinet level official to tour Tar Creek and see what we are dealing with there. Tar Creek is a 40 square-mile site that is the number one listed site on the National Priorities List. While, much work has been done and much credit goes to the EPA and specifically the Region 6 Administrator, Richard Greene, there is more work left to do. I want to take this opportunity to get the EPA`s continued commitment to protect human health at Tar Creek and get this site cleaned up.

EPA Co-hosts Community Meeting at Tar Creek

The Environmental Protection Agency, the US Army Corps of Engineers, and the Department of Interior, in coordination with the State of Oklahoma, hosted a community meeting and open house to present the collaborative efforts taking place toward a holistic solution for the Tar Creek area.

The meeting highlighted projects coordinated between the federal agencies, state and local partners, the University of Oklahoma, and the Quapaw Tribe.

The open house was an opportunity for community members to learn more about these and other local activities and services, as well as participate in one-on-one discussions with agency, tribal, and organization members.

Public meeting notice March 2004

Project Update - March 2004

Guest Commentary for Joplin Globe - March 2004

EPA, Interior, Army, to Work Together in Removing Health Risks at Tar Creek, Oklahoma

The 40 square mile Tar Creek Superfund Site in northeastern Oklahoma is part of the 1,188 square mile historic zinc and lead mines known as the Tri-State Mining District in Missouri, Kansas, and Oklahoma. The district's historic lead and zinc production ranks as one of the highest in the world, with total ore production estimated to have been slightly more the 0.5 billion short tons, with production high during World War II. Mining began in the early 1900's and continued until the 1960's. The by-products of the mining operation were highly acidic mine water and large amounts of discarded mine and mill tailings, discarded in chat piles or settling ponds. The principle pollutants are lead, cadmium, and zinc, and chat was freely used and placed throughout the area by individuals and municipal and county agencies. There are approximately 30,000 people residing in the area, and most of the land on the Tar Creek site is allotted Indian Land.

On May 1, 2003, the Environmental Protection Agency (EPA) signed a Memorandum of Understanding (MOU) with the U.S. Department of the Interior and the U.S. Department of the Army to develop and implement solutions to the human health and environmental threats posed by the Tar Creek site. The MOU gives the federal agencies the opportunity to coordinate with the affected Indian tribes, the State of Oklahoma, local communities, and other stakeholders in determining the most effective manner for resolving the issues at this site.

At the present time, the EPA is the only entity that has actually accomplished results at the Tar Creek site. The EPA is directly responsible for progress through its yard remediation, community education, and blood lead testing programs. Approximately 1,780 residential properties have been remediated. As a result, there has been a 50 percent decrease (24 percent to 12 percent) in the number of children with blood lead levels equal to or greater than the 10ug/dL standard set by the Center for Disease Control. This is a notable and meaningful protection provided to the children, who we must remember are most at risk. And, we fully expect to see an even larger decrease when the county blood lead data is analyzed again in the spring of 2004. EPA continues to be intricately involved in the work being done to improve the health of the Tar Creek residents.

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Center for Children's Environmental Health and Disease Prevention

Harvard School of Public Health, Boston Research Projects

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Project 1:

Metals, Nutrition and Stress in Child Development

Community-Based Participatory Research Project

Project Leader: Robert O. Wright

Toxic waste sites typically contain multiple chemicals, yet the vast majority of epidemiologic studies focus only on the health effects of a single chemical, rather than joint exposures. The role of chronic stress in modifying the toxicity of metal exposure is another issue which may be relevant to community health, as the presence of a Superfund site has been demonstrated to be associated with increased chronic stress.

The problem of environmental exposure on contaminated lands is also particularly acute for Native Americans whose traditional way of life has close ties to the environment. Because the land and what’s grown on it is central to individual and community life, not only are tribal populations disproportionately exposed to environmental toxicants, but the usual preventive measures, such as recommendations to reduce consumption of game or fish threaten to diminish their culture.

Such a situation mandates a different approach to exposure assessment, education and health care intervention for communities in which subsistence lifestyles predispose them to exposure to environmental contaminants.

In this community-based participatory research project, the Harvard School of Public Health, L.E.A.D. (Local Environmental Action Demanded, a community advocacy group), and Integris Baptist Regional Health Center are partnering to utilize the culture-based exposure assessment conducted in Project 2 to develop a multi-component intervention program to reduce toxic metal exposures among children living on or near the Tar Creek Superfund site in northeast Oklahoma.

The project comprises both observational specific aims on metal mixtures and psychological stress in predicting child development, as measured by the Bayley Scale Assessment, as well as nutritional interventions to promote increased dietary iron and calcium intake to reduce toxic metal absorption, home visits to develop social supports, and community-level interventions to promote targeted remediation of compliance and reduce exposure to toxic metals among children, as well as to determine the modifying influence of joint exposures to metals and stress on neurologic outcomes as measured by the Bayley Scales of Child Development.

Original Abstract/2004 Progress Report/2005 Progress Report

Project 2:

Exposure Assessment of Children and Metals in Mining Waste:

Composition, Environmental Transport and Exposure Patterns

Exposure Assessment Research Project

Project Leader: James P. Shine

Project 2 explores the transport and fate of metals from mining wastes (“chat”) that could potentially lead to adverse exposure in children in communities surrounding the Tar Creek Superfund Site. Although metals in mining waste have been thought by some to be relatively unavailable for geochemical mobilization or biological uptake (due to interactions with reactive sulfides), researchers at the Harvard Children’s Center hypothesize that reactions releasing metals to which children are exposed may make metals from mining waste more bioavailable than suspected. Hey may also favor the release of some metals (such as zinc and cadmium) over others (such as copper and lead). Thus, the mixture of metals to which children are exposed may be very different from the mixture of metals present in the parent chat. In addition, metals that have mobilized off the chat piles into other exposure media such as soil, water, airborne particulates and indoor dust, may have a higher relative bioavailability when compared to parent waste material.

The Harvard Center is testing this hypothesis, and is determining whether the types and bioavailability of metals to which children are exposed can be better understood through a more sophisticated consideration of the underlying geochemistry of metals in mine wastes. Specifically, Harvard Center researchers are studying which metals are enriched in down-gradient exposure media relative to metals in chat waste, and are using sequential extraction techniques and X-ray absorption spectroscopy to demonstrate that metals in these down-gradient media have a higher relative bioavailability.

In conjunction with Project 1, researchers are using these data to conduct a nested case-control study to examine the extent that environmental and behavioral factors, including diet and activity patterns, may explain differences in blood levels of lead (Pb) and manganese (Mn) in children from the Tar Creek area with high and low levels of Pb and Mn in their blood. The researchers will use the samples collected in this project to supply the animal studies (Projects 3 and 4) with well-characterized exposure material with respect to the concentrations and potential bioavailability of metals within each media. Finally, in parallel with the exposure assessment, researchers are conducting micro-array experiments and assess their utility as part of an overall exposure/adverse health outcome assessment.

Original Abstract/2004 Progress Report/2005 Progress Report

Project 3:

Manganese, Iron, Cadmium and Lead Transport from the Environment to
Critical Organs during Gestation and Early Development in a Rat Model

Laboratory-Based Mechanistic Study

Project Director: Joseph D. Brain

Project 3 explores the transport of iron (Fe), manganese (Mn), cadmium (Cd) and lead (Pb) from environments experienced by children to the blood and critical organs such as the brain, heart, liver and kidney. Researchers at the Harvard Children’s Center seek to better understand metal exposures of children and their mothers in settings like Tar Creek, Oklahoma by (1) utilizing exposures during and after pregnancy; (2) using metal ions as well as complex environmental samples from Tar Creek; and (3) comparing different routes of entry from the environment into the body.

Project 3 is also exploring the role of toxic metals and iron status as they interact to influence metal absorption. In animal models, the researchers are simultaneously studying both the molecular mechanisms of metal transport as well as the corresponding pharmacokinetics of metals from the nose, lung and gut to the blood, central nervous system and other organs. These data will be correlated with outcomes in both animal (Project 4) and human studies (Project 1). When data from Project 3 are combined with data from the exposure assessment in Project 2, researchers will be able to better identify which routes of exposure result in the most significant body burdens of toxic metals. From this knowledge, researchers at the Harvard Children’s Center should be able to craft optimal strategies in Tar Creek to reduce the dose of toxic metals to mothers and children and thus better respond to the environmental concerns of the citizens of Tar Creek.

Original Abstract - 2004 Progress Report - 2005 Progress Report

Project 4:

Metals Neurotoxicity Research Project

Laboratory-Based Mechanistic Study

Project Leader: Tim Maher

With the exception of research on lead, alterations in cognitive and behavioral function as a result of exposure to metals has to date received little systematic attention. Even less attention has been placed on the effects of exposures to combinations of metals or such exposures on a background of external environmental stressors – scenarios that are unfortunately all too common. The use of animal models to study the neurotoxic effects of such exposures allows for more tightly controlled experimental design than is possible in human studies and allows for a more in-depth examination of the effects of the exposures on the nervous system and the mechanisms that underlie those effects. The enhanced understanding of the sites and mechanisms of the toxic action of these exposures that animal models can provide may result in development of more effective interventions.

Development in the nervous system is marked by tremendous cellular plasticity as the highly intricate and specific connections within and between brain regions are established. Two important mechanisms by which such contaminants can adversely affect the proper establishment of neuronal structure are disruption of normal synaptic transmission, which can have dramatic effects on cellular plasticity, and the induction of cell death. Such effects at the cellular level could lead, at the behavioral level, to deficits in a variety of functions including intellectual and social behaviors.

In Project 4, researchers are examining neurotoxic effects in juvenile rates of in utero and postnatal exposure to individual metals found in mining waste (“chat”) from the Tar Creek Superfund Site, specific mixtures of those metals, and actual chat from the site. In addition, researchers are exploring how stress may modify the effects of metal exposures, as the psychological stresses that accompany life at a Superfund site have been raised as an issue of concern in the Tar Creek community.

The aim of these animal studies is to complement the research being conducted in Project 1.

To accomplish this, researchers are looking at both the cellular and behavioral levels in rat models, and are taking advantage of experiments being conducted as part of Project 2 and Project 3, so that the exposures in the experiments reflect the actual exposures experienced by the Tar Creek community. When data from Project 4 are combined with the exposure assessment in Project 2 and body burden data from Project 3, researchers will better be able to identify which routes of exposure result in the most significant neurological effects and the contribution of manganese and lead in chat to the neurological impacts of exposure to the chat. Thus, the Harvard Children’s Center research will improve our understanding of the neurological effects of exposure to mixtures of metals, and in so doing, support the Center’s overall goal of crafting optimal strategies in Tar Creek to reduce the neurological effects of toxic metals in humans.

Original Abstract/2004 Progress Report/2005 Progress Report

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Workshop to provide information on chat sales

Chat owners and buyers can learn more about buying, selling and using chat from the Tar Creek area at a workshop scheduled for August 19, from 5-8 p.m. at the Miami Convention Center, in Miami, Oklahoma.

The intent of the workshop is to ensure chat sales from the Tar Creek Superfund site continue and comply with the federal Chat Rule.

Officials from EPA, as well as representatives from the Oklahoma Department of Environmental Quality, Bureau of Indian Affairs, U.S. Department of the Interior and the Quapaw Tribe will present information at the workshop. EPA has established that chat from the Tar Creek area can be used safely as an aggregate in asphalt and cement road surfaces. Chat also has beneficial uses in non-transportation, non-residential concrete and cement projects, such as commercial foundations, side walks, and parking areas.

Chat sales are a significant part of EPA cleanup plans for Tar Creek. Ottawa County, Oklahoma, contains more than 50 million tons of chat.

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Criteria for the Safe and Environmentally Protective Use of Granular Mine Tailings Known as "Chat"

Final Rule - July 18, 2007

P R O P O S E D - R U L E

SUMMARY

In July 2007, EPA finalized criteria for the environmentally protective use of chat in transportation construction projects carried out in whole or in part with federal funds. EPA is also recommending criteria as guidance for the beneficial use of chat in non-transportation, non-residential concrete and cement projects, such as commercial foundations, side walk areas, and parking areas.

Chat is a gravel-like waste created from lead and zinc mining activities in the Oklahoma, Kansas, and Missouri tri-state mining region between the late 1800s and mid 1900s. Currently about 100 million tons of chat contaminated with lead, zinc and cadmium are located in the tri-state mining district. The finalized criteria will help reduce chat piles and improve human health and the environment in the Tri-state area.

The tri-state district covers approximately 2,500 square miles and includes parts of Ottawa County, Oklahoma; Cherokee County, Kansas; and Jasper, Lawrence, Newton and Barry Counties, Missouri. It includes four Superfund National Priority List (NPL) sites: Cherokee County, Tar Creek (Ottawa County), Newton County Mine and the Oronogo-Duenweg Mining Belt.

Federal Register Notice | PDF Version (23 pp, 240K) - July 18, 2007

The support materials for this final and the proposed rule and the public comments EPA received are available for public review online at Regulations.gov.

To use Regulations.gov:

Proposed Rule - April 4, 2006

Summary

In April 2006, EPA proposed criteria for the environmentally protective use of chat in transportation construction projects carried out in whole or in part with federal funds, and in concrete and cement projects. Chat is a gravel-like waste created from lead and zinc mining activities in the Oklahoma, Kansas, and Missouri tri-state mining region between the late 1800s and mid 1900s. The proposed criteria involve safely encapsulating chat particles in asphalt or cement and concrete.

Currently about 100 million tons of chat contaminated with lead, zinc and cadmium are located in the tri-state mining district. The proposed criteria will help reduce these piles, thus reducing the amount of chat particles that are spread by wind, water or air into the surrounding environment.

The tri-state district covers approximately 2,500 square miles and includes parts of Ottawa County, Oklahoma; Cherokee County, Kansas; and Jasper and Newton Counties, Missouri. It includes four Superfund National Priority List (NPL) sites: Cherokee County, Tar Creek (Ottawa County), Newton County Mine and the Oronogo-Duenweg Mining Belt.

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The Chat Rule

What does the chat rule do?

EPA is proposing mandatory criteria for the beneficial use of chat from the tri-state mining district in transportation construction projects that are carried out, in whole or in part, using federal funds. EPA also is proposing criteria for the beneficial use of chat in non-transportation, nonresidential concrete and cement projects. This package is called the chat rule.

Why isn't the Department of Transportation (DOT) writing this regulation?

The Safe, Accountable, Flexible, and Efficient Transportation Equity Act of 2005 requires EPA to develop criteria for the use of chat in transportation construction projects and cement and concrete projects. While EPA is the appropriate party to assess the environmental risks in the beneficial use of chat, the Agency is consulting with US DOT throughout the development of these criteria to ensure that the materials are structurally sound for transportation projects.

What is chat and where does it come from?

Chat, a local term for mining waste, is a lead/zinc mining waste from the tri-state mining district. Chat, also known as granular mine tailings, is composed of chert-like material, containing lead, zinc and cadmium contaminants. The tri-state region covers approximately 2,500 square miles and includes parts of Ottawa County, Oklahoma; Cherokee County, Kansas; and Jasper and Newton Counties, Missouri.

Why is chat a potential hazard to human health?

When left exposed to the environment, the lead in chat can be a hazard to human health. Chat particles can enter soil, surface water, groundwater, and air. Exposure to lead has been known to cause learning disabilities and damage the human immune, blood and nervous systems. Children are the most susceptible to these effects.

Is chat safe to use?

Chat can be used safely when its particles are encapsulated in asphalt or concrete. Asphalt and concrete bind chat in a solid mixture so its particles are unlikely to be spread by wind or water.

How will chat be used?

Chat from the tri-state area will be used in hot asphalt mix or concrete for transportation construction projects, such as roads and bridges. Chat may also be used in non-transportation, nonresidential concrete and asphalt projects.

Why was the Kansas, Oklahoma and Missouri tri-state mining district chosen?

The transportation bill enacted by Congress in August specifically calls for EPA to address chat from the tri-state mining district. As such, the proposed rule will impact only chat currently located in the tri-state mining district because chat located in this area is geologically and chemically similar.

Will EPA be addressing the beneficial use of chat from other mining districts in the country?

No, EPA is not addressing the beneficial use of chat from any other mining districts because the transportation bill only requires EPA to develop criteria for the beneficial use of chat from the tri-state mining district.

How will this action affect local tribes?

This rule will minimally affect the local tribes. The Bureau of Indian Affairs (BIA) has initiated a process to allow chat sales from tribal lands. This rule will clarify the environmentally protective uses of chat in transportation construction and in cement and concrete projects. Chat sales destined for other uses are unaffected by this rule.

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Cleanup plan finalized for Tar Creek Superfund site

The Environmental Protection Agency, in cooperation with the State of Oklahoma Environmental Secretary, Oklahoma Department of Environmental Quality, and the Quapaw Tribe of Oklahoma, has completed the final cleanup plan for the Tar Creek Superfund site in Ottawa County, Oklahoma.

"This master plan will ensure a coordinated commitment to permanently clean up the Tar Creek Superfund site, said EPA Regional Administrator Richard E. Greene.

“It is a long-awaited step in finalizing work to clean up one of the nation's largest Superfund sites, and I am pleased to be part of this monumental occasion."

Components of the cleanup plan include:

(1) funding for the voluntary relocation of residents and businesses located in Picher, Cardin and Hockerville through the State of Oklahoma’s Lead-Impacted Communities Relocation Assistance Trust,

(2) chat sales, and

(3) disposal of source materials in a manner that will reduce the overall footprint of contamination and reduce the need for land use restrictions, institutional controls, and operation and maintenance. The cost of the plan is approximately $167 million.

The final cleanup plan reaffirms years of hard work by local, tribal, state and federal partners to permanently clean up the site. It addresses contamination posed by chat piles, other mine and mill waste, and smelter waste in the 40-square mile former lead and zinc mining area.

EPA based its decision on public comments, extensive studies of the extent of contamination, and human health and environmental risks caused by the contamination at the site. More details on the plan are described in the record of decision. (161 pp, 4.7 MB, About PDF)

EPA has spent nearly $150 million addressing immediate threats to the residents near and around the site by removing lead and zinc waste, known as chat, from residential yards and from high access areas. After yard remediation and extensive health education efforts funded by EPA, a 50 percent reduction in the number of children with elevated blood lead levels has been achieved in local communities.

EPA listed the Tar Creek site on its National Priorities List in 1983.

The site is located in northeastern Oklahoma and is part of the 1,188 square mile historic zinc and lead mines known as the Tri-State Mining District in Missouri, Kansas, and Oklahoma. Mining began in the early 1900s and continued until the 1960s.

Much of the land on the Tar Creek site is allotted Indian Land.

The towns of Picher, Cardin, Commerce, North Miami and Quapaw are also part of the site.

Approximately 19,000 people live in the communities surrounding the site.

Additional information on the Tar Creek site and the record of decision

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Radio Announcements

Blood lead levels in children living in the area of the Tar Creek Superfund site are substantially lower than they were in previous years, according to a report released by the Agency for Toxic Substances and Disease Registry. Following are EPA comments on the report.

A report by the Agency for Toxic Substances and Disease Registry shows substantially lower blood levels of lead in children living near the Tar Creek Superfund site than in previous surveys. The EPA is very pleased to see this considerable improvement in the health of children in the Tar Creek area. This progress further encourages our commitment to continue our work until the risk of exposure to lead is finally removed from these communities.

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TAR CREEK (OTTAWA COUNTY) OKLAHOMA
EPA ID# OKD980629844
Site ID: 0601269
EPA REGION 6 - CONGRESSIONAL DISTRICT 02

Contacts: Mike McAteer (OU2) 214-665-7157 - Ursula Lennox (OU4) 214-665-6743 - John Meyer (OU5) 214-665-6742

Updated: September 2008

CURRENT STATUS

OU1 (Surface Water/Groundwater)

The 3rd Five Year Review was completed in September 2005 and is available on EPA’s website.

EPA is funding the ODEQ to monitor ground water in the Roubidoux aquifer; groundwater monitoring activities are on-going.

OU2 (Residential Properties)

On Saturday, May 10, 2008, an EF-4 tornado struck parts of the Tar Creek Superfund site. EPA responded to the scene and conducted air monitoring and surficial soil sampling. EPA also established hand wash stations and distributed dust masks to responders and residents as a normal safety precaution when dealing with debris from a disaster.

A risk evaluation of the field data collected was performed and concluded that there are no immediate adverse health concerns associated with lead from exposure to soil to first responders or residents returning to their homes and that there are no adverse health effect from inhalation of particulate matter.

EPA is working with federal, state, and local officials to assess the impact of the tornado and to ensure that prompt and comprehensive assistance is provided to affected residents. EPA has also provided $8 million in federal funding to the Oklahoma Department of Environment Quality to expedite the buyout and relocation of residents of Picher, Oklahoma.

As of August 10, 2007, 2,254 residential yards and public areas have been remediated since the inception of cleanup in Quapaw, Cardin, Picher, Commerce, and North Miami. Work on the final 119 properties in Commerce began in December of 2005 and was completed in October 2007.

The EPA is funding ATSDR and Ottawa County Health Department (OCHD) to provide community health education and blood lead screening for the five-city mining area. The OCHD also works with local health professionals including Indian Health Service physicians to provide education to the medical community.

October 2004, Report To Congress by the Agency for Toxic Substances and Disease Registry

(ATSDR). This report shows that children between the ages of 1 and 5 living at the Tar Creek site who had a blood lead level in excess of the 10ug/dL level decreased from 31.2% in 1996 to 2.8% in 2003.

The 2.8% level is only slightly higher than the findings of the National Health and Nutrition Examination Surveys (NHANES) for children living in the United States as a whole, which stands at 2.2% for children between the ages of 1 and 5 during the years 1999-2000.

OU4 (Chat Piles, Other Mine and Mill Wastes, Smelter Wastes)

EPA in coordination with ODEQ, the Quapaw Tribe, BIA, DOI, and the OK-DOT conducted a Chat Sales Availability Sessions and a Workshop August 19-20, 2008.

The Availability Sessions enabled participants to meet one-on-one with the parties listed above, and gain additional insight on their role Tar Creek 2 EPA Publication Date: September 3, 2008 involving chat and chat sales.

The workshop informed participants on the purpose of the Chat Rule, record keeping requirements, the desire to facilitate chat sales and encouraged the exchange of information between chat sellers, purchasers, and owners of chat.

On June 17, 2008 EPA conducted a series of meetings with chat sellers and a gravel operator in Picher, OK. Participants included representatives from the Bureau of Indian Affairs, EPA-Region 7, the Oklahoma Department of Environmental Quality and the Quapaw Tribe.

During these meetings...

EPA discussed the Chat Rule, reporting requirements, upcoming plans to conduct a chat sales workshop in August, and addressed questions posed by the participants. The exchange was beneficial to all parties and EPA gained additional insight on measures that should be pursued to enhance participation at the upcoming chat sale workshop. EPA will continue to meet and coordinate with its stakeholders in preparation for the workshop.

EPA signed the Record of Decision (ROD) for OU4 on February 20, 2008. The ROD provides a complete explanation of EPA’s final decision, a summary of site investigations, and a responsiveness summary that addresses comments received during the public comment period on the July 2007 Proposed Plan.

The ROD is available on EPA’s webpage - http://www.epa.gov/earth1r6/6sf/6sf-decisiondocs.htm.

The ROD and the OU4 Administrative Record, which is a collection of technical site material and documents that forms the basis for the selected remedy, is available at the following site repositories:

Miami Public Library Oklahoma Department of Environmental Quality
200 North Main St 707 North Robinson
Miami, OK 74354 Oklahoma City, OK 73102
918-542-3064 405-702-1000
U.S. EPA - Region 6
1445 Ross Ave
Dallas, TX 75202
214-665-6427 (Please call for an appointment if you desire to review the file)

Meetings and consultations between EPA, ODEQ, the Quapaw Tribe, and the 10 Downstream Tribes on site activities are being conducted as needed.

A public meeting was conducted on August 28, and an Availability Session was held the following day (August 29) for the public to meet with EPA representatives on a one-on-one basis to ask any questions related to the Proposed Plan.

EPA released the Proposed Plan of Action for OU4 on July 29, 2007 for public comment. The 30-day public comment period that was scheduled to conclude August 30, 2007, was extended, to accommodate the public’s request. The public comment period on the Proposed Plan of Action for OU4 concluded October 1, 2007.

EPA conducted consultations with representatives of the eleven Federally-recognized tribes from January through July 2007, to hear and address their concerns on the draft Proposed Plan of Action. The consultations were accomplished through group meetings, individual meetings and conference calls.

EPA has completed 3 chat disposal pilot projects.

Approximately 34,600 tons of chat was injected into under ground mine caverns.

An additional 40,000 tons of mine waste were contained in an innovative trench/road system.

Two more pilots are underway.

Both include injecting washed chat fines directly into mine caverns and eliminating sediment/holding ponds.

The data will help better define design criteria.

OU5 (Sediment and Surface Water)

EPA Region 6 is working with EPA Region 7 as part of multi-state effort to characterize sediment and surface water throughout the Spring and Neosho River basins.

Sampling was conducted in the river basins on May 1 – 5, 2006.

The results from the sampling are expected to be available by October 2006.

A second phase of sampling was conducted in Summer 2007.

This sampling focused on collecting data on the toxicity of the sediments and the results will be used to guide future cleanup activities.

Memorandum of Understanding (MOU) Activities

Representatives from the various tribes, USACE, USGS, BIA, EPA, and ODEQ are conducting Tar Creek 3 EPA Publication Date: September 3, 2008 multiple meetings, in order to share information and keep parties abreast of pilots and studies that are being pursued in and around the site.

The cleanup of lead-contaminated soils from over 2,000 residential yards and high access areas located within the five-city mining area has significantly reduced the exposure of the population, especially young children.

October 2004, Report To Congress by the Agency for Toxic Substances and Disease Registry (ATSDR).

This report shows that children between the ages of 1 and 5 living at the Tar Creek site who had a blood lead level in excess of the 10ug/dL level decreased from 31.2% in 1996 to 2.8% in 2003.

The 2.8% level is only slightly higher than the findings of the National Health and Nutrition Examination Surveys (NHANES) for children living in the United States as a whole, which stands at 2.2% for children between the ages of 1 and 5 during the years 1999-2000.

Abandoned well plugging has reduced the potential for contaminants in the shallow Boone Aquifer to migrate to the Roubideax drinking water aquifer.

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National Priorities Listing (NPL)

History

Site Hazard Ranking System Score: 58.15
Proposed Date: 7/27/1981
Final Date: 9/08/1983

Location: The Tar Creek Superfund Site (hereinafter “the Site”) is part of the Tri-State Mining District, which includes northeastern Oklahoma, southeastern Kansas, and southwestern Missouri. Specifically, the Site includes the Old Picher Field lead and zinc mining area located in northeastern Ottawa County.

Population: Approximately 19,556 people live in the surrounding area.

Setting: The Site consists of five mining cities, Picher, Cardin, Quapaw, Commerce, and North Miami, and other areas within Ottawa County. Chat piles are located throughout the communities.

Principal Pollutants: Lead, cadmium, and zinc.

Health Considerations:

Lead-contaminated soils and chat piles are a source of exposure to the population, especially to young children. A percentage of young children living in the five-city mining area are known to have blood lead levels in excess of the 10 g/dL (micrograms per deciliter) standard set by the Center for Disease Control (CDC). The percentage of children with elevated blood lead levels remains well above state and national averages.

Children are the most sensitive population for lead exposures. Chronic exposure can deleteriously affect the immune system, blood system, nervous system, and kidneys. Harmful effects include premature births, smaller babies, decreased mental ability in the infant, learning difficulties, and reduced growth in young children.

Record of Decision (ROD)

Operable Unit 1: ROD signed on June 6, 1984
Operable Unit 2: ROD signed on August 27, 1997
Operable Unit 4: ROD signed on February 20, 2008
Tar Creek 4 EPA Publication Date: September 3, 2008

The OU1 ROD addressed

(1) the surface water degradation by the discharge of acid mine water, and

(2) the threat of contamination of the Roubidoux Aquifer, the regional water supply, by downward migration of acid mine water from the overlying Boone Aquifer through abandoned wells connecting the two.

Recharge was to be prevented by utilizing diking and diversion structures to stop the surface water of Tar Creek from entering the two collapsed mine shafts in Kansas, which were identified as the main inflow points.

Additionally, the remedy called for preventing the downward migration of acid mine water into the Roubidoux Aquifer by plugging 66 abandoned wells.

During remediation, an additional 17 wells were identified and addressed, bringing the total to 83 wells.

Construction activities were concluded on December 22, 1986.

The OU2 ROD addressed the residential areas.

The full text for this ROD is located on the Internet at: www.epa.gov/earth1r6/6sf/6sf-decisiondocs.htm

The OU4 ROD addresses the source materials, rural residential yard contamination, transition zone soil contamination, and contamination in water drawn from rural residential wells.

The selected remedy also includes relocation, which will continue to be implemented by the Lead Impacted Communities Relocation Assistance Trust (LICRAT), and chat sales.

Though EPA does not own any chat and will not purchase any chat, it will assist chat sales participants as part of EPA’s CERCLA remedy.

The full text for this ROD is available at the webpage listed above.

Site Contacts

EPA Remedial Project Managers: Mike McAteer, OU2 214-665-7157
Ursula Lennox, OU1 & 4 214-665-6743
John Meyer, OU5 214-665-6742
EPA Community Coordinator: Janetta Coats 214-665-7308
EPA Site Attorney: Jim Costello 214-665-8045
EPA State Coordinator: Kathy Gibson 214-665-7196
EPA Regional Public Liaison: Donn R. Walters 214-665-6483
EPA Toll-Free Telephone Number: 1-800-533-3508
ODEQ Program Manager: Kelly Dixon 405-702-5156
ODEQ Tar Creek Coordinator Angela Hughes 405-702-5141
ODEQ Project Managers: Dennis Datin, P.E. 405-702-5125
David Cates, P.E. 405-702-5133
Quapaw Environmental Program Director: Tim Kent 918-542-1853
Quapaw Superfund Program Manager: Vacant

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GOVERNOR FRANK KEATING’S
TAR CREEK SUPERFUND TASK FORCE
ALTERNATIVES FOR ASSESSING INJURIES
TO NATURAL RESOURCES AT THE
TAR CREEK SUPERFUND SITE
OTTAWA COUNTY, OKLAHOMA
REPORT OF THE
NATURAL RESOURCE DAMAGES SUBCOMMITTEE
JULY 21, 2000
(Page 1)

INTRODUCTION

On February 2, 2000, Brian C. Griffin, Oklahoma Secretary of Environment, established a Subcommittee of the Governor’s Tar Creek Superfund Task Force to research avenues for assessing Natural Resource Damage Claims at the Tar Creek Superfund Site (the “Site”).

The Subcommittee includes representatives of the City of Miami; Grand Gateway; the Oklahoma Attorney General’s Office; the Oklahoma Department of Wildlife Conservation; the Quapaw Tribe of Oklahoma; the United States Fish and Wildlife Service, and the United States Bureau of Indian Affairs. The Subcommittee was chaired by Kelly Hunter Burch, Assistant Attorney General, and Lloyd Landreth, Esq., Gardere & Wynne, LLP.

The Subcommittee’s objective is to explore state and tribal alternatives for recovering damages for injuries to natural resources resulting from mining activities at the Site. Specifically, the Subcommittee was tasked with:

(1) Developing an outline of actions needed to assess injuries and damages which identifies cooperating agencies, timeframes for completion, and resource needs; and

(2) Outlining a process for identifying all potentially responsible parties that may be liable for Natural Resource Damages and the resources needed to complete that process.

LEGAL BASIS FOR NATURAL RESOURCE DAMAGE CLAIMS

The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) provides that responsible parties may be held liable for damages for injury, destruction, or loss of natural resources resulting from a release of hazardous substances, including the reasonable costs of assessing the damages. 42 U.S.C § 9607(a)(C). Natural resources under CERCLA include “land, fish, wildlife, biota, air, water, ground water, drinking water supplies, and other such resources belonging to, managed by, held in trust by, appertaining to or otherwise controlled by the United States . . . any State or local government . . . or any Indian tribe . . ..” 42 U.S.C. §9601(16).

(Page 2)

Natural resource damage claims are different from remediation efforts undertaken by the Environmental Protection Agency under CERCLA, which are intended to abate threats to public health and the environment.

Claims for natural resource damages pursuant to CERCLA are designed to compensate the public for past and interim injuries to natural resources. Only designated federal, state or tribal trustees may bring natural resource damage claims on behalf of the public. Damages recovered by the natural resource trustees must be used to “restore, replace or acquire the equivalent of such natural resources.” 42 U.S.C. §9607(f)(1).

THE NATURAL RESOURCE DAMAGE ASSESSMENT PROCESS

There are two types of regulations available for assessment of natural resource damages: (1) standard simplified procedures requiring minimal field investigation (Type A); and (2) protocols for conducting assessments in individual cases (Type B).

These regulations were promulgated by the U.S. Department of Interior in 43 C.F.R. Part 11. A natural resource damage assessment (NRDA) conducted by trustees in accordance with these regulations has the force and effect of a rebuttable presumption in any administrative or judicial proceeding under CERCLA. 42 U.S.C. §9607(f)(2)(C). However, CERCLA also allows the trustees to use other methods of assessing and quantifying damages.

If the trustees for the Tar Creek Superfund Site elect to follow the U.S. Department of Interior regulations, only the Type B method would be applicable to the NRDA. A Type B Assessment requires a multistage administrative process, with opportunities for public and Potentially Reponsible Party (“PRP”) participation in the latter stages. The stages of a Type B Assessment are summarized as follows:

(1) Preassessment Phase.

This phase provides for notification, coordination, and emergency action.

It includes a preassessment screen which is intended to be a rapid review of readily available information. The preassessment screen allows the trustees to make an initial determination of whether a hazardous substance release has affected natural resources and whether the potential injury is significant enough to justify a NRDA.

(2) Assessment Plan Phase. If the trustees decide to proceed with a NRDA, a trustee council may

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be formed in which one representative is designated as the “lead trustee.” The trustee council will then develop an Assessment Plan which outlines the methodologies and processes to apply in the NRDA. The Assessment Plan ensures that the assessment is performed in a planned and systematic manner and that the methodologies chosen demonstrate a reasonable cost. PRPs may be invited to participate in the assessment process at this stage.

(3) Type B Assessments.

The process for implementing Type B assessments has been divided into the following three phases:

(1) Injury Determination phase.

In this phase, the trustees formally establish that one or more natural resources have been injured as a result of a release of a hazardous substance. The trustees will determine both the pathways through which resources have been exposed to a hazardous substance and the nature of the injury.

(2) Quantification Phase.

The purpose of this phase is to establish the baseline condition of the injured resource, the areal and temporal extent of the injury, and estimates of the likelihood and time for recovery.

(3) Damage Determination Phase.

The purpose of this phase is to establish the appropriate compensation expressed as a monetary value for the injuries to natural resources. The regulations include guidance on acceptable cost estimation and valuation methodologies for determining compensation based on the cost of restoration, rehabilitation, replacement, and/or acquisition of equivalent resources, and the lost value of the injured resources from the time of injury until the resources recover or are restored.

(4) Post-assessment Phase.

This phase requires a Report of Assessment containing the results of the assessment and it documents that the assessment has been carried out according to regulations. It also delineates the manner in which the demand will be presented to PRPs and the steps to be taken when sums are awarded as damages.

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PRELIMINARY INFORMATION ON NRD AT THE TAR CREEK SITE

The Tar Creek Superfund Site, in Ottawa County, Oklahoma, is related to a larger Superfund remedial action being conducted in Cherokee County, Kansas and Jasper County, Missouri. The remedial actions are not being conducted jointly, however, releases of hazardous substances in these three states are the result of lead and zinc mining that took place from the early 1900's to the mid 1970's in what is commonly referred to as the Tri- State Mining District.

When mining operations ceased at the Site in the 1970s, the metallic sulfide minerals in the mines lowered the groundwater pH in the abandoned mine excavations. Rising groundwater levels surfaced through old air shafts and subsidence areas, entered surface water drainages, and spread downstream into associated streams and wetlands.

This water generally contains elevated concentrations of dissolved metals which adversely affects aquatic life, including lead, zinc, and cadmium. Deposition of excavated materials (“chat piles”) began in the early 1900's. The chat, laced with heavy metals, was scattered throughout the Site, and is suspected as a source of contamination of surface water and groundwater. Ponds and streams throughout the Site are potentially contaminated with mine and chat drainage.

Natural resources potentially affected by contaminants at the Site include, in part, federal and state threatened and endangered species, migratory birds, surface water, ground water, drinking water, plants, fish, biota, wildlife, cultural, agricultural, and terrestrial resources. Natural resources specific to the Tribes include, in part, natural resources used in traditional, cultural, spiritual and/or subsistence practices, such as medicinal herbs, furbearing animals, plants and fish used for ceremonial purposes.

In particular, some of the species that are potentially impacted by releases of hazardous substances include the endangered gray bat, the threatened Neosho madtom, the Ozark cavefish, and the threatened bald eagle. There has also been significant reduction in the number of fish and aquatic invertebrates below the mine discharge points in surface watersheds. The reduction in biomass and diversity of aquatic biota in streams and wetlands, as well as uptake of contaminants at the site, has also potentially affected migratory birds in all three states.

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STATUS OF THE TRI-STATE PARTNERSHIP ACTIVITES

Natural resources trustees for the three states, the eight Indian tribes, and the federal government have formed a partnership to share resources and information about injuries to natural resources in the Tri-State Mining District. In Oklahoma, the natural resource trustees include the Secretary of Environment for the State of Oklahoma, the U.S. Fish and Wildlife Service and Bureau of Indian Affairs for the U.S. Department of the Interior, and eight separate Indian Tribes (the “Trustees”).

The Tri-State Partnership is in the process of compiling and analyzing available data pertinent to a Tri- State NRDA. Preliminary indications are that there have been extensive injuries to natural resources at the Site. It is possible that damages could exceed several hundred million dollars.

The State of Oklahoma and the U.S. Department of Interior recovered some funds for natural resource damages at the Site in the Eagle Picher Bankruptcy Settlement.

The State of Oklahoma received $345,612

The U.S. Fish and Wildlife Service received approximately $400,000

The U.S. Fish and Wildlife Service is proposing to undertake partial restoration for loss of natural resources with the acquisition and management of an Ottawa County endangered bat maternity cave, conservation of high quality bottomland forest along the Neosho River, and acquisition and protection of a large continuous stand of Ozark forest and cave habitats in Adair County, Oklahoma. These proposed restoration projects are scheduled to be implemented in 2000.

AVAILABLE OPTIONS FOR PURSUIT OF A NRD CLAIM

Currently, the Trustees are in the preassessment phase of the NRDA regulations. In the preassessment phase, the Trustees must determine whether there is a reasonable probability that a natural resource damage claim will be successful before funds and resources are expended in carrying out an assessment. Representatives of natural resource Trustees in Oklahoma met on July 19, 2000 to discuss the formation of a trustee council.

Oklahoma Trustees could complete the preassessment phase and make a decision on whether to pursue a NRDA as early as the Spring of 2001.

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The following will outline options for proceeding with a NRDA at the Tar Creek Superfund Site:

(5) Initiate Assessment Plan Phase (Winter 2001)

If the Trustees determine that an assessment is warranted, a plan for the assessment of natural resource damages must be developed. The Assessment Plan will ensure that the NRDA is conducted in a planned and systematic manner at a reasonable cost. The plan will include a Preliminary Estimate of Damages, an Injury Determination, Quantification of Injuries, and a Damage Determination.

(1) Costs.

The following costs may be incurred in the Assessment Plan phase of the damage assessment:

(i) Methodology identification and screening;

(1) Potentially responsible party notification;

(2) Public participation;

(3) Exposure confirmation analysis;

(4) Preliminary estimate of damages; and

(5) Any other Assessment Plan costs for activities authorized by sections 11.30 through 11.38 of the Type B regulations.

(2) Recovery of Damages.

At the conclusion of the assessment, the Trustees will present the PRPs with a written demand for damages and assessment costs. If the PRPs decline to pay damages and costs, litigation may be initiated pursuant to Section 107 of CERCLA.

(3) Post-Assessment Phase.

Sums recovered by the federal government acting as trustee shall be retained by the trustee, without further appropriation, in a separate account in the U.S. Treasury. Sums recovered by the state shall either:

(i) Be placed in a separate account in the state treasury or

(ii) Be placed by the responsible party or parties in an interest bearing account payable in trust to the state agency acting as trustee. Sums

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recovered by an Indian Tribe shall either

(i) Be placed in an account in the tribal treasury or

(ii) Be placed by the responsible party or parties in an interest bearing account payable in trust to the Indian Tribe.

(6) Identification of Potentially Responsible Parties.

The Subcommittee has developed a listing of the majority of the information sources available to identify PRPs at the Site. In addition, the Oklahoma Attorney General’s Office has created a database that can be used to store all of the available information regarding ownership, leases, company data, production, location, and other pertinent information related to mining, smelting and transportation activities in the Oklahoma portion of the Tri-State Mining District. The database is interfaced with a GIS mapping system that will plot the precise location of the mine on a map that contains numerous data layers.

Although there is an enormous amount of data which remains to be analyzed, it appears that there are viable PRPs at the Site. The Office of the Attorney General will continue to gather and input information into the database after the conclusion of this Subcommittee’s work, however, it will be necessary to contract with a professional consultant to complete the work necessary to identify all of the PRPs. The Subcommittee is currently obtaining cost estimates for completing the PRP search.

Because the results of a full PRP search will be beneficial to both a NRDA and a Cost Recovery Action for remediation, the Subcommittee is proposing that the costs be shared between the U.S. Department of Interior, the State of Oklahoma, and the U.S. Environmental Protection Agency. This approach would require a legislative appropriation by the State of Oklahoma.

(7) NRDA Resource Needs.

Whenever possible, the assessment costs may be shared among the Trustees. The Department of Interior has a Natural Resource Damage Assessment and Restoration Fund which can be accessed by the federal government to cost-share with the state

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and the other trustees. The U.S. Department of Interior Tri-State NRDA effort has been funded for fiscal year 2000 at approximately $310,000. Funding needs for 2001 will likely be higher depending on the progress made in 2000.

If the cost of a preassessment screen is shared between the State of Oklahoma and the U.S. Department of Interior, the state’s portion may range between $100,000 and $200,000.

If the Trustees decide that a NRDA is warranted, the state’s portion of the cost share is likely to exceed one million dollars. Given the recovery potential in this case, the Subcommittee recommends that the state pursue funding for the preassessment phase. This will allow the Trustees to make an informed decision on whether to proceed to the assessment phase.

(4) Cooperative Assessments and Integration

The costs of an assessment can be substantially reduced by conducting cooperative assessments with PRPs and by integrating assessment work into the remedial process. These techniques are currently being employed successfully in other states, including the State of Missouri’s work in the Tri-State District.

Unlike Missouri, the Oklahoma PRPs are not participating in the remedial action Encouraging the PRPs to work cooperatively to address remediation and natural resource injuries at the Site will significantly reduce the costs of remediation and restoration activities, as well as potentially eliminate the costs of litigation.

Much of data needed to complete a NRDA at the Site is similar to that which will have to be collected during remedial investigation work and, where additional information is needed, additional data collection can be readily included into remedial sampling efforts. The cost savings inherent to integrating NRDA and remedial efforts is self evident.

It also seems prudent to integrate restoration alternatives into the remedial investigation, feasibility, and design phases at the Tar Creek Site given the complex and diverse nature of the problems that have been identified. For example, there has been extensive discussion regarding

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the benefits of artificial wetlands at the site for treatment of hazardous substances, as well as drainage and flooding problems. Creation of artificial wetlands will also be a viable restoration alternative for injuries to natural resources that can supplement the projects designed for remedial purposes. Integration of the NRDA and remedial activities will allow the decision makers to identify all of the alternatives for addressing the problems at the Site and will substantially reduce duplication of efforts.

(5) Cooperating Entities.

The Trustee for the State of Oklahoma, the Oklahoma Secretary of Environment, has designated three agencies to represent the interests of the state in the Tri-State Partnership:

the Oklahoma Department of Environmental Quality,

the Oklahoma Department of Wildlife Conservation,

and the Oklahoma Attorney General’s Office.

The U.S. Fish and Wildlife Service,

the Office of the Solicitor,

the Bureau of Indian Affairs,

the U.S. Geological Survey,

and the U.S. Office of Surface Mining all participate in the Tri-State Partnership on behalf of the federal government.

There are eight Indian Tribes represented in the partnership, including the

Eastern Shawnee Tribe of Oklahoma,

Miami Tribe of Oklahoma,

Modoc Tribe of Oklahoma,

Ottawa Tribe of Oklahoma,

Peoria Tribe of Indians of Oklahoma,

Quapaw Tribe of Oklahoma,

Seneca-Cayuga Tribe of Oklahoma,

and the Wyandotte Tribe of Oklahoma.

In addition, the State of Kansas is represented by

Kansas Department of Wildlife and Parks and the

Kansas Department of Health and Environment.

The State of Missouri is represented by the

Missouri Department of Natural Resources, the

Missouri Department of Conservation,

and the Missouri Attorney General’s Office.

CONCLUSION

Based on preliminary information gathered by this Subcommittee, it appears that the Trustees have sustained injuries to natural resources as a result of a release of hazardous substances at the Tar Creek Superfund Site. It is possible that damages at the Site could exceed several hundred million dollars.

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The Subcommittee has also determined that there are viable PRPs at the Tar Creek Superfund Site.

Completion of the research undertaken by the Subcommittee on this issue will require the expertise of a professional consulting firm. Because the results of a thorough search for PRPs at the Site will benefit both a cost recovery action and a natural resource damage claim, the Subcommittee proposes that the costs of the search be shared between the State of Oklahoma, the U.S. Environmental Protection Agency, and the U.S. Department of Interior.

The Subcommittee recommends that the Trustees proceed with the preassessment phase of a NRDA.

This step will allow the Trustees to formally determine whether there is a reasonable probability of making a successful claim before funds and resources are expended in carrying out the assessment phase. The Subcommittee further recommends that the State of Oklahoma pursue funding to conduct the preassessment phase on a cost-share basis with the U.S. Department of Interior.

If the Trustees decide to proceed with an assessment, the Subcommittee recommends that the assessment work and the remedial effort be integrated and that the PRPs be encouraged to work cooperatively with all parties to remediate and restore the Site.

EPA Provides Funds To Expedite Buyout of Picher Residents

Release date: 05/21/2008

(Dallas, Texas - May 21, 2008) The Environmental Protection Agency (EPA) is providing $8 million in federal funding to the Oklahoma Department of Environment Quality (ODEQ) to expedite the buyout and relocation of residents of Picher, Oklahoma. The mining town is in the center of the Tar Creek Superfund site and was heavily damaged by a May 10 tornado that struck parts of northeast Oklahoma and southwest Missouri.

The funding will be made available in two segments. The first segment of $3 million was specifically directed by Congress for the relocation of Picher, Cardin and Hockerville residents. The second segment of $5 million is being made available through the federal Superfund program. This funding will provide assistance for the buyout of residents, and demolition or relocation of homes, businesses, and public use structures located in the disaster area.

“We appreciate Senator Inhofe’s leadership in securing additional funds to assist these communities,” said EPA Regional Administrator Richard E. Greene. “We are working closely with Oklahoma officials and the Relocation Trust to ensure that the victims of the tornado get the help they need.”

In response to the May 10 tornado, EPA Region 6 deployed its mobile Command Post and emergency response staff to Picher to conduct air monitoring and soil sampling. Analysis of the air and soil data indicate no health risks to residents or responders from the debris created by the tornado. EPA will continue to assist the community until tornado-related debris removal is completed.

EPA listed the Tar Creek Superfund site on its National Priorities List in 1983. The site is located in northeast Oklahoma and is part of the 1,188 square mile historic zinc and lead mines known as the Tri-State Mining District in Missouri, Kansas and Oklahoma.

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STATE OF OKLAHOMA
DEPARTMENT OF ENVIRONMENTAL QUALITY (DEQ)
CUSTOMER SERVICES DIVISION

FY03 Section 106 Water Quality Management Program
I-006400-01
FY03/04 Carryover Project #8 (Task 600)
Fish Tissue Metals Analysis in the Tri-State Mining Area

FY 2003/Final Report/Submitted by:Oklahoma Department of Environmental Quality
Customer Services Division - 707 North Robinson - P. O. Box 1677
Oklahoma City, OK 73101-1677 - Telephone: (405) 702-1000
Effective: July 1, 2003
Revision 2 - 12/4/07 - Approval Date:2/1/08

Acknowledgements

The Oklahoma Department of Environmental Quality wishes to thank the US Fish and Wildlife Service for their help in the collection of fish as well as advice and counsel on development of sample preparation and analysis methods for this study.

Executive Summary

The Customer Services Division (CSD) of the Oklahoma Department of Environmental Quality (ODEQ) performed a study to determine the safety of consuming fish caught in Oklahoma waters affected by runoff from the Tri-State Mining Area and the Tar Creek Superfund Site.

Responding to concerns by local residents and tribes, this study was designed to determine levels of metals in fish tissue that would be harmful to human health if consumed in excess amounts.

Local tribes from the Tar Creek area indicated traditional customs involve eating whole fish, including bones, which have been canned by means of pressure-cooking. Since metals are known to accumulate in the bones and organs of fish, there was a concern that these traditional methods of preparation would be unsafe.

Local tribes advised ODEQ they believed fish consumption rates were higher among tribal members than among the general public.

CSD field personnel worked cooperatively with the US Fish and Wildlife Service to collect fish from the Neosho and Spring Rivers and local ponds receiving mine waste runoff. The State Environmental Laboratory developed sample preparation and analysis methods specifically for this study.

CSD risk assessment personnel used EPA guidance to develop safe levels for cadmium and zinc in fish, and utilized the Integrated Exposure Uptake Biokinetic (IEUBK) Model for evaluating lead concentrations in fish that would be safe for the public to consume.

Results...

Results of this study conclude that fillets of fish caught in ponds within the Tar Creek Superfund Site and the Spring and Neosho Rivers are safe to eat at rates up to 6 8-ounce meals per month based on laboratory reporting limits.

Whole-uneviscerated and whole-eviscerated portions of all fish from the Oklahoma sections of the Spring and Neosho Rivers downstream to Grand Lake and ponds in the Tri-State Mining Area should not be consumed.

Fish from these waters have higher concentrations of lead than fish collected in a national study. The higher fish tissue lead concentrations are positively correlated (R2 = 86%) to lead concentrations in the sediments of the area waters.

A follow-up study is recommended to verify these results and to determine the downstream extent of problems. Future studies should incorporate lower analytical reporting limits.

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Background and Statement of Issues

The Tri-State Mining District located in northeast Oklahoma, southeast Kansas, and southwest Missouri was once a major provider of lead and zinc ores in the early to mid 20th century.

Since the cessation of mining in the area, the mines remain closed and abandoned. Metals located both in the mines and in waste ore on the surface can become mobilized under low pH conditions and be transported by ground and surface waters. Water has been discharging from the closed mines since the 1970’s and is a major source of contamination to Tar Creek, a tributary of the Neosho River.

The Spring and Neosho Rivers and their tributaries (particularly Tar Creek) have been impacted by runoff from these abandoned lead and zinc mines. Additionally, the percolation of rainwater through chat piles mobilizes metals into solution, which flows into local ponds, many of which are millponds at abandoned ore processing sites.

Fish caught locally in these rivers and ponds constitute a significant portion of the diets of the citizens of the area. Furthermore, area tribal members report that fish are prepared and consumed using a pressure cooker to can and preserve whole fish including bones. These methods would potentially increase the ingestion of metals that might accumulate in fish.

Additionally, local tribes advised that they believed fish consumption rates were higher among tribal members than the general public. Questions have been raised about the safety of eating fish from these waters.

The consumption of fish containing elevated levels of metals is a concern because chronic exposure to heavy metals can cause health problems. Chronic lead exposure has been linked to anemia, neurological dysfunction and renal impairment. Chronic cadmium exposure has been linked to renal damage, hypertension, and cardiovascular effects.

Although zinc is an essential nutrient required for proper growth and development, the presence of zinc can affect the body’s metabolism of other metals.

This study evaluates the potential human health effects associated with the ingestion of fish from the Tri-State Mining Area in Oklahoma. In addition, an evaluation of possible relationships between metals concentrations in fish tissue and metals concentrations in water and sediment was done.

Fish tissue concentrations were also compared to values from the National Contaminant Biomonitoring Program conducted by the U.S. Fish and Wildlife Service.

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Monitoring Methods

Sample Collection

Fish were collected from 4 ponds and 6 river sites in 2002. The river sites were evenly split with 3 sites on Spring River and 3 sites on the Neosho River.

Two of the pond sites were millponds at former ore processing locations and 2 pond sites were adjacent to and received runoff from chat piles.

The pond sites are located in the Tar Creek Superfund area while the stream sites are outside the Superfund area proper but within the larger Tri-state Mining District.

Table 1. Site Locations

Each group is listed by Site ID, Site Name, Latitude and Longitude. In this order from top to bottom

Site ID... Site Name... Latitude... Longitude...

TC-MPACP / Atlas Chat Pile Pond / 36°58.867’ / 94°48.332’

TC-MPBG / Blue Goose Mill Pond / 36°58.102’ / 94°51.784’

TC-MPNWWC / Northwest Western Chat Pile Pond / 36°59.081’ / 94°51.349’

TC-MPWCP / Western Chat Pile Mill Pond / 36°58.920’ / 94°51.436’

TC-NRCB / Neosho River at Conners Bridge / 36°47.949’ / 94°49.165’

TC-NRECC / Neosho River at Elm Creek Confluence / 36°53.470’ / 94°55.677’

TC-NRRP / Neosho River at Riverview Park / 36°51.944’ / 94°52.728’

TC-SRBH / Spring River at Blue Hole / 36°56.096’ / 94°44.765’

TC-SRMB / Spring River at Mocassin Bend / 36°52.311’ / 94°45.933’

TC-SRTB / Spring River at Twin Bridges State Park / 36°48.174’ / 94°45.213’

A total of 80 composite fish samples representing 8 species were collected using various combinations of electrofishing, gill nets, and rod and reel.

Species targeted for collection and analysis were carp, channel catfish and white crappie. At sites where those species were not available in sufficient numbers, other commonly consumed species were collected.

These include white bass, spotted bass, largemouth bass, bluegill sunfish and smallmouth buffalo. Because comparisons were to be made between different preparation methods, an attempt was made to collect consistent size ranges within species at all sites.

Laboratory Analysis

Fish collections were delivered to ODEQ’s State Environmental Laboratory where they were sorted by site, species, and size.

Fish were then sorted into composites consisting of 3 to 8 individuals with the smallest fish in the composite at least 75 percent of the length of the largest fish in the composite.

Composite samples of similar mean length were assembled for different preparation methods: fillets, whole-uneviscerated fish, and whole-eviscerated fish.

Sufficient numbers of fish were available to perform analyses using the 3 preparation methods for carp and channel catfish at the 6 river sites, white crappie at 5 of the river sites, and largemouth bass at the 4 pond sites.

In addition, 25 composite samples consisting of other commonly consumed species were assembled.

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A sample preparation technique was developed to prevent cross-contamination between samples as metals are found in both the mucous and scales of fish.

Only stainless steel cutting utensils were used and the preparation surfaces were sheeted in polyethylene. All utensils and equipment were thoroughly cleaned and polyethylene sheeting replaced between the preparation of each sample.

Fish were skinned and filleted, simply eviscerated, or kept whole as appropriate. A commercial grade food grinder with stainless steel cutting blades was used to mascerate samples. The ground tissue was then homogeneously mixed before being sent through the food grinder a second time. A subsample of the ground tissue was then collected for analysis.

A microwave digestion technique2 was developed to prepare the subsamples for analysis. One gram subsamples were digested in 10 milliliters of concentrated nitric acid (HNO3) brought to 200o C under pressure in a four-step temperature ramping process. Samples were held at 200o C for 10 minutes and then allowed to cool for 15 minutes. All tissue, including bones if present, was at that point dissolved into the HNO3. Digested sample aliquots were then diluted with ultra-pure water to a volume of 50 mls and allowed to rest.

EPA Method 200.73 for the analysis of metals was used to analyze the fish tissue samples. Digested samples were diluted again by 50 percent to create a 10% HNO3 solution just before analysis on an inter-coupled plasma (ICP) Trace® Analyzer. A 10 mil. aliquot of the digested sample was injected into the ICP and 3 readings of each element were recorded. The mean of the 3 readings as well as the standard deviation was calculated. If the percent of the standard deviation relative to the mean of the 3 readings exceeded 20 percent, the sample results were rejected. The mean of the readings was used to calculate the amount of each element in the 1-gram aliquot of digested fish flesh. This value was then converted to mg/kg units and entered into the AQUARIUS laboratory information system.

Quality Assurance

A total of 4 field replicate samples were submitted for fish. These consisted of duplicate composite samples of the same species, similar in size, collected at the same site. Each of the sample preparation methods was represented by a field replicate. Precision values were all 0 percent for cadmium (all values below the laboratory reporting limit), 7 to 14 percent for zinc, and 0 to 4 percent for lead. All precision values fall within acceptable limits for field replicate samples as outlined the Quality Assurance Project Plan4 for this study.

A total of 8 laboratory duplicate samples of fish tissue were prepared. These consisted of duplicate subsamples of the ground composited tissue. These were digested and analyzed alongside the rest of the samples. Precision values were all 0 percent for cadmium (all values below the reporting limit), 1 to 25 percent for zinc, and 0 to 18 percent for lead. All precision values fall within acceptable limits for laboratory duplicates as outlined in the Quality Assurance Project Plan for this study.

Results

Results for all analyses are included in Appendix A.

Data Analysis

Determination of Safe Consumption Levels

The determination of safe fish consumption levels for lead, zinc, and cadmium was performed using 2 different methods. Zinc and cadmium levels were determined by using methods described in the U.S. EPA document Guidance For Assessing Chemical Contaminant Data For Use in Fish Advisories5. This method utilizes Reference Dose values (RfDs) to calculate contaminant exposure levels that would likely not result in an appreciable risk of adverse heath effects over a lifetime. The level for lead was determined using EPA’s Integrated Exposure Uptake Biokinetic (IEUBK) Model for Lead6. This model considers total environmental lead exposure and predicts the blood lead levels for children up to 84 months of age. A method similar to one utilized by the Washington State Department of Health7 was used to establish the allowable levels of lead in fish tissue. Since children are more sensitive to the deleterious effects of lead, the consumption recommendations for lead are based on the protection of children. It is assumed that levels that are protective of children are also protective of adults.

To address the issue of elevated consumption rates among tribal members, safe consumption levels were calculated using two different consumption rates: 1 meal per week as the Standard Consumption Rate and 2 meals per week as the Elevated Consumption Rate.

Cadmium and Zinc

For cadmium and zinc safe consumption levels were calculated using the following equations:

Cm= (RfD x BW)/CRlim

Where

Cm = measured concentration of chemical contaminant m in a given species of fish (mg/kg)

RfD = reference dose (mg/kg-day)

BW = consumer body weight (kg)

CRlim = maximum allowable fish consumption rate (kg/d)

and:

CRlim = (CRmw x MS)/Tap

Where

CRmw = maximum allowable fish consumption rate (meals/week)

MS = meal size (kg fish/meal)

Tap = time averaging period (days/week)

Combining equations yields:

Cm = (RfD x BW x Tap)/(CRmw x MS)

Reference dose values were obtained from the EPA Integrated Risk Information System (IRIS) database8,9. Default values obtained from EPA’s Guidance For Assessing Chemical Contaminant Data For Use in Fish Advisories5 were used for body weight and meal size. Equation inputs are as follows:

Reference Dose Cadmium = 0.001mg/kg-day

Zinc = 0.3 mg/kg-day

Body weight Children = 14.5 kg (32lb)

Adults = 70 kg (154 lb)

Meal Size 0.227 kg (8 oz)

Consumption Rate Standard Rate = 1 meal/week

Elevated Rate = 2 meals/week

Time averaging Period 7 days/week

From this, the following allowable fish contaminant concentrations were calculated:

Standard Rate:

Children

Adults

Cadmium

0.45 mg/kg

2.2 mg/kg

Zinc

135 mg/kg

650 mg/kg

Elevated Rate:

Children

Adults

Cadmium

0.22 mg/kg

1.1 mg/kg

Zinc

67 mg/kg

325 mg/kg

The State Environmental Laboratory’s reporting limit for cadmium (0.30 mg/kg) is above the safe concentration calculated using the elevated consumption rate for children. Because of this, either the meal size or the consumption rate could be adjusted to determine safe levels of consumption of fish based on results at the reporting limit.

Calculations of safe consumption levels based on a fish concentration of 0.30 mg/kg are as follows:

For a meal size of 0.227 kg (8 oz):

CRmw = (RfD x BW x Tap)/(Cm x MS)=(0.001 x 14.5 x 7)/(0.30 x 0.227)= 1.5 meals/week

For a consumption rate of 2 meals per week:

MS = (RfD x BW x Tap)/(Cm x CRmw)= (0.001 x 14.5 x 7)/(0.30 x 2)= 0.169 kg (6 oz) fish meal

Lead

Safe fish concentration levels for lead were calculated using the IEUBK model which predicts the distribution of blood lead levels for children age 84 months and younger.

The model generates a protective level at which no more than 5 percent of modeled blood lead levels exceed the EPA Intervention Level10 of 10 ug/dl (micrograms/deciliter).

Blood lead concentrations above the Intervention Level indicate action should be taken to determine the cause of the elevated concentration.

This risk assessment methodology is more conservative than that used for cadmium and zinc in that total lead exposure is accounted for through estimates of exposure through soil, house dust, air, water, and diet.

EPA default values were used for all inputs into the IEUBK except for soil and house dust lead concentrations, and factors related to fish consumption and concentration.

Soil lead concentrations were determined by computing the 95% upper confidence level(UCL) of the mean of yard soil concentrations11and high access area concentrations12.

Residential yards and high access areas(HAAs) such as parks, schools and playgrounds have been sampled for lead concentration as part of the cleanup activities in the Tar Creek area.

If yard or HAA soil concentrations were found to have soil lead levels greater than 500 mg/kg, the soil was removed and replaced with low lead concentration borrow fill soil from outside the area.

Yard and HAA replacement activities are nearing completion at the time this report is being written.

Yard lead data indicate that 3257 of 7977 samples (41%) exceed 500 mg/kg.

These areas were replaced with borrow fill having a mean lead concentration of 18.1 mg/kg13.

The mean value of the yards after remediation was calculated after replacing those values greater than 500 mg/kg in the dataset with values of 18.1 mg/kg.

The resulting mean of the post-remediation yards is 140.9 mg/kg. The 95% UCL for the mean is 144.2 mg/kg.

A total of 28 high access areas were sampled in the towns of Picher, Cardin, Quapaw, Commerce, and North Miami.

Ten of the 28 eight sites (36%) averaged greater than 500 mg/kg soil lead level.

The soil at these sites was removed and replaced with borrow fill having a mean lead value of 18.1 mg/kg.

The mean value of the HAAs after remediation was calculated after replacing the values of sites that were greater than 500 mg/kg with 18.1 mg/kg.

The resulting mean of the post-remediated HAAs was 134.7 mg/kg. The 95% UCL for the mean was 163.8 mg/kg

Based on this information it was decided to use a soil concentration input of 165 mg/kg. The IEUBK default for soil concentration to house dust concentration is 0.7. Using this, the house dust concentration was calculated to be 115 mg/kg. Inputs into the IEUBK model are given in Table 2.

Table 2. IEUBK Inputs

Input - Value - Drinking Water - 4.00 ug/L (EPA default value)

Soil - 165 mg/kg (based on the 95% UCL of the mean of yard soil levels and high access area soil levels)

House Dust - 115 ug/g (based on soil level)

Paint - 0 per day (EPA default)

Maternal Blood Contribution - 2.5 ug/dl (default in the infant model)

Outdoor Air Concentration - 0.100 ug/m3 (EPA default)

Indoor Air - 30% of outdoor air concentration (EPA default)

Time Outdoors - 1 to 4 hours per day (EPA defaults based on age)

Ventilation Rates - 2 to 7 m3/day (EPA defaults based on age range)

Lung Absorption - 32 percent (EPA default)

Diet Uptake - 50% (EPA default varies slightly with age)

Water Uptake - 0.36 to 1.13 ug/day (EPA default, varies with age)

Soil and Dust Uptake - 5.1 to 5.67 ug/day (EPA default varies with age)

Percentage of Meat Intake Consisting of Locally Caught Fish

Standard Consumption Rate: 32 percent - Elevated Consumption Rate: 64 percent

(based on one or two 8-ounce meals per week as a percentage of median EPA default daily meat consumption of 101.57 g/day based on age)

The allowable lead concentration in fish was determined by setting the model inputs to those described in Table 2 and manipulating the Lead in Fish concentration to a level that results in just less than 5 percent of the target population with a blood lead level of 10 ug/dl.

For example, in the case of the Standard Consumption Rate of one 8-ounce meal per week, the model was initially run with the Percentage of Meat Intake Consisting of Locally Caught Fish input at 32 percent and the Lead in Fish concentration set to 0 mg/kg resulting in 0.44 percent of the target population with a blood lead level greater than 10 ug/dl. The Lead in Fish concentration was incrementally increased until just below 5 percent of the target population had a blood lead level of more than 10 mg/dl. That final Lead in Fish concentration was 0.36 mg/kg.

This process was repeated for an Elevated Consumption Rate of two 8-ounce meals per week of locally caught fish. The resulting allowable lead level was 0.18 mg/kg.

Allowable fish contaminant concentrations based on either one or two 8-ounce meals per week are as follows:

Contaminant / Children / Standard / Consumption / Rate / Children / Elevated Consumption / Rate / Adults / Standard / Consumption Rate / Adults / Elevated Consumption / Rate

Lead: 0.36 mg/ - 0.18 mg/kg - 0.36 mg/kg - 0.18 mg/kg

Cadmium: 0.45 mg/kg - 0.22 mg/kg - 2.2 mg/kg - 1.1 mg/kg

Zinc: 135 mg/kg - 67 mg/kg - 650 mg/kg - 325 mg/kg

As in the case of cadmium, the allowable lead in fish concentration at the Elevated Consumption Rate of two 8-ounce meals per week was less than the State Environmental Laboratory’s reporting limit of 0.25 mg/kg.

To determine a safe consumption level based on the SEL’s reporting limit, the Lead in Fish concentration was set to 0.25 mg/kg and the Percentage of Meat Intake Consisting of Locally Caught Fish input was initially set at 64 percent (two 8-ounce meals per week.)

This resulted in 7.8 percent of the target population with a blood level exceeding 10 ug/dl. The Percentage of Meat Intake Consisting of Locally Caught Fish input was then incrementally reduced until just under 5 percent of the target population had an acceptable blood lead level.

That final level was 47%.

Allowable fish consumption based on the SEL’s reporting limit of 0.25 mg/kg was calculated as follows:

CRLim = (MDI X PF X TAP X 0.0353 ounces/gram)/8 ounces/meal where

CRLim = Consumption rate in meals/month

MDI = median daily consumption of meat by children younger than 8

PF = Proportion of meat intake consisting of locally caught fish

CRLim = (101.57 g/day X 0.51 X 7 days/week X 0.0353 oz/g)/8 oz/meal= 1.5 meals/week or for a consumption rate of 2 meals per week:

MS = (CRLIM X PF X TAP X 0.0353 oz/g)/2 meals/week= (101.57g/day X 0.51 X 7 days/week X 0.0353 oz/g) / 2 meals/week= 5.9 oz. fish meal

Comparison of Collected Fish Concentrations to Allowable Levels

Fish were collected at 3 sites on Spring River, 3 sites on the Neosho River, 2 ponds near chat piles and 2 millponds at former ore processing sites.

Sample analysis was performed on whole-uneviscerated fish, whole-eviscerated fish and fillets of carp and channel catfish at the 6 river sites, white crappie at 5 of the river sites, and largemouth bass at the 4 pond sites.

In addition, 25 samples of various other commonly consumed species were performed using the various preparation methods.

Table 3 lists the percentage of samples (by preparation method and species) exceeding the allowable fish contaminant concentrations at the Standard Consumption Rate.

Table 4 lists the percentage of samples exceeding the allowable fish contaminant concentrations at the Elevated Consumption Rates.

Table 3. Percentage of Samples Exceeding Allowable Contaminant Concentration Levels at Standard Consumption Rates (1 meal per week).

Preparation


Preparation Codes:
ALL – All Sample Preparations
FL – Fillet
WE – Whole-eviscerated
WU – Whole-uneviscerated
Number of Samples

Cadmium - Children (percent exceeding 0.45 mg/kg)

Cadmium - Adults - (percent exceeding 2.2 mg/kg)

Lead - Children and Adults - (percent exceeding - 0.36 mg/kg)

Zinc - Children - (percent exceeding - 135 mg/kg)

Zinc - Adults - (percent exceeding - 650 mg/kg)

All Species
All-80-3-0-27-0-0
FL-25-0-0-0-0-0
WE-25-0-0-24-0-0
WU-30-7-0-50-0-0
Smallmouth Buffalo
All-4-0-0-100-0-0
FL-0-0-0-0-0-0
WE-0-0-0-0-0-0
WU-4-0-0-100-0-0
10
Preparation Number of Samples
Cadmium - Children-(percent exceeding 0.45 mg/kg)
Cadmium - Adults(percent exceeding 2.2 mg/kg)
Lead - Children - and Adults- (percent exceeding-0.36 mg/kg)
Zinc - Children-(percent exceeding-135 mg/kg)
Zinc - Adults -(percent exceeding 650 mg/kg)
Carp-All -18-11-0-56-00-0
FL-6-0-0-0-0-0
WE-6-0-0-67-0-0
WU-6-33-0-100-0-0
Channel Catfish -All-18-0-0-17-0-0
FL-6-0-0-0-0-0
WE-6-0-0-0-0-0
WU-6-0-0-33-0-0
Bluegill Sunfish -All-5-0-0-40-0-0
FL-1-0-0-0-0-0
WE-1-0-0-0-0-0
WU-3-0-0-66-0-0
Largemouth Bass -All-130-0-0-15-0-0
FL-4-0-0-0-0-0
WE-4-00-0-25-0-0
WU-5-0-0-20-0-0
Spotted Bass -All-3-0-0-0-0-0
FL-1-0-0-0-0-0

WE-1-0-0-0-0-0

WU-1-0-0-0-0-0

White Bass -All-2-0-0-0-0-0

FL-0-0-0-0-0-0

WE-0-0-0-0-0-0

WU-2-0-0-0-0-0

White Crappie -All-15-0-0-0-0-0

FL-5-0-0-0-0-0

WE-5-0-0-0-0-0

WU-5-0-0-0-0-0

Preparation Codes:
ALL – All Sample Preparations
FL – Fillet
WE – Whole-eviscerated
WU – Whole-uneviscerated
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Table 4. Percentage of Samples Exceeding Allowable Contaminant Concentration Levels at Elevated Consumption Rates (2 meal per week)

Preparation - Number of Samples

Cadmium - Children -(percent exceeding 0.22 mg/kg)

Cadmium - Adults -(percent exceeding-1.1 mg/kg)Lead

Children and Adults -(percent exceeding-0.18 mg/kg)

Zinc - Children -(percent exceeding-67 mg/kg)

Zinc - Adults -(percent exceeding-325 mg/kg)

All Species-All-80-6-0-36-1-0

FL-25-0-0-4-0-0

WE-25-0-0-36-0-0

WU-30-20-0-60-3-0

Smallmouth Buffalo -All-4-0-0-100-0-0

FL-0-0-0-0-0-0

WE-0-0-0-0-0-0

WU-4-0-0-100-0-0

Carp-All-18-28-0-66-6-0

FL-60-0-0-17-0-0

WE-6-000-83-000

WU-6-83-0-100-17-0

Bluegill Sunfish -All-5-0-0-40-0-0

FL-1-0-0-0-0-0

WE-1-0-0-0-0-0

WU-3-0-0-66-0-0

Channel Catfish -All-18-0-0-28-0-0

FL-6-0-0-0-0-0

WE-6-0-0-33-0-0

WU-6-0-0-50-0-0

Largemouth Bass -All-13-0-0-23-0-0
FL-4-0-0-0-0-0
WE-4-0-0-50-0-0
WU-5-0-0-20-0-0
Spotted Bass - All 3 0 0 0 0 0
FL 1 0 0 0 0 0
WE 1 0 0 0 0 0
WU 1 0 0 0 0 0
White Bass - All 2 0 0 0 0 0
FL 0 0 0 0 0 0
WE 0 0 0 0 0 0
WU 2 0 0 0 0 0 12
Preparation Number of Samples
Cadmium Children (percent exceeding 0.22 mg/kg)
Cadmium Adults (percent exceeding 1.1 mg/kg)
Lead Children and Adults (percent exceeding 0.18 mg/kg)
Zinc Children (percent exceeding 67 mg/kg)
Zinc Adults (percent exceeding 325 mg/kg)
White Crappie - All 15 0 0 13 0 0
FL 5 0 0 0 0 0
WE 5 0 0 0 0 0
WU 5 0 0 40 0 0
Preparation Codes:

ALL – All Sample Preparations

FL – Fillet

WE – Whole - eviscerated

WU – Whole - uneviscerated

From the two tables the following can be discerned:

A single fillet sample of carp exceeded allowable levels for lead and the Elevated Consumption Rate.

No other fillet portions of any fish exceeded laboratory reporting limits. No fillet portions exceed allowable levels for any metal tested at the Standard Consumption Rate.

Allowable levels for cadmium at the Elevated Consumption Rate for children were exceeded only in samples of whole-uneviscerated carp.

The allowable level for Zinc at the Elevated Consumption Rate for Children was exceeded by a single whole fish sample.

Allowable levels for lead at the elevated consumption rate were exceeded in 36 percent of all whole-eviscerated samples and 60 percent of all whole fish samples.

Allowable levels of lead at the Standard Consumption Rate of 1 meal per week were exceeded in 5 species:

33 percent of whole-uneviscerated channel catfish
17 percent of whole-eviscerated channel catfish
100 percent of whole-uneviscerated smallmouth buffalo BR> 100 percent of whole-uneviscerated carp
67 percent of whole-eviscerated carp
66 percent of whole-uneviscerated bluegill
20 percent of whole-uneviscerated largemouth bass
25 percent of whole-eviscerated largemouth bass
Allowable levels of lead at the Elevated Consumption Rate of 2 meals per week were exceeded in 5 species:
50 percent of whole-uneviscerated channel catfish
33 percent of whole-eviscerated channel catfish
20 percent of whole-uneviscerated largemouth bass
50 percent of whole-eviscerated largemouth bass
66 percent of whole-uneviscerated bluegill sunfish
40 percent of whole-eviscerated white crappie
17 percent of carp fillets
83 percent of whole-eviscerated carp
100 percent of whole-uneviscerated carp
100 percent of whole-uneviscerated smallmouth buffalo

Based on this information ODEQ recommends children living in the Tar Creek area consume no more than six 8-ounce fillet meals per month of fish caught in ponds within the Tar Creek Superfund Site and the Spring and Neosho Rivers above Grand Lake.

All adults and children should avoid eating all species of whole-eviscerated or whole-uneviscerated fish caught in these waters.

Comparison of Preparation Methods

Fish samples were analyzed using 3 different preparation methods: fillets, whole-eviscerated, and whole-uneviscerated.

There are 23 instances in the data set where analyses were performed using the three preparation methods on the same species from the same site.

These data were pooled and statistical tools were applied to determine if significant differences exist between the preparation methods in relation to tissue metals concentration.


NOTE: Boxplot construction legends go to {http://www.deq.state.ok.us/LPDnew/Tarcreek/GovrTaskForce/TarCreekFishReport.pdf) beginning on page 14 on.
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These plots indicate some differences between the whole-eviscerated and the whole-uneviscerated preparations while illustrating generally lower concentrations in fillet samples. To confirm these observations, a Kruskal-Wallis test14 was applied to the data. The Kruskal-Wallis test uses median values and average ranks to determine if the observed differences in 2 or more populations are statistically significant, that is, of a greater magnitude than would be expected to occur by chance. The Kruskal-Wallis test is an extension of the Wilcoxon Rank Sum test and does not require the distribution of the data to be normal or symmetric. For this test all values below the laboratory reporting limit were set to one-half the reporting limit. The results are as follows:

H0: The medians of the preparation methods are all equal.

HA: At least one of the medians is larger or smaller than at least one of the other medians.

a = 0.05

For Cadmium:Preparation-Number of Samples-Median-Average Rank-Z Statistic

Fillet -23-0.15-32.5-0.73

Whole Eviscerated-23-0.15-32.5//-0.73

Whole Uneviscerated-23-0.15-40.0-1.46

Overall-69-35.0

H Statistic = 10.61

Degrees of Freedom = 2 p = 0.005 (adjusted for ties)

For Lead:Preparation - Number of Samples-Median-Average Rank-Z Statistic

Fillet -21-0.125-22.6//-2.87

Whole Eviscerated-21-0.125-35.0-0.93

Whole Uneviscerated-21-0.250-38.6-1.93

Overall-63-32.0

H Statistic = 12.14

Degrees of Freedom = 2

p = 0.002 (adjusted for ties)

16pagebreak

For Zinc: Preparation-Number of Samples-Median-Average Rank-Z Statistic

Fillet-23-6.54-13.0//-6.45

Whole - Eviscerated-23-21.2-45.9-3.18

Whole- Uneviscerated-23-19.9-46.5-3.27

Overall-69-35.0 - H Statistic = 41.65 - Degrees of Freedom = 2 p = < 0.001

These results indicate that in each case the null hypothesis is rejected in favor of the alternative hypothesis: at least one of the preparation methods differs from at least one of the other preparation methods. The Z statistic indicates how the mean rank for the group differs from the mean rank for all the observations.

From this information and the boxplots one can conclude that in the case of cadmium, the whole-uneviscerated portion is significantly higher than both fillets and whole-eviscerated preparations. For lead, fillet concentrations are significantly less than concentrations in whole-uneviscerated and whole-eviscerated portions. For zinc, fillet concentrations are also significantly lower than both whole-eviscerated and whole-uneviscerated portions.

Relationship of Tissue Concentrations to Sediment and Water Concentrations.

The relationship of tissue metals concentrations to water and sediment levels was explored through linear regression analysis. To be consistent and to provide the most unbiased data, metals concentrations from whole-uneviscerated carp samples (the response variable) were plotted versus water and sediment concentrations (predictor variables). The regression equation was computed along with values for R2 and S. R2 is the percentage of variation in the response variable due to the predictor variable and S is an estimator of the standard deviation around the regression line.

Regression analysis was not run for total and dissolved fractions of lead and cadmium in water because all results were less than the reporting limit. For all other fractions, values less than the reporting limit were set to one-half of the reporting limit.

Of the various combinations of tissue concentration vs. media concentration, only lead in fish vs. lead in sediment yielded a result indicating a solid relationship between the two. The results are given in Table 3 and shown in Figure 5.

17pagebreak

Table 5. Regression Results - Test - Regression Equation - S - R2

Cadmium in Fish vs. Cadmium in Sediment

Cd(fish) = 0.253 + 0.069 Cd(Sed)-0.231-31.0 %

Lead in Fish vs.Lead in Sediment - Pb(fish) = 0.132 + 0.063 Pb(Sed) - 0.497 - 86.3 %

Zinc in Fish vs.Dissolved Zinc in Water - Zn(fish) = 50.3 + 0.133 Zn(Diss) - 9.175 - 20.1 %

Zinc in Fish vs.Total Zinc in Water - Zn(fish) = 52.1 + 0.056 Zn(Tot) - 9.170 - 20.2 %

Zinc in Fish vs.Zinc in Sediment - Zn(fish) = 53.2 + 0.010 Zn(Sed) - 9.594 - 12.6 %

Comparison to Historic Data

ODEQ intended to compare data collected for this study to data collected from the region in 1982 by the Oklahoma State Department of Health15 to determine if tissue values were changing over time. However, an examination of the 1982 data revealed that all samples were fillets analyzed only for lead and all results were below the reporting limit at the time of 1.0 mg/kg compared to a reporting limit of 0.25 mg/kg for this study. This makes a comparison of the 2 time periods unsuitable due to the differing reporting limits and the censoring of all 1982 data.

Comparison to National Data

Whole -uneviscerated fish data from this study was compared to data collected for the U.S. Fish and Wildlife Service National Contaminant Biomonitoring Program16 (NCBP) to determine if tissue metals concentrations in fish collected from the Tri-State Mining District differed from values of fish collected nationwide. The NCBP data was queried to select concentration values representing the same species and size ranges within those species as was collected for the Tri-State Mining District study. Data were labeled as to study and were pooled into a single database.

One of the difficulties in comparing the 2 data groups was the difference in reporting limits for lead and cadmium. The NCBP study used varying reporting limits of 0.001 to 0.05 mg/kg for cadmium and 0.008 to 0.1 mg/kg for lead. The Tri-State Mining District study used reporting limits of 0.3 mg/kg for cadmium and 0.25 mg/kg for lead. For this comparison, all cadmium values below 0.3 mg/kg were set to 0.29 mg/kg and all lead values below 0.25 mg/kg were set to 0.24 mg/kg. The Kruskal-Wallis test was run on the pooled data to determine if there were statistical differences between the 2 study populations.

The results are as follows and boxplots illustrating the data are as follows:

H0: The medians of the 2 study populations are equal.

HA: One of the medians is larger or smaller than the other median.

a = 0.05

For Cadmium: Preparation - Number of Samples - Median - Average Rank - Z Statistic
NCBP -409-<0.30-217.2/-1.41
Tri-State -29-<0.30-251.6
Overall -438-219.5
H Statistic = 1.99
Degrees of Freedom = 1
p = 0.158
H Statistic(adjusted for ties) = 27.13
Degrees of Freedom = 1
p = <0.001
19pagebreak
Conclusions and Recommendations

In comparison to fish collected in the National Contaminant Biomonitoring Program, the fish from Oklahoma waters in the Tri-State Mining Area have lead concentrations higher than one would expect to find in fish from waters elsewhere in the United States. The elevated levels of lead in the fish positively correlate to the concentration of lead in the sediments of these waters. The consumption of whole-eviscerated or whole-uneviscerated fish from these waters is discouraged. However, the consumption of fillets from fish in this area is safe at rates at least as high as six 8-ounce meals per month based on the laboratory reporting limit.

Further study is needed to validate these findings and to determine the downstream extent of the metals uptake in fish species. Specifically, fish from Grand Lake need to be tested for tissue lead concentrations. Additionally, due to local fish harvesting practices, other bottom dwelling fish such as various species of suckers should be included in a follow-up study. Laboratory analytical techniques should be modified to lower reporting limits to levels in the 0.15 mg/kg range for lead and cadmium.

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References

1. Oklahoma Department of Environmental Quality. 2002. Standard Operating Procedure for the Tri-State Mining Area Fish Collection and Preparation. Customer Service Division, Oklahoma Department of Environmental Quality, Oklahoma City, OK.

2. CEM Corporation. 1999. Mars Microwave Accelerated Reaction System Operation Manual, Microwave Sample Preparation Note: 5BI-8. CEM Corporation, Mathews, NC.

3. U.S. EPA. 1991. EPA Method 200.7 Revision 3.3, Determination of Metals and Trace Elements By Inductively Coupled Plasma-Atomic Emission Spectroscopy. U.S. EPA, Washington, DC.

4. Oklahoma Department of Environmental Quality. 2001. Fish Tissue Analysis in the Tri-State Mining Area Quality Assurance Project Plan. Customer Service Division, Oklahoma Department of Environmental Quality, Oklahoma City, OK.

5. U.S. EPA. 2000. Guidance For Assessing Chemical Contaminant Data For Use in Fish Advisories, Volume II: Risk Assessment and Fish Consumption Limits. U.S. EPA, Washington, DC.

6. U.S. EPA. 1994. Guidance Manual For The Integrated Exposure Uptake Biokinetic Model for Lead in Children. U.S. EPA, Washington, DC.

7. Washington State Department of Health. 2001. Evaluation of Cadmium, Lead, and Zinc Contamination of Spokane River Fish. Spokane, Washington.

8. U.S. EPA. 1994. IRIS: Cadmium, CASRN 7440-43-9. U.S. EPA, Washington, DC.

9. U.S. EPA. 1992. IRIS: Zinc and Compounds, CASRN 7440-66-6. U.S. EPA, Washington, DC.

10. U.S. CDC (Centers for Disease Control). 1985. Preventing lead poisoning in young children: a statement by the Centers for Disease Control. CDC report no. 99-2230, Atlanta, GA.

11. Morrison Knudson Corporation. 1999. Data from residential yard samples in the Tar Creek Superfund area. Boise, ID.

12. Ecology & Environment, Inc. 1995. Tar Creek High Access Areas. Summary of Response Activities. Dallas, TX.

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13. Cates, David, 2003. Background concentrations of soils in Ottawa County, Memo to Tar Creek File. ODEQ, Oklahoma City, OK.

14. Kruskal, W.H. 1952. A non-parametric test for the several sample problem. The Annuls of Mathematical Statistics, 23, 525-540(5.2).

15. Oklahoma State Department of Health. 1982. An Environmental Health Evaluation of the Tar Creek Area. OSDH. Oklahoma City, OK.

16. Schmitt, C.J. and Brumbaugh, W.G. 1990. National Contaminant Biomonitoring Program: concentrations of arsenic, cadmium, copper, lead, mercury, selenium, and zinc in fresh water fishes of the United States, 1976-1984. Archives of Environmental Contamination and Toxicology, 19: 731-747. (Data online at http://www.cerc.usgs.gov/data/ncbp/fish.htm

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NOTICE: To see Appendix A- : Data Tables/Site/Per Species go to (http://www.deq.state.ok.us/LPDnew/Tarcreek/GovrTaskForce/TarCreekFishReport.pdf) dissolved oxygen-ph-specific conductance-water temperature-total alkalinity-total hardness-solids suspended-dissolved cadmium-total cadmium-dissolved lead- total lead-total zinc-cadmium sediment-lead sediment-zinc sediment-mean length in inches-mean weight in grams-preparation-qa category-cadmium in fish-lead in fish-zinc in fish

STATE OF OKLAHOMA
DEPARTMENT OF ENVIRONMENTAL QUALITY
CUSTOMER SERVICES DIVISION (DEQ)

FY 2006/2007 Section 106 Water Quality Management Program

I-006400-01

FY 06 Increase Workplan Task 600

Fish Tissue Metals Analysis in the Tri-State Mining Area

Follow-up Study

FY 2006

Final Report

Submitted by: Oklahoma Department of Environmental Quality

Customer Services Division

707 North Robinson - P. O. Box 1677 - Oklahoma City, OK 73101-1677 - Telephone: (405) 702-1000

Effective: September 14, 2007

Revision 2

12/4/07

Page 2 of 45

Approval Date:2/1/08

Acknowledgements

The Oklahoma Department of Environmental Quality wishes to thank the Oklahoma Department of Wildlife Conservation and the Peoria Tribe of Indians of Oklahoma for assistance in the collection of fish. In addition, ODEQ wishes to thank the U.S. Bureau of Indian Affairs for their assistance in gaining access to collection sites as well as the Agency for Toxic Substances and Disease Registry for providing input and review.

Revision 2

12/4/07

Page 3 of 45

Approval Date:2/1/08

Click On The Tar Creek Superfund Juggler'To Go Back To The Top Of These Documents

Executive Summary

The Customer Services Division (CSD) of the Oklahoma Department of Environmental Quality (ODEQ) performed a followup study to confirm results and answer further questions as a result of a 2003 ODEQ report concerning the safety of consuming fish caught in Oklahoma waters affected by runoff from the Tri-State Mining District and the Tar Creek Superfund Site. Responding to concerns by local residents and tribes, this study was designed to determine levels of metals in fish tissue that would be harmful to human health if consumed in excess amounts. Local tribes from the Tar Creek area indicated traditional customs involve eating fish preparations that include bones, which include fish canned by means of pressure-cooking and the preparation of non-game fish for which it is difficult to obtain boneless fillets. Since metals are known to accumulate in the bones and organs of fish, there was a concern that these traditional methods of preparation would be unsafe. Local tribes advised ODEQ they believed fish consumption rates were higher among tribal members than among the general public.

CSD field personnel worked to collect fish from the Neosho and Spring Rivers, Grand Lake, and local ponds in Ottawa County receiving mine waste runoff. Paddlefish were also provided by the Peoria Tribe and Oklahoma Department of Wildlife Conservation (ODWC). The State Environmental Laboratory developed sample preparation and analysis methods specifically for this study. CSD risk assessment personnel used EPA guidance to develop safe consumption levels for cadmium and zinc in fish, and utilized the Integrated Exposure Uptake Biokinetic (IEUBK) Model for evaluating lead concentrations in fish that would be safe for the public to consume.

The scope of this study was expanded to include Grand Lake which is utilized by many people living outside the Tar Creek area. The IEUBK model used to develop consumption advisory levels evaluates exposure to lead from multiple sources. Because people living in the Tar Creek area are exposed to higher background levels of lead than citizens living outside the area, advisory levels were determined for both groups using different exposure assumptions.

Consumption of some preparations of fish caught in waters affected by contaminated runoff from abandoned lead and zinc mines in the Oklahoma portion of the Tri-State Mining District have levels of lead that could potentially cause adverse health effects.

Carcass preparations of (1) game fish and sunfish from Mill Ponds, (2) non-game fish from the Neosho River, (3) catfish, non-game fish and sunfish in the Spring River, and (4) non-game fish from Grand Lake have lead concentrations high enough to warrant recommendations for Tar Creek area residents to restrict consumption. Additionally, fillet samples in non-game fish from Spring River warrant similar recommendations for Tar Creek area residents

Carcass preparations of (1) sunfish for Mill Ponds, (2) non-game fish and sunfish from the Spring River, and (3) non-game fish from Grand Lake have lead concentrations high

Revision 2 - 12/4/07 - Page 4 of 45 - Approval Date:2/1/08

enough to warrant recommendations for non-residents of the area to restrict consumption.

Flesh and roe preparations of paddlefish from the area have low concentrations of lead, cadmium, and zinc. While it was unclear if skinless fillets have higher levels of lead and cadmium, skinless fillets have lower levels of zinc. A conservative approach to reducing one’s exposure would be to only consume skinless fillets.

Background and Statement of Issues

The Tri-State Mining District located in northeast Oklahoma, southeast Kansas, and southwest Missouri was once a major provider of lead and zinc ores from the late 19th to the mid 20th century. Since the cessation of mining in the area, the mines remain closed and abandoned. Metals located both in the mines and in waste materials on the surface can become mobilized and transported by ground and surface waters. Water discharging from the closed mines and surface materials is a major source of contamination to Tar Creek, the Neosho and Spring Rivers, ponds within the Superfund area and, ultimately, Grand Lake.

The Spring and Neosho Rivers and their tributaries (particularly Tar Creek) have been impacted by runoff from these abandoned lead and zinc mines. Additionally, the percolation of rainwater through chat piles can transport metals laden materials into local ponds, many of which are millponds at abandoned ore processing sites. Fish caught locally in the rivers, ponds, and Grand Lake make up a significant portion of the diets of some citizens in the area. Furthermore, area tribal members report that fish are prepared and consumed using techniques that result in the potential ingestion of bone material. These preparation techniques could increase their exposure to metals that might accumulate in fish. Additionally, local tribes advised that they believe fish consumption rates are higher among tribal members than the general public. Questions have been raised about the safety of eating fish from these waters.

The consumption of fish containing elevated levels of metals is a concern because chronic exposure to heavy metals can cause health problems. Chronic lead exposure has been linked to anemia, neurological dysfunction and renal impairment. Chronic cadmium exposure has been linked to renal damage, hypertension, and cardiovascular effects. Although zinc is an essential nutrient required for proper growth and development, the presence of excess zinc can affect the body’s metabolism of other metals (e.g. copper), especially when combined with zinc nutritional supplements.

In 2003, the ODEQ conducted a study1 that examined metals concentrations in fish tissue from the Spring and Neosho Rivers, as well as mill ponds in the Tar Creek Superfund site. That study recommended that people living in the Tar Creek area not consume portions of fish that contained bones. It also was determined that fillets were safe to consume at rates up to six 8-ounce meals per month. The ODEQ was unable to recommend higher consumption rates for boneless fillet portions because analytical reporting limits for lead were not low enough to make that determination.

The findings of the 2003 report identified several areas requiring follow-up study. These included repeating the study to confirm the initial findings, extending the study downstream into Grand Lake, more emphasis on species likely to be consumed in a manner that would increase metals exposure, and the use of lower analytical reporting limits to allow for refined consumption recommendations. This study addresses those issues.

Revision 2 - 12/4/07
Page 8 of 45
Approval Date:2/1/08

The scope of this study was expanded to include Grand Lake which is utilized by many people living outside the Tar Creek area. The IEUBK model used to develop consumption advisory levels evaluates exposure to lead from multiple sources. Because people living in the Tar Creek area are exposed to higher background levels of lead than citizens living outside the area, advisory levels were determined for both groups using different exposure assumptions.

Monitoring Methods - Sample Collection

The 2003 study examined fish that were collected from 4 ponds and 6 river sites. The river sites were evenly split with 3 sites on Spring River and 3 sites on the Neosho River. Two of the pond sites were millponds at former ore processing locations and 2 pond sites were adjacent to and received runoff from chat piles. The ponds are located in the Tar Creek Superfund area while the stream sites are outside the Superfund area proper but within the larger Tri-state Mining District. This study repeats sample collections at those same sites for the rivers and ponds. In addition, fish were collected at 7 sites extending throughout the length of Grand Lake and 1 site located in the Grand Neosho River directly below Pensacola Dam which impounds Grand Lake.

In addition, paddlefish fillet samples collected by the Peoria Tribe and the Oklahoma Department of Wildlife Conservation (ODWC) were analyzed and used for this study. The paddlefish provided by the Peoria Tribe were collected in May, 2006 in the Spring and Neosho Rivers. The paddlefish provided by ODWC were collected in January and February of 2007 in Grand Lake.

Analysis was performed on composite samples of fillet and carcass preparations of the ODEQ collected fish. The fillet samples were generally boneless and skinless. However, a small number of boneless, scaled, skin-on fillet samples were analyzed to compare to the more prevalent boneless, skinless preparations. Carcass preparations consisted of scaled, skin-on, headless, eviscerated fish.

Because of the size and availability of paddlefish, analysis was performed on individual fish. Paddlefish have a cartilaginous bone structure that makes boneless fillet portions difficult to obtain. Preparations consisted of skinless cross-cut sections laterally across the fish with the vertebrae removed. For the purposes of this report these preparations will be referred to as “skinless fillets”. In addition, analysis was performed on 8 samples of roe (eggs) from the individual paddlefish.

A total of 195 composite and individual fish samples representing 15 species were collected for this study. ODEQ collected stream and lake samples by electrofishing and the ponds by rod and reel. ODWC collected paddlefish from Grand and Hudson Lakes by electrofishing. The Peoria Tribe collected paddlefish from the Spring and Neosho Rivers by rod and reel.

A maximum of 5 species was collected at each site. Limited species were present in the pond sites. Emphasis was placed on species that are commonly consumed including non-game species that local fishing practices such as gigging target. These would include paddlefish, carp, smallmouth buffalo, and redhorse sucker. Consistent size ranges within species were collected at each site.

Laboratory Analysis

Fish collections were delivered to ODEQ’s State Environmental Laboratory where they were sorted by site, species, and size. Fish were then sorted into composites consisting of 3 to 5 individuals with the smallest fish in the composite at least 75 percent of the length of the largest fish in the composite. Composite samples of similar mean length were assembled for the different preparation methods: boneless skinless fillets, boneless skin-on fillets and carcasses.

A sample preparation technique2 developed for the 2003 study was used to prevent cross-contamination between samples as metals are found in both the mucous and scales of fish. Only stainless steel cutting utensils were used and the preparation surfaces were sheeted in polyethylene. All utensils and equipment were thoroughly cleaned and polyethylene sheeting replaced between the preparations of each sample.

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Fish were filleted and skinned, scaled and filleted, or eviscerated and the head removed by cutting anterior to the gill plate as appropriate. A commercial grade food grinder with stainless steel cutting blades was used to mascerate samples. The ground tissue was then homogeneously mixed before being sent through the food grinder a minimum of three more times. A subsample of the ground tissue was then collected for analysis.

A 1 gram aliquot was digested in accordance with EPA Method 200.33. Digestion was accomplished by adding concentrated nitric acid (HNO3) and heating to a temperature of 95 ºC for 1 hour before allowing the digestate to cool. This process was repeated 6 times until all tissue, including bone material, was in solution. The samples were then diluted with 50 ml of ultrapure water and allowed to settle overnight before filtering with a 2 micron Filtermate device. Laboratory fortified matrix (LFM) and laboratory fortified blank (LFB) samples were prepared appropriately for internal quality assurance and control measures. A 1 ml. aliquot of the digestate was added to ultrapure water along with an internal standard solution to complete the sample preparation.

In accordance with EPA Method 200.74, a 10 ml aliquot was injected into inductive-coupled plasma mass spectrometer (ICP-MS) and 3 readings of each element were recorded. The mean of the 3 readings as well as the standard deviation was calculated. The mean of the readings was used to calculate the amount of each element in the 1 gram aliquot of digested fish flesh. This value was then converted to mg/kg units and entered into the AQUARIUS laboratory information system.

By using a different digestion technique that allowed a larger sample aliquot and more sensitive instrumentation, analytical reporting limits were improved by nearly an order of magnitude over the 2003 study for cadmium and lead. Reporting limits were improved 3 fold for zinc. A comparison is shown in Table 3.

Table 2. Comparison of 2003 and 2007 Analytical Reporting Limits

Metal - 2003 Study (mg/kg) - 2007 Study

Cadmium - 0.3 - 0.05

Lead - 0.25 - 0.05

Zinc - 0.3 - 0.1

Quality Assurance

A total of 12 field replicate samples were submitted for fish. These consisted of duplicate composite samples of the same species, similar in size, collected at the same site. There were 4 replicates of carcass samples and 8 replicates of skinless fillet samples. All precision values for lead and cadmium were within acceptable limits. For zinc, 3 of the 4 precision values for carcass samples and 2 of 8 values for boneless fillet samples fell outside acceptable limits as outlined in the Quality Assurance Project Plan5 for this study. Because it was determined that even with the increased variance in

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precision, zinc is not the determining factor with regards to safe consumption levels. The project manager chose to accept and report the zinc values in this study.

A total of 21 laboratory duplicate samples of fish tissue were prepared. These consisted of duplicate subsamples of the ground composited tissue. All precision values fall within acceptable limits for laboratory duplicates as outlined in the Quality Assurance Project Plan for this study.

Results

Results for all analyses are included in Appendix A - Data Analysis

Determination of Safe Consumption Levels

Allowable contaminant concentrations for various consumption rate scenarios were calculated based on methods outlined in the 2003 Tar Creek Fish study. The determination of safe fish consumption levels for lead, zinc, and cadmium was performed using 2 different methods. Zinc and cadmium levels were determined by using methods described in the U.S. EPA document Guidance For Assessing Chemical Contaminant Data For Use in Fish Advisories6. This method utilizes Reference Dose values (RfDs) to calculate contaminant exposure levels that would likely not result in an appreciable risk of adverse heath effects over a lifetime. The level for lead was determined using EPA’s Integrated Exposure Uptake Biokinetic (IEUBK) Model for Lead7. This model considers total environmental lead exposure and predicts the blood lead levels for children up to 84 months of age.

A method similar to one utilized by the Washington State Department of Health8 was used to establish the allowable levels of lead in fish tissue. Since children are more sensitive to the deleterious effects of lead, the consumption recommendations for lead are based on the protection of children. It is assumed that levels that are protective of children are also protective of adults.

Allowable concentrations were calculated based on consumption rates of 8-ounce meals per month for both children and adults. Consumption rates for children up to 100 percent of the national mean meat consumption for children7 (109 oz./month) were used. Consumption rates of up to 16 meals per month were calculated for adults for cadmium and zinc.

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Cadmium and Zinc

For cadmium and zinc, safe consumption levels were calculated using the following equations:

Cm= (RfD x BW)/CRlim
Where
Cm = allowable concentration of chemical contaminant m in a given species of fish (mg/kg)
RfD = reference dose (mg/kg-day)
BW = consumer body weight (kg)

CRlim = maximum allowable fish consumption rate (kg/d)
and:
CRlim = (CRmm x MS)/Tap
Where
CRmm = maximum allowable fish consumption rate (meals/month)
MS = meal size (kg fish/meal)
Tap = time averaging period (days/month)
To calculate the allowable fish consumption rate (in meals/month) based on the concentration of cadmium or zinc in fish, the previous formula is rearranged to:
Cm = (RfD x BW x Tap)/(CRmm x MS)
Reference dose values were obtained from the EPA Integrated Risk Information System (IRIS) database9,10. Default values obtained from EPA’s Guidance For Assessing Chemical Contaminant Data For Use in Fish Advisories5 were used for body weight and meal size. Equation inputs are Illustrated in Table 3.
Table 3. Inputs for calculating acceptable consumption levels for cadmium and zinc.
Input - Value - Reference Dose
Cadmium = 0.001mg/kg-day - Zinc = 0.3 mg/kg-day - Body Weight
Children = 14.5 kg (32lb) - Adults = 70 kg (154 lb)
Meal Size - 0.227 kg (8 oz) - Consumption Rate - 1 to 16 meals/month
Time Averaging Period - 30.42 days/month
Allowable levels in fish tissue for zinc and cadmium are illustrated in Table 4.
Table 5. IEUBK Inputs
Input Value Drinking Water
4.00 ug/L (EPA default value)
Soil
Residents - 165 mg/kg (based on the 95% UCL of the mean of yard soil levels and high access area soil levels)
Non-residents – 16 mg/kg (national background soil level)
House Dust
Residents - 115 ug/g (based on soil level)
Non-residents – 11.2 (based on soil level)
Paint
0 per day (EPA default)
Maternal Blood Contribution
2.5 ug/dl (default in the infant model)
Outdoor Air Concentration
0.100 ug/m3 (EPA default)
Indoor Air
30% of outdoor air concentration (EPA default)
Time Outdoors
1 to 4 hours per day (EPA defaults based on age)
Ventilation Rates
2 to 7 m3/day (EPA defaults based on age range)
Lung Absorption - 32 percent (EPA default)
Diet Uptake - 50% (EPA default varies slightly with age)
Water Uptake - 0.36 to 1.13 ug/day (EPA default, varies with age)
Soil and Dust Uptake - 5.1 to 5.67 ug/day (EPA default varies with age)
Percentage of Meat Intake Consisting of Locally Caught Fish
7.34 to 100 percent (based on one to sixteen 8-ounce meals per month as a percentage of median EPA default daily meat consumption of 101.57 g/day based on age)
The allowable lead concentration for a given meals-per-month scenario was
Lead
Allowable concentration levels for lead based on various consumption rates were derived using EPA’s Integrated Exposure Uptake Biokinetic (IEUBK) model for assessing exposures in children from multiple sources. The model generates a protective level at which no more than 5 percent of modeled blood lead levels exceed the EPA Intervention Level11 of 10 ug/dl (micrograms/deciliter). Blood lead concentrations above the Intervention Level indicate action should be taken to determine the cause of the elevated concentration. This risk assessment methodology is more conservative than that used for cadmium and zinc in that total lead exposure is accounted for through estimates of exposure from soil, house dust, air, water, and diet. EPA default values were used for all inputs to the IEUBK except for soil and house dust lead concentrations, and factors related to fish consumption and concentration.

The soil concentration used for Tar Creek area residents in the IEUBK was 165 mg/kg. This reflects the 95th upper confidence level of the mean lead concentration of residential yards and high access areas in the Tar Creek Area after remediation efforts were concluded12, 13, 14. The IEUBK default ratio is 0.7 for soil concentration to house dust concentration. Using this ratio, the house dust concentration input was calculated to be 115 mg/kg. These values were used in both the 2003 and 2007studies. The soil concentration value used for non-residents was 16 mg/kg which is reported as the national background soil level 15. This yielded a house dust value of 11.2 m/kg. IEUBK inputs are shown in Table 5.

The allowable lead concentration for a given meals-per-month scenario was determined by setting the consumption rate as a percentage of total meat consumption and varying the fish tissue concentration value to a level that resulted in just less than five percent of the target population with a blood lead level of 10 ug/dl.

For example, a consumption rate of one 8-oz meal per month equals 7.34 percent of the average meat consumption for children. The model was initially run with this value in the Percentage of Meat Intake Consisting of Locally Caught Fish input and the Lead in Fish concentration set to 0 mg/kg resulting in 0.44 percent of the target population with a blood lead level greater than 10 ug/dl. The Lead in Fish concentration was incrementally increased until just below 5 percent of the target population had a blood lead level of more than 10 mg/dl. That final Lead in Fish concentration was 1.59 mg/kg. This means that fish with lead levels above 1.6 mg/kg are a concern for children who consume up to 7 percent of their meat as locally caught fish. The process was repeated for each consumption rate scenario up to the mean monthly meat consumption for children of 109 oz.

Sample Results

A total of 195 samples representing 15 species of fish were collected at 3 sites on Spring River, 3 sites on the Neosho River, 2 ponds receiving runoff from chat piles, 2 millponds at former ore processing sites, 7 sites in the main body of Grand Lake, and 1 site on the Grand Neosho River directly downstream of Grand Lake. Sample analysis was performed on preparations of boneless skinless fillets, scaled headless skin-on eviscerated carcasses, boneless scaled skin-on fillets, and roe (eggs).

All sample results can be found in Appendix A.

Lead

Table 7

lists the number of samples as well as minimum, maximum and mean values for lead by species, preparation, and site type. Mean values were calculated by substituting one half the analytical reporting limit for results less than the reporting limit. For this grouping, the Grand Neosho River site was included with the Grand Lake sites.

Mean lead values ranged from < 0.05 mg/kg to 0.74 mg/kg. The highest concentrations were found in carcass preparations of Millpond sunfish species and carcass preparations of carp and buffalo from the Spring River. Skinless fillet preparations

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were below the analytical reporting limit of 0.05 mg/kg except for Millpond sunfish, Spring River carp and drum, and Neosho River smallmouth buffalo.. All samples of Paddlefish eggs were below the reporting limit. Table 7. Sample values for lead by species, preparation, and site type. Cadmium

Table 8

lists the number of samples as well as minimum, maximum and mean values for cadmium by species, preparation, and site type. Mean values were calculated by substituting one half the analytical reporting limit for results less than the reporting limit. For this grouping, the Grand Neosho River site was included with the Grand Lake sites.

Mean cadmium values ranged from < 0.05 mg/kg to 0.23 mg/kg. The highest concentrations were found in carcass preparations of Spring River carp. All fillet and egg sample preparations were below the analytical reporting limit.

Zinc

Table 9

lists the number of samples as well as minimum, maximum and mean values for zinc by species, preparation, and site type. Mean values were calculated by substituting one half the analytical reporting limit for results less than the reporting limit. For this grouping, the Grand Neosho River site was included with the Grand Lake sites.

Mean zinc values ranged from 1.6 mg/kg to 29.6 mg/kg. The highest concentrations were found in carcass preparations of Neosho River, Spring River, and Grand Lake carp as well as carcass preparations of green and bluegill sunfish from the Millponds.

Comparison of Results to Consumption Rate Levels

For the evaluation of sample results in relation to consumption rate levels, samples were combined into species groupings and evaluated by sample preparation and site type. Species groupings are shown in Table 10.

A comparison of mean metals concentrations of the various preparations of species groups by site to calculated consumption limit levels is provided in Table 11. Mean values were calculated by substituting one half the analytical reporting limit for results less than the reporting limit.

Our evaluation shows the following:

consumption limit levels for several group means were exceeded for lead and in 1 instance cadmium. No group means exceed the consumption limits for zinc.

skinless fillet fish from mill ponds, the Neosho River, and the Grand Lake are safe to eat. Consumption of fish from these waterbodies does not need to be limited if the fish are filleted and the skin removed.

skinless fillet fish from the Spring River are safe to eat except for non-game fish (carp, freshwater drum, redhorse sucker, smallmouth buffalo). Consumption should be limited to no more than nine 8 oz meals per month of skin-less non-game fish for people living in the Tar Creek area.

the consumption of skin-on non-game fish should be limited depending upon where they are caught. Table 10 shows the allowable number of meals.

the consumption of sunfish from the mill ponds should not exceed two 8 oz meals per month for people living in the Tar Creek Area. Non-residents should not exceed five 8 oz. meals per month.

carcass preparations had consistently higher levels of lead than skinless fillet samples.

the only skinless fillet samples exceeding consumption limit levels were in non-game fish from Spring River for people living in the Tar Creek area.

carcass preparations of non-game fish exceed consumption limit levels in all waterbodies where they are present for people living in the Tar Creek area.

game fish carcasses exceeded consumption limit levels only in the Mill Ponds

sunfish carcasses exceeded consumption limit levels in both Spring River and the Mill Ponds.

catfish carcasses exceeded consumption limit levels only in Spring River

Comparison of Skinless and Skin-On Fillet Samples

ODEQ was asked to compare values of skin-on versus skinless fillets in order to further refine consumption advice. In order to achieve this, composite paired samples of same-species skin-on and skinless fillets were collected at various sites. The results of these samples are shown in Table 12.

The results for lead and cadmium were inconclusive. All cadmium values fell below the analytical reporting limit so no comparison could be made. The same was true for 3 of the pairs for lead. In the case of the other 2 pairs, the skinless fillets were higher by a factor of 1.7 in one pair while the skin-on fillets were higher by a factor of 10 in the other pair.

Zinc showed the most clear difference with all skin-on fillet concentrations higher than skinless fillets by an average factor of 1.7

Conclusions and Recommendations

Consumption of some preparations of fish caught in waters affected by contaminated runoff from abandoned lead and zinc mines in the Oklahoma portion of the Tri-State Mining District have levels of lead that potentially could cause adverse health effects for residents living near the Tar Creek Superfund site and non-residents from outside the area, particularly children. Residents of the Tar Creek area are more at risk based on evidence that people in the area are exposed to higher levels of lead than those living elsewhere.

Lead is the only metal for which group means exceed consumption limit levels. No group means exceed the consumption limits for cadmium or zinc. Skinless fillet fish from mill ponds, the Neosho River, and the Grand Lake are safe to eat. Consumption of fish from these waterbodies does not need to be limited if the fish are filleted and the skin removed. Skinless fillet fish from the Spring River are safe to eat except for non-

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game fish (carp, freshwater drum, redhorse sucker, smallmouth buffalo). Consumption of fillets of non-game fish should be limited to no more than nine 8 oz meals per month for residents of the Tar Creek area..

Carcass preparations (headless eviscerated fish preparation with the bones) of game fish and sunfish from the Mill Ponds, non-game fish from the Neosho River, catfish, non-game fish and sunfish in the Spring River, and non-game fish from Grand Lake have lead concentrations high enough to warrant consumption restriction recommendations.

Additional observations include the following:

Flesh and roe preparations of paddlefish from the area have low concentrations of lead, cadmium, and zinc.

It was unclear if skinless fillets have higher levels of lead and cadmium. The data indicate skinless fillets have lower levels of zinc. A conservative approach to reducing one’s exposure would be to only consume skinless fillets.

A consumption advisory will be issued for people eating fish from waters affected by runoff from the Tri-States Mining District Because there is a need to balance a message that both informs that public and remains simple enough to understand and remember, the ODEQ will consult with local, national, and tribal health officials to craft an effective educational campaign.

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References

1.Oklahoma Department of Environmental Quality. 2003. Fish Tissue Metals Analysis in the Tri-State Mining Area. Customer Services Division, Oklahoma Department of Environmental Quality. Oklahoma City, OK.

2.Oklahoma Department of Environmental Quality. 2002. Standard Operating Procedure for the Tri-State Mining Area Fish Collection and Preparation. Customer Service Division, Oklahoma Department of Environmental Quality, Oklahoma City, OK.

3.U.S. EPA. 1991. EPA Method 200.3 Revision 1.0, Sample Preparation for Spectrochemical Determination of Total Recoverable Elements in Biological Tissues. U.S. EPA, Cincinatti, OH.

4. U.S. EPA. 1991. EPA Method 200.7 Revision 3.3, Determination of Metals and Trace Elements By Inductively Coupled Plasma-Atomic Emission Spectroscopy. U.S. EPA, Washington, DC.

5. Oklahoma Department of Environmental Quality. 2006. Fish Tissue Analysis in the Tri-State Mining Area Followup Study Quality Assurance Project Plan. Customer Service Division, Oklahoma Department of Environmental Quality, Oklahoma City, OK.

6. U.S. EPA. 2000. Guidance For Assessing Chemical Contaminant Data For Use in Fish Advisories, Volume II: Risk Assessment and Fish Consumption Limits. U.S. EPA, Washington, DC.

7. U.S. EPA. 1994. Guidance Manual For The Integrated Exposure Uptake Biokinetic Model for Lead in Children. U.S. EPA, Washington, DC.

8. Washington State Department of Health. 2001. Evaluation of Cadmium, Lead, and Zinc Contamination of Spokane River Fish. Spokane, Washington.

9. U.S. EPA. 1994. IRIS: Cadmium, CASRN 7440-43-9. U.S. EPA, Washington, DC.

10. U.S. EPA. 1992. IRIS: Zinc and Compounds, CASRN 7440-66-6. U.S. EPA, Washington, DC.

11. U.S. CDC(Centers for Disease Control). 1985. Preventing lead poisoning in young children: a statement by the Centers for Disease Control. CDC report no. 99-2230, Atlanta, GA.

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12. Morrison Knudson Corporation. 1999. Data from residential yard samples in the Tar Creek Superfund area. Boise, ID.

13. Ecology & Environment, Inc. 1995. Tar Creek High Access Areas. Summary of Response Activities. Dallas, TX.

14.Cates, David, 2003. Background concentrations of soils in Ottawa County, Memo to Tar Creek File. ODEQ, Oklahoma City, OK.

15.Shaklette, H.T. and Boergnen, J.G. 1984. Element Concentration in Soils and Other Surficial Materials of the Conterminous United States. USGS Professional Paper 1270. Washington, D.C.

Charts and graphs may be viewed bu going to: (http://www.deq.state.ok.us/CSDnew/2007TCFishReport.pdf)

Click On The Tar Creek Superfund Juggler'To Go Back To The Top Of These Documents

Governor Frank Keating’s
Tar Creek Superfund Task Force
Water Quality Subcommittee
Task 1 Report
Surface & Ground Water Monitoring

July 26, 2000

EXECUTIVE SUMMARY

On January 28, 2000, Governor Frank Keating appointed a Tar Creek Superfund Task Force panel to examine all facts related to the cleanup of the Superfund site in Ottawa County.
Eight subcommittees were formed to gather these facts.
The Mine Shaft Subcommittee was asked to complete two tasks.

Task 1
was to identify and locate mine shafts and other openings associated with the abandoned lead and zinc mines that pose a threat to public health and safety.
Task 2
was to propose solutions and potential funding sources for closing the hazardous underground openings.

The Subcommittee identified the sources of old mine maps and related information.

The Eagle-Picher Mining Company mined more acres than any other company in the Tar Creek Superfund area.

Therefore, the 40-acre maps produced by Eagle-Picher should provide the best, most comprehensive information.

Other mining maps have also been located.

To supplement this information, former miners were interviewed to verify the location of the mine openings and the extent of the mining.

Former studies of the mining area also provided valuable information.

The best estimate is there are more than 1,320 mine shafts and thousands of drill holes and other related mine openings in the area.

Many of the openings are closed, but the stability of the mine closures need to be field verified.

This information, once digitized and geo-referenced in a Geographic Information System (GIS), should be downloaded utilizing Global Positioning System (GPS) equipment.

Field staff using GPS can then find the exact location of a mine opening and input all related features.

The information for each mine opening can then be evaluated using a Project Selection Matrix developed by the Subcommittee.

This matrix provides a mechanism for ranking the mine openings.

The openings most hazardous to the public would rank the highest.

The Subcommittee recommends the following to complete Task 1:

Use the 40-acre Eagle-Picher maps as the base maps;

seek public input in locating mine openings through notices in local newspapers;

employ at least two field staff to gather on-site information:

utilize the Project Selection Matrix for ranking individual mine openings;

identify lands under jurisdiction of the Bureau of Indian Affairs;

and begin closure of mine openings as soon as funds become available, even if data gathering has not been completed.

Total estimated cost to complete Task 1 is $250,000

The timeline to complete Task 1 is 11 months.

Upon request, the Subcommittee received numerous mine shaft closure methods from governmental agencies and the private sector.

These methods included designs and costs as well as the advantages and disadvantages for each method.

The Subcommittee supplemented this data by reviewing existing reports for closing both non-coal and coal underground mine openings.

After reviewing all the material, the Subcommittee decided that the preferred closure method is backfilling, if it is economically feasible, because it is a permanent closure.

Other recommended, but less permanent, closure methods are a concrete cap, a concrete wedge, or a concrete plug.

Open drill holes should also be closed.

The estimated average cost of closing an open mine shaft would be about $10,000 and an open drill hole would be $200.

The v subcommittee identified potential funding sources, including their statutory authority, to close the mine openings.

The Subcommittee recommends the following to accomplish Task 2:

Close open mine shafts using backfill as the preferred closure method (if economically feasible);

plug all open drill holes that are 10 inches or greater in diameter;

and begin discussions with federal agencies to secure funds for mine closures, with special efforts toward securing 9:1 matching funds with the Environmental Protection Agency.

Total estimated cost to complete Task 2 is $10 million

Depending on the amount of funding and the number of closures, it will take 5 years to complete the closure work.

It is believed that on-site field investigations will indicate that many of these shafts are sufficiently closed, thus reducing the total time and dollars needed.

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INTRODUCTION

The Mine Shaft Subcommittee is one of eight subcommittees established under Governor Frank Keating’s Tar Creek Superfund Task Force.

The primary objective of this subcommittee is to develop feasible alternatives for plugging the numerous abandoned mine shafts existing in the Tar Creek Superfund area.

To accomplish this objective, two tasks have been given to the subcommittee:

Task 1

Develop an effective means for identifying and locating all open mine shafts, and other openings that create a safety hazard, that exist within the immediate vicinity of the Tar Creek Superfund project area.

The subcommittee shall identify the resources necessary to complete this effort, the entities responsible for performing the identification, and potential funding sources for the project.

Task 2

Assess the effectiveness and feasibility of current efforts to plug abandoned mine shafts and explore other feasible alternatives to remediate this critical safety concern.

The subcommittee shall draft a project proposal for each plugging alternative that includes a scope of work, timeline, resource needs (both capital and personnel), and potential sources of funding for the project.

The subcommittee is co-chaired by James Graves (Grove, Oklahoma) and Mike Kastl (Oklahoma Conservation Commission)

The subcommittee members are:

A. L. Suman – Ottawa Reclamation Authority
Sam Freeman – City of Picher
Bill Erdner – U.S. Army Corps of Engineers
Mike Sharp – Oklahoma Conservation Commission
Len Meier – Office of Surface Mining, U.S. Department of the Interior
Dennis Datin – Oklahoma Department of Environmental Quality
John Dalgarn – Bureau of Indian Affairs, U.S. Department of the Interior
Meredith Garvin – Quapaw Tribe
Frank Wood – Metallurgical Consultant
Ed Keheley – Quapaw, Oklahoma
Jo Rainbolt – Office of Congressman Tom Coburn
Joe Crawford – Ottawa County Commissioner, District #1

BACKGROUND INFORMATION

Picher Mining History

Lead and zinc mining in northeastern Oklahoma began in 1891 near Peoria.

Several other communities in the area were settled as a result of these mining activities, increasing the area population to approximately 32,000 people in the early 1920s.

Estimates state that as many as 250,000 people were directly or indirectly affected by portions of the Tri-State (Kansas, Oklahoma, and Missouri) Mining District activities.

At one time the Picher Mining Field was the leading U.S. producer of lead and zinc, supplying approximately 26.3 percent of the nation’s lead and zinc products.

From 1907 through 1946 more than 1,900,000 tons of lead and zinc were mined in the area, at a value of more than $202 million.

To reach the underground bodies of ore throughout the Tri-State Mining District, early miners and mining companies excavated hundreds of working and prospective mine shafts.

Thousands of drill holes dotted the mining area.

During the early mining era there were more than 200 processing mills operating in the Picher Mining Field.

Each mining company had a mill located at its most productive site.

An aerial view of the Picher Field taken in 1995 is shown on Map 1 and illustrates the high concentration of mining activity.

Water was pumped from underground through the mill and used to separate the ore from the waste rock.

The mills had the capacity to pump between 2,000 to 10,000 cubic feet of water per minute to separate between 30 and 70 tons of ore per hour.

A mining method known as jigging and tabling was used to extract the ore, but it was not very efficient.

Beginning in the 1920s the use of the flotation process ensured the recovery of 80-85 percent of the metal contained in the crude ore.

Between 1920 and 1945, 36 million gallons of water were pumped daily from the mines by 63 major pumping stations in order to keep the mines dry.

In 1934 the Eagle-Picher Mining Company began construction on the Central Mill;

the mill was completed in 1935 with a capacity of 500 tons of ore per hour.

It was believed that this mill would replace all of the other mill sites;

an assumption that did not prove true.

In 1947 there were 65 mining companies operating 135 mines and 46 mills in the Tri-State Mining District.

Even with the Central Mill's increased capacity, it was not possible to handle production for all the mines.

The mills produced more than three billion tons of waste rock (chat).

Mining companies would re-run the chat as many as three times in order to recover all the ore possible.

Sludge and mill waste were also recycled from mill sites.

Such recycling accounts for some of the variability in the level of lead found in the chat.

In 1946 the Tri-State Zinc and Lead Ore Producers Association lobbied the U.S. Congress for economic assistance to continue the mining of marginal ore deposits remaining in the mining district.

Although the Tri-State ore producers were not successful in their lobbying, assistance

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was provided by a production subsidy under the Strategic Minerals Act of 1949, which paid mining companies a subsidy for tonnage produced regardless of ore content.

This provided an economic incentive to remove pillars (support columns).

Removal of pillars fulfilled miners’ predictions of mines collapsing, water filling mine caverns, and contaminated acid water flowing into Grand Lake.

In 1958 many of the mining companies were shutting their doors and moving out of the field.

As each mine closed, the water level rose, and it became more difficult for those remaining to continue in business.

Eagle-Picher, the largest company in the area and the last to shut its doors, began subleasing to gougers in the late 1950s.

The gougers would enter the mines and mine out any ore remnants.

It was during this era that additional pillars were removed, thereby increasing the potential for subsidence of the surface above the mines.

Eagle-Picher opened up the first incline tunnel at the Swalley Mine northeast of Picher in 1969 through 1970.

The Kansas Health Department, due to the heavy iron ore and other minerals draining into Spring River and Lytle Creek, closed this operation.

The company invested more than $1 million trying to contain the water and reduce contamination problems.

The extensive mining in the Tri-State District left abandoned shafts and underground caverns extending from south and west of Commerce, Oklahoma, to Joplin, Missouri.

The caverns are not continuous; however, only small parcels of solid land exist in some areas, which could cause potentially hazardous situations.

Mining Method

A standard shaft was 5 feet by 7 feet encased in wood cribbing from hard rock to the top of the ground.

A 6 ½-foot round hole was made from the hard rock down to the mining level.

As modern equipment became available, larger holes were made (6 ft. by 9 ft. and 7 ft. by 8 ft.).

Mining was accomplished by the room and pillar method, which consisted of cutting open stopes with irregularly spaced pillars.

Generally, the ore body was crosscut by the shaft; therefore, the problem presented was how to mine the better grade of ore and leave only the lowest grade of ore for pillars to support the roof.

The structure and formations of the roof of the stope and the width and height of the ore body controlled the size and spacing of the pillars.

If the shaft had been completed in the ore body, stopes were opened up radially for the full height of the ore, with pillars 20 to 50 feet in diameter and properly spaced to support the roof, usually 30 to 100 feet apart.

About 15 percent of the ore body was left for pillars.

Later when the mine reserves were depleted, as much as 50 percent of the tonnage left in the pillars was recovered by slabbing operations or by complete removal of certain pillars.

The depth of mines varied in the mining fields according to the ore veins.

The average depth was 237 feet.

Shafts on the Kansas-Oklahoma state line in the central portion of the mining field were deep.

They became even deeper further north, with some mines extending down to 458 feet.

South of the state line mine shafts were shallower. Shafts in Hockerville, Commerce, Quapaw and Lincolnville were very shallow, from 78 to 120 feet deep.

Shafts in Douthat and southwest of Cardin were 200 to 290 feet in depth.

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(Insert "Depth of Mine Workings and Shaft in the Picher Field" Map)

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In the shallow mining area ore veins extended close to the surface and no cap rock was present, only shell rock.

It is in these areas that large cave-ins have occurred.

These areas will be a factor in addressing subsidence and mine shaft closure.

There are areas in the Picher Mining Field where large unsupported caverns exist that have shown no outward signs of subsidence.

This is due to a 30- to 40-foot solid limestone layer near the ground surface.

Some of the more productive mines had three levels of mining, and in some mines pillars in all three areas were removed leaving little or no support.

According to some former miners, a baseball game could be played in the open space and grass roots could be seen growing from the ceiling.

In some of these areas subsidence of 80 to 140 feet has already occurred, but the surface ground looks deceptively normal.

In other areas where the ceiling is only 15 feet high, subsidence or cave-ins leave only small, sunken areas on the surface.

Some of the larger caveins reach the surface resulting in as much as a 170-foot subsidence.

Historical Sealing Methods

As the early mines began to close, several methods were initially used to cover the open shafts and protect people, livestock, and pets from falling into them.

In some cases old car bodies and railroad ties were used to seal the mine shafts.

These were temporary methods of closure.

However, these methods have been the only cover on some of the shafts for up to 60 years.

In 1936 Eagle-Picher sealed six mine shafts by drilling into hard rock and using steel bars to anchor a wooden form over which a concrete slab was poured.

Between 1956 and 1962 Eagle-Picher poured concrete shaft covers over five additional known mine shafts.

The Ottawa Reclamation Authority (ORA) sealed six shafts in the Picher area by building pyramid-shaped wooden forms holding six to seven yards of concrete.

After the concrete was poured, the forms were removed and the concrete slab was pushed over the opening to the shaft.

The hole was then backfilled to prevent ground water from entering.

Later the ORA used old cement mixer bodies instead of the wooden forms to plug three shafts.

Filled with concrete, the mixer bodies made adequate seals for the shafts.

The Authority also closed additional shafts using Haliburton oil tanks.

In January 2000 the Oklahoma Department of Environmental Quality (DEQ) and Grand Gateway Economic Development Association (GGEDA) sealed three mine shafts as a pilot project for future closure and sealing methods.

Each shaft required a different method of sealing

The first used the cement mixer body method,

The second was filled with large rocks from a nearby boulder pile, and the third was covered with a cement slab.

Total cost for the pilot closure project was $15,000.

Each of the methods is being evaluated for future use.

Previous Studies

The Luza Report, completed in 1986, identified 1064 shafts in northeast Oklahoma.

The report did not investigate areas within city limits.

However, different mine maps and interviews with former miners indicate there are more mine shafts, particularly within the city limits of each of the mining towns.

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In 1998 the DEQ and GGEDA began a program to map and identify shafts, subsidence, chat piles, mill sites, and other mining hazards that exist in the mining field.

The mapping utilized old mining area maps, interviews with former miners and area residents, research at area universities and colleges, GPS location data, and fieldwork.

To date, the program has identified approximately 85 percent of the shafts in the northeastern Oklahoma mining field on hard copy maps.

Mine Shafts Identified in Previous Studies

Picher-Carden 212

Quapaw (city limits) 4

Commerce area 36

Peoria 4

Luza Report 1,064

Total 1,320

Analysis

It is the opinion of Dr. Charles Nodler, Jr., archivist at Missouri Southern College (Joplin, Missouri), that there are possibly more than 300 shafts in the Picher-Cardin area alone.

And that in the mining district as a whole, which includes Kansas, Oklahoma and Missouri, there are in excess of 2,600 shafts.

Missouri Southern College has one of the most extensive collections of data pertaining to the mining district.

TASK 1

Develop an effective means for identifying and locating all open mine shafts, and other large openings that create a safety hazard, that exist within the immediate vicinity of the Tar Creek Superfund project area.

The subcommittee shall identify the resources necessary to complete this effort, the entities responsible for performing the identification, and the potential funding sources for the project.

Identifying and Locating Mine Openings

In identifying and locating mine openings that pose a threat to public health and safety, the openings were classified into four major categories

open shafts

sealed shafts

drill holes (open holes 10 inches or greater in diameter)

and subsidence-related mine openings.

Subsidencerelated mine openings are addressed by the Subsidence and Sinkhole Subcommittee.

The Mine Shaft Subcommittee has relied primarily on mine maps, interviews with former miners, aerial photos, and miners’ field notes to gather information about the mine shafts and drill holes.

In many cases, the miners verified shaft locations and provided valuable information about the depth of the mining, the geology of the mined area (rock cap or shale between the ore and the surface), the number and direction of drifts from a mine shaft, and other pertinent details.

There are numerous shafts that have been sealed in past years utilizing a variety of methods.

In some cases, the former miners can verify if a mine shaft was closed and the method that was used to close the shaft.

Some of the methods, such as using wooden timbers or car bodies to bridge the openings, should be considered temporary at best.

These shafts have a high potential for failure and should be re-opened and sealed properly.

Additionally, knowledge gained from local citizens and former miners will be used to locate, in the field, as many openings as possible.

Eagle-Picher Mining Company.

The company has very extensive mining records of the Tri-State Mining District, particularly of the Picher field, which is the largest mining field within the district.

These records include 40-acre detailed mine maps on essentially all land involved in the mining, thousands of drill logs (drilling records of the rock types above a mine roof), information on how the shafts were abandoned and the locations, survey notes to find the shafts, and other valuable mining records.

The 40-acre maps are the most up-to-date maps available because Eagle-Picher was the only large company left in the Picher field during the final stages and controlled most of the final mining done earlier by smaller mining companies.

The 40-acre mine maps are vital;

because they show the extent of the underground mining in detail, they are ideal for determining the safety of the surface.

These maps also show the roof heights of the underground workings; this is extremely important because some of the underground rooms were mined to heights greater than 90 feet.

In those areas mined at greater heights, a cave-in could go to the surface causing possible injury/death or destruction of property.

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Miners searching for the location of ore bodies below the surface sank hundreds, if not thousands, of drill holes throughout the mining area.

The drill logs maintained by the miners catalogue the rock type in the roofs of the mines.

The type and thickness of the rock between the roofs of the mines and the surface varies.

This information is very significant.

If there is a thick limestone cap over a mined-out area, the surface area should be safe unless the underground mining was very high and wide.

The most dangerous situation occurs where extensive shale exists between a mine roof and surface.

In this case, extreme caution must be maintained when using any equipment on the surface. Open drill holes can pose two hazards.

Some of the open drill holes have collapsed and are large enough for a child to enter.

The second hazard is that they provide a conduit for surface water to enter the underground workings, thereby contributing to the magnitude of acid mine drainage (AMD) being produced in the region.

The Eagle-Picher records give the condition of abandoned mine shafts in the Picher field and other areas of the Tri-State district, showing the locations and how the shafts were abandoned.

Many of the older shafts merely caved-in and as a result were not properly closed.

These shafts are even more hazardous because nohing is known about the extent of the cave-ins, which could cause surface hazards at any time.

Many shafts remain open and present a very serious threat to people, livestock and pets.

In addition to the negative impact on public safety, these open shafts and drill holes contribute to environmental degradation of the region's surface and underground water supplies.

Surface water flowing into these openings enters the underground mine workings where it picks up pollutants that, when exposed to oxygen, produce AMD.

AMD has a very deleterious effect on the aquatic environment, which is feared to be as far reaching as to impact Grand Lake.

Eagle-Picher survey notes are also key pieces of information.

Eagle-Picher surveyors were known for their accuracy and professionalism.

With these survey notes, it is possible to locate most of the shafts, mine cave-ins, drill hole cave-ins, and other problem areas no longer distinguishable on the surface due to surface activity and weathering in the Picher field.

All the extensive mining records were stored for many decades in a large vault at the Eagle-Picher Mining Company headquarters at Cardin, Oklahoma.

In 1970 Eagle-Picher moved its headquarters to Reno, Nevada.

Several attempts have been made to gain access to the maps at Eagle-Picher’s headquarters.

Eagle-Picher officials have indicated that many of the maps were destroyed or heavily damaged by flood water.

Those who have sought mining records at the Reno office have verified that little or no maps are available due to the flood damage.

Other sources for mine information include colleges/universities, local, state, and federal agencies, retired miners, and interested citizens.

The 40-acre maps will be the most useful because of the detail of the underground mines and should be obtained from other sources.

Luza Report (Stability Problems Associated with Abandoned Underground Mines in the Picher Field Northeastern Oklahoma).

In 1979 the U.S. Bureau of Mines entered into cooperative agreements with the state geological surveys of Oklahoma, Kansas, and Missouri to investigate the mine-related problems in the Tri-State area.

A field-inspection program was initiated in May 1981 and field work was completed in May 1982.

The Oklahoma portion of this study was printed in 1986. The principal objectives of the investigation were:

(1) compile a series of maps showing the location and extent of past mining activities and the resulting surface

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effects of underground and open-pit mine workings, shafts, ground subsidence, accumulations of mine waste, and tailings ponds;

(2) identify hazardous areas with potential for future damage to persons or property; and

(3) consider methods to protect the public from hazardous and potentially hazardous conditions.

The compiled mine-workings maps and field surveys indicated that at least 1,064 shafts were located in the Oklahoma portion of the Picher Field.

However, areas within city limits were not included.

The field work consisted of locating the shafts, describing the present condition at each shaft, the presence or absence of water, and the water depth, and measuring or estimating surface-collapse dimensions.

The shafts were grouped into seven shaft-status categories.

A summary of the shaft inventory is listed in the table below.

At the time of the study more than 50 percent of the shafts were concealed or filled.

Shafts that were indicated on mine maps but could not be found were classified as concealed.

With several shafts, it was not possible to distinguish between the filled and/or concealed condition.

Therefore, these shafts were grouped into one category.

A shaft was considered open if the original cribbing was still intact and no apparent obstruction could be observed.

However, most shafts were nearly full of water, which obscured the condition of the shaft below the water line.

Where the shaft collar was undergoing minor collapse (less than 10 feet) and the cribbing was nearly intact, the shaft was classified as open with minor collapse.

About 25 covered shafts were recognized.

Generally, a thin concrete slab was used to cover the shaft.

Concrete debris from former shaft covers was observed in the bottoms of a few shaft collapses.

Thus, it appears that shaft covers are ineffective in securing shafts.

There is high probability that most of the 25 recognized covered shafts will fail in the future.

At the time of the report 481 shafts were either open or in some stage of collapse.

Almost 70 percent of the open mine shafts and/or shaft collapses occur in Sections 19, 23, 28, and 29 Township 29 North, Range 23 East.

The area with the second-largest concentration of open shafts lies northeast of Lincolnville in Sections 30, 31, and 32, Township 29 North, Range 24 East.

About 65 percent (316) of the sites were recommended for filling as a closure method.

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This category includes open shafts, open shafts with minor collapse, minor collapses, and moderate collapses.

Chat was not recommended as an initial fill material in the mine shafts.

Waste rock from large boulder piles found adjacent to most mine shafts was recommended.

No action was recommended for 21 percent (107) of the sites.

Generally, the no-action category included collapse features that were nearly full of water and had exhibited no recurring collapse for a number of years.

The report recommended the remainder of the sites be fenced, with some being filled if economically feasible.

Global Positioning System (GPS) and Geographic Information System (GIS).

During the mining operations, surveyors located and mapped various features in the field that were associated with the mines.

Modern technology allows the exact geographic location of these features to be obtained using a Global Positioning System (GPS) receiver.

Using the data entry features of the GPS receiver, various attributes of a mine opening can be entered into a data dictionary.

The resulting data becomes a databse for use in a Geographic Information System (GIS).

The GIS can be used to correlate mine openings and their attributes with other data that is being gathered throughout the mining region and prioritize their closing.

Numerous mine shafts have been sealed with materials that will decay over time, leading to an unstable and unsafe situation.

Visually locating these shafts in the field is very difficult.

However, locations of shafts and drill holes can be found on virtually all maps as well as the extent of the underground workings.

With the tools available today, the location of these features can be calculated using GIS and GPS techniques.

First, the old mine maps can be converted into an image that can be viewed on a computer.

Once scanned, special computer software can be used to digitize important features, including known survey points.

These survey points can then be located in the field and the geographic locations recorded using GPS.

These points can be transferred to the GIS where the digitized map survey points are tied to the true GPS survey points using a technique known as rubbersheeting.

This process removes distortion that was present in the old paper map and puts the digitized map features in their proper geographic location.

The location of various features can now be obtained from the GIS and transferred to the GPS receiver.

In the field, one can navigate to the precise location of the map features of interest using the GPS receiver in navigation mode.

However, before any of this equipment can be used on site, each landowner must be contacted, and consent to enter the respective property must be provided by the landowner.

Developing a positive relationship with each of the affected landowners is a key factor in the ultimate goal of closing the dangerous mine shafts or holes.

\ A right-of-entry assuring the landowner that the first phase is merely one of investigation and fact-gathering signed by the landowner will be necessary.

This developing relationship will make it easier when it comes time to talk about shaft closure.

Project Selection

Once the mine shafts and drill holes have been located, closure priorities must be established.

Those sites that pose the highest threat to public health and safety should be addressed first.

In order to properly select these sites, a Project Selection Matrix has been developed by the Mine Shaft Subcommittee to rank the abandoned underground mine shafts and abandoned drill holes

(see Appendix A - PROJECT SELECTION MATRIX FORM).

The matrix is divided into three sections

Physical Conditions (80 points),

Human Exposure (80 points),

and Environmental Factors (50 points).

Therefore, the maximum points a hazardous site could receive would be 210 points.

A Project Selection Matrix form will be filled out for each mine shaft or drill hole visited.

After all the hazardous sites are visited and the forms completed, the sites will be ranked.

Those sites with the highest points should be reclaimed first.

Final ranking will need to consider such things budget constraints, location of sites (if bidding a group of sites), and availability of construction materials.

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Identifying Necessary Resources

Staff and Equipment.

Since September 1998 James Graves, as site manager with the Grand Gateway Economic Development Association (GGEDA), has identified and located mine maps and other related information in order to verify the number of open mine shafts and drill holes poseing a threat to the public health and safety in the Tar Creek Superfund area.

According to Mr. Graves, about 85 percent of the mine shafts have been identified on mine maps.

However, most drill holes have not been identified.

The Mine Shaft Subcommittee proposes an accurate digital base map of the mined area that includes the various layers of information be developed.

This base map should consist of a 1:2400 scale digital grayscale orthophoto derived from aerial photography.

The photography is available from the U.S. Army Corps of Engineers but needs to be digitally scanned, rectified, and geo-referenced.

Development of a detailed inventory and an accurate data layer of the location of mine shafts, drill holes, and extent of mine workings will require the digitization and accurate geo-referencing of the 40-acre Eagle-Picher mine maps and other mine maps.

Many of the shafts and virtually all of the drill holes can not be located easily in the field.

Their geographic coordinates will need to be established from the accurately referenced mine maps and then GPS used to locate them in the field.

Development of the digital orthophoto base map, digitization, and geo-referenceing of the mine maps and locating shafts using GPS is estimated to take approximately 11 months and cost around $250,000.

The Mine Shaft Subcommittee recommends that this digital base map and all associated mine shaft and drill hole data be maintained and managed by the Oklahoma Conservation Commission.

Potential Funding

To date the Environmental Protection Agency (EPA) has provided most of the funding for the work coordinated by James Graves through the Oklahoma Department of Environmental Quality, working with the Grand Gateway Economic Development Association and the Ottawa County Conservation District.

Potential funding sources for further inventory of mine shafts and open drill holes are discussed under the section “Identifying Agencies for Funding and Closure of Mine Openings” of this report.

Recommendations for Task 1

1. An accurate digital orthophoto base map needs to be developed to serve as a background for visualization of the various layers of information that have been and are still being gathered.

The 40-acre mine maps (Eagle-Picher Mining Company) and other relevant mine maps digitized and geo-referenced will provide the basis of the inventory of the mine shafts and drill holes in the Tar Creek Superfund area.

These maps can be supplemented with information gathered from former miners and residents and current landowners with knowledge of these hazards.

This information will be used to field verify the location of shafts and open drill holes and should be managed by the Oklahoma Conservation Commission.

2. Notices should be published in local newspapers in Ottawa County seeking public input as to the location of these mine shafts and drill holes.

The notice would include the address and/or a phone number to send and/or call in the information.

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3. Two people are required to do the field work. With the hidden dangers of abandoned mine openings, the two field staff should work as a team in the field, not individually.

The field work will use the inventory described in (1) above to verify the location of mine shafts and drill holes and to record various attributes of each feature.

The field staff will need GPS and GIS equipment to accomplish this work. Color photos will be taken of each site and added to the information in the inventory.

4. Once the field data has been completed, the sites will be evaluated using the Project Selection Matrix for ranking purposes.

The matrix will prioritize shafts and drill holes based primarily on human health and safety considerations.

Environmental impacts will also be considered since open shafts and drill holes are a conduit for surface water to enter the mine workings and increase the production of acid mine drainage.

5. Subject to funding availability, closure work will begin immediately on those shafts and drill holes as prioritized by the matrix process.

6. Lands under the jurisdiction of the Bureau of Indian Affairs (BIA) need to be identified.

This would enable the proper authorities to know where to close mine shafts and other mine-related openings as soon as funding is available.

7. Funding for identifying and collecting the field information on the mine shafts and drill holes will likely come from one of the sources listed in Appendix C.

The timeline for completing Task 1: 11 months

The total costs to accomplish Task 1: $250,000

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TASK 2

Assess the effectiveness and feasibility of current efforts to plug abandoned mine shafts and explore other feasible alternatives to remediate this critical safety concern.

The subcommittee shall draft a project proposal for each plugging alternative that includes a scope of work, timeline, resource needs (both capital and personnel), and potential sources of funding for the project.

Assessing Closure Methods

Historically, mine openings were either left open or crudely closed.

Minimal effort and expense were put into these closures, and often any available on-site materials were used.

Fencing was one of the most common techniques, and badly deteriorated examples of the fencing can still be seen around abandoned shafts.

Rough cut logs or lumber from a mine was often placed over shafts, but over the years many coverings have decayed and offer little or no protection.

The local rail spur or the steel rails from the mines also were used to cover shafts and, if secured properly, provided an effective closure.

Each mine shaft and open drill hole will need to be prioritized using the Project Selection Matrix.

Determining the appropriate closure method will involve the evaluation of numerous additional factors such as location, access to a mine, physical site characteristics, landowner needs, and costs.

In some cases, historic and cultural resources and environmental and wildlife considerations will need to be assessed also.

A wide range of closure methods have been used by the mining industry and local, state, and federal agencies.

Backfilling is one of the oldest and most commonly used methods for closing mine openings.

In most cases, this is the preferred closure method.

However, if the bottom of a mine shaft opens into a large cavity, then another closure method would have to be used since backfilling would be cost-prohibitive.

Such large cavities (20 feet or greater height) are prevalent throughout the Tar Creek Superfund area.

In order to determine if a large underground cavity is present, the use of a remote television system will be necessary.

Where the cavity is less than 20 feet in height, backfilling will be the preferred closure method.

When backfilling is discussed, someone will suggest using the lead/zinc chat piles as fill for the mine shafts.

The viability of using chat as fill material in mine shafts is still being debated.

Economic and environmental factors will ultimately determine if some of the chat will be used for this purpose.

Generally, if chat were used in backfilling a shaft, it would make up a portion of the total backfill.

The backfill method utilizes a range of gradations of fill material, with the coarsest material at the bottom and the finest material near the top.

Chat, being relatively fine, would be placed in the upper portion of the shaft.

The DEQ will determine chat use guidelines based on a risk assessment of its use as a fill material.

These guidelines will not be in conflict with current DEQ regulations based on the public nuisance law found in 27A O.S. 2-6-105

(see APPENDIX C - POTENTIAL FUNDING SOURCES FOR CLEANUP OF THE TAR CREEK SUPERFUND AREA).

Other closure methods include concrete caps, wedges, concrete plugs, grates, polyurethane foam (PUF), hollow core plugs, and fencing.

If backfilling can not be used, concrete caps, wedges, or concrete plugs can be utilized.

In 1983 the U.S. Bureau of Mines published a report, A Study of Stability Problems and Hazard Evaluation of the Kansas Portion of the Tri-State Mining Area.

The report contained suggested methods for closing mine openings.

For shafts that dead end into solid bedrock, backfilling was the preferred closure method.

For those shafts that entered into rooms of various vertical and/or lateral extents, a concrete plug was chosen.

And for shafts that were bridged by rock or concrete foundations, backfilling or a plug were the suggested closure methods.

Several state and federal agencies were contacted and asked to send closure information such as methods used, design and specifications, equipment used, costs, and the pros and cons for each method

(see APPENDIX B - CLOSURE METHODS).

Developing Closure Proposals

As a part of TASK 2, project proposals have been developed for closing a hypothetical 300-foot open mine shaft.

The first 20 feet of the shaft is 5-foot x 7-foot cribbing; the remaining 280 feet is a 7-foot round shaft.

The three proposals are backfill, a concrete cap, and a concrete wedge.

Each proposal contains a scope of work, timeline, and resource needs (both capital and personnel).

However, most of the existing open mine shafts are water-filled even above sound rock.

Special considerations may be required for each closure method depending on the depth of water.

Backfill

Scope of Work...

Fill the bottom portion of the shaft with riprap material from a rock quarry and complete the fill with suitable on-site material (earth fill).

Assume that a 5-foot by 7-foot drift extends in two directions at the bottom of the shaft.

Fill the shaft with riprap to approximately 10 feet above the top of the drift.

In this case, the bottom 17 feet of the shaft requires about 54 tons of riprap.

The remaining 283 feet of the shaft requires about 400 cubic yards of fill material.

Timeline - 3 to 5 days

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Room Ceiling - Mine Floor - 7' dia. Shaft - Backfill Placement

Resource Needs (capital and personnel)

The contractor needs a front-end loader, a 10-wheel dump truck, and a small dozer.

Total cost to accomplish this work is approximately $2,500.

Estimates have also been developed for backfilling the 300-foot open mine shaft with a room at the bottom, using varying ceiling heights.

Riprap material from a rock quarry is used to form a base from the mine floor to 10 feet above the room ceiling within the shaft.

Then, transition materials and earth fill are used to fill the remainder of the shaft.

Costs were estimated using $10 per ton for riprap in place and $7.13 per foot of shaft depth for earth fill placement.

The following table shows ceiling height, tons of riprap based on a 1:1 angle of repose, and estimated cost for filling:

Ceiling Height (ft.) Riprap (tons) Cost

10 - 150 - $ 3,726
20 - 803 - 10,185
30 - 2,330 - 25,154
40 - 5,105 - 52,833
50 - 9,500 - 96,711
100 - 68,800 - $689,355

Concrete Cap

Scope of Work:

Excavate down to sound rock, which is estimated to be 20 feet since the cribbing goes to that depth.

Excavation to provide 2:1 side slopes and bottom dimensions of 16 feet by 16 feet to accommodate placement of the concrete slab or cap.

The concrete cap is two sections of preformed reinforced concrete with dimensions of 5 feet by 10 feet by 8 inches.

Set the cap in place and backfill with the excavated material.

Excavation requires removal of approximately 2,692 cubic yards, and backfill will require placement

Source: Oklahoma Conservation Commission

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of approximately 2,718 cubic yards.

An access ramp for placement of the concrete cap may be needed.

Timeline - 2 to 3 weeks

Resource Needs (capital and personnel) - The contractor needs a large trackhoe and a small dozer.

Total cost to accomplish this work is approximately $11,500.00

Concrete Wedge

Scope of Work:

Excavate down to sound rock, which is estimated to be 20 feet since the cribbing goes to that depth.

Excavation to provide 2:1 side slopes and a bottom diameter of 15 feet at sound rock to accommodate placement of the wedge.

The wedge has a 9-foot square top and a height of 4½ feet. Set the wedge in place, fill with concrete, then backfill with the excavated material.

Excavation requires removal of approximately 2,044 cubic yards, and backfill requires placement of approximately 2,070 cubic yards.

An access ramp for placement of the concrete wedge may be needed.

Timeline - 2 to 3 weeks

Resource Needs (capital and personnel)

The contractor needs a large trackhoe and a small dozer.

Total cost to accomplish this work is approximately $10,500.

Plugging Drill Holes

All open drill holes 10 inches in diameter or larger should be plugged with concrete to a depth of 10 feet.

The Luza Report indicated that 481 mine shafts were either open or in some stage of collapse.

It would take $4.8 million to close these shafts at an average cost of $10,000 per shaft.

There are other mine shafts not included in the Luza Report as well as open drill holes and mine shafts that were covered and/or sealed but in need of a more permanent closure.

An additional $5.2 million would be needed to address these sites.

The total cost for closing the open mine shafts and open drill holes is estimated to be $10 million.

A time frame of 5 years is estimated to complete the closure work.

Identifying Agencies for Funding and Closure of Mine Openings

There are several federal, state, and local agencies that have been and continue to be involved with reclamation of abandoned mines that pose a threat to public health and safety in Oklahoma.

Their respective laws allow technical, legal, and financial help to be provided to the communities and citizens in the Tar Creek Superfund area.

The federal agencies included in this report are the Environmental Protection Agency, the U. S. Department of the Interior’s Office of Surface Mining, the U. S. Department of Agriculture’s Natural Resources Conservation Service, and the U. S. Army Corps of Engineers.

The state agencies/authorities that have been involved with reclamation of abandoned mine shafts are the Oklahoma Department of Environmental Quality, the Oklahoma Conservation Commission, the Oklahoma Department of Mines, and the Ottawa Reclamation Authority.

(See APPENDIX C - POTENTIAL FUNDING SOURCES FOR CLEANUP OF THE TAR CREEK SUPERFUND AREA for more details concerning specific legislation and funding sources.)

A brief summary for each agency, as well as other possible funding sources, follows:

Environmental Protection Agency.

The Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA) as amended by the Superfund Amendments and Reauthorization Act of 1986, popularly known as the Superfund program, is administered by the Environmental Protection Agency (EPA).

This law can be used for enforcement and funding in the Tar Creek Superfund area.

The Clean Water Act (CWA); 33 U.S.S. s/s 121 et seq. (1977), is an amendment to the Federal Water Pollution Control Act of 1972, which set the basic structure for regulating discharges of pollutants to waters of the United States.

This law gives EPA the authority to set effluent standards on an industry basis (technology-based) and continues the requirements to set water quality standards for all contaminants in surface waters.

The CWA makes it unlawful for any person to discharge any pollutant from a point source into navigable waters unless a National Pollution Discharge Elimination System permit is obtained under the Act.

The Safe Drinking Water Act (SDWA); 42 U.S.C. s/s 300f et seq. (1974), was established to protect the quality of drinking water in the U.S.

This EPA law focuses on all waters actually or potentially designed for drinking use, whether from aboveground or underground sources.

EPA officials have indicated that treatment of mine shafts and drill holes must show a positive impact on water quality before EPA will approve funding.

Oklahoma Department of Environmental Quality.

The state of Oklahoma through the Oklahoma Department of Environmental Quality (DEQ) has the State of Oklahoma Environmental Quality Code.

This law can be used for enforcement and funding in the Tar Creek Superfund area.

The Waste Management Division of DEQ has the responsibility of

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carrying out the activities as required by the State of Oklahoma Environmental Quality Code and the EPA’s CERCLA laws.

In January 2000 DEQ completed a pilot project by closing three mine shafts northeast of Quapaw, Oklahoma.

(See APPENDIX B - CLOSURE METHODS for more details on the DEQ closures.)

United States Army Corps of Engineers

The Section 22

Planning Assistance to States (PAS) Program of The Water Resources Development Act of 1974 authorizes the Corps of Engineers (COE) to use its technical expertise in water and related resource management to help states and Native American tribes with their water resource problems.

This is a cost-share program and requires a 50-percent match by the state or tribe.

PAS studies do not lead to federal construction projects.

A water quality problem would have to be associated with the mine openings before PAS funds could be utilized.

The Section 206

Aquatic Ecosystem Restoration Program of The Water Resources Development Act of 1996 authorizes the COE to carry out aquatic ecosystem restoration projects if they improve environmental quality, are in the public interest, and are cost-effective.

The program may be applicable where acid mine drainage exists.

If the mine shafts and drill holes are contributing to acid mine drainage problems in the area, then funding could be obtained through the Aquatic Ecosystem Restoration Program.

This also is a cost-share program requiring a 35- percent, non-federal match.

The Abandoned Mine Restoration Act of 1999 authorizes the Secretary of the Army through the COE to assist stewards of federal and non-federal lands to address environmental and water quality problems caused by drainage and related activities from abandoned, inactive, and postproduction noncoal mines.

On non-federal lands, the COE would also require a match of 35 percent from non-federal entities.

This is pending legislation that could be used to close mine shafts and drill holes if they were degrading water quality.

Office of Surface Mining.

The Surface Mining Control and Reclamation Act of 1977 (PL 95-87) provides for the restoration of lands mined and abandoned or left inadequately restored before August 3, 1977.

The Surface Mining Act authorizes the Secretary of the Interior to expend Abandoned Mine Reclamation Fund monies for reclamation of high priority problems that present an extreme danger to the public.

States and tribes receive annual grants out of this Trust Fund from the U.S. Department of the Interior’s Office of Surface Mining (OSM).

Both coal and noncoal hazards can be addressed under PL 95-87.

OSM officials have indicated that Trust Fund monies could be matched with non-CERCLA (Superfund) EPA funds to fill mine shafts, if the mine shafts are contributing to acid mine drainage.

Oklahoma Conservation Commission.

The Oklahoma Conservation Commission (OCC) is responsible for reclaiming over 32,000 acres of abandoned surface coal mines and another 40,000 acres of abandoned underground coal mines in a 16-county area of eastern Oklahoma.

The Surface Mining Control Act of 1977 (PL 95-87) provides the funding to reclaim sites that pose health and safety problems to the public.

PL 95-87 established an AML Trust Fund through a tax on coal producers.

The OCC receives an annual grant of $1.5 million to address these AML hazards.

Even though all the funds received to date have been spent on coal AML problems (over $90 million high priority coal problems are yet to be reclaimed), some of this money may be used for noncoal hazards such as the lead and zinc problems in Ottawa County.

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Section 409 of PL 95-87 states that the Secretary of the Interior, at the request of the governor of any state, is authorized to fill voids, seal open abandoned mine shafts, tunnels, and entryways and reclaim the surface impacts of the underground mines.

The Secretary will approve only those sites that could endanger life and property, constitute a hazard to the public health and safety, or degrade the environment.

To date no AML funds have been spent in Oklahoma on noncoal hazards.

Natural Resources Conservation Service.

The U.S. Department of Agriculture’s Natural Resources Conservation Service (NRCS) is authorized through Section 406 of The Surface Mining Control and Reclamation Act of 1977 (PL 95-87) to reclaim rural lands affected by mining.

PL 95-87 made money available to the Secretary of Agriculture from the AML Trust Fund.

This program is known as Rural Abandoned Mine Program (RAMP).

RAMP funds could be appropriated by Congress to eliminate noncoal hazards such as lead and zinc in the Tar Creek Superfund area.

AML Trust Funds dedicated to RAMP have grown to over $254 million because there have been no Congressional appropriations to RAMP since 1995.

Oklahoma Department of Mines.

The Oklahoma Department of Mines (ODM) regulates all mining activities in Oklahoma.

ODM must follow The Surface Mining Control and Reclamation Act of 1977 (PL 95-87) when regulating active coal mining.

There is a programmatic connection between ODM and OCC.

Section 405(c) of PL 95-87 states that “The Secretary shall not approve, fund, or continue to fund a State abandoned mine reclamation program unless that State has an approved State regulatory program pursuant to section 503 of this Act.”

In other words, if OSM makes a finding that ODM is not properly administering it’s coal regulatory program, then AML funding to OCC could be frozen.

All lead/zinc underground mines operated under the Oklahoma State Mining Code.

In 1955 the Oklahoma Legislature passed a statute, Title 45, Sections 436 and 437, which provides that all open vertical mine shafts should be protected either by fencing or by plugging and filling.

It is further provided that any person, firm, or corporation that allows a vertical mine shaft to remain open shall be deemed negligent as a matter of law and shall further be guilty of a misdemeanor.

However, the law incorporated no provision or funds for closing and/or sealing those open shafts that were abandoned by companies no longer in business prior to enactment of the law.

The State Attorney General ruled that mere ownership of the land upon which there is an open mine shaft does not constitute maintenance, use, or abandonment of an open mine shaft.

The present landowner cannot be compelled, therefore, to fill, seal, fence or otherwise take safety measures for the protection of the public.

City and /or State Tax.

One funding possibility is for the local and/or state citizens to vote on a tax that would generate revenue for mine shaft closures.

Oklahoma Legislature.

The Oklahoma Legislature could appropriate funds to address the safety hazards associated with the underground mines.

These funds could be matched with federal funds to maximize the reclamation efforts.

Special Congressional Appropriations/Legislation.

Special appropriations could be in the form of a Congressional line-item appropriation that specifically directs the funds to be spent on the abandoned lead and zinc mine hazards.

It is also possible for a new law to be passed that would direct an agency to reclaim the lead and zinc mine hazards.

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Donations.

Individuals or groups could donate to a fund that would be used solely for the purpose of reclaiming the hazards associated with the abandoned lead and zinc mines.

These donations could possibly be used to match federal funds.

Recommendations for Task 2

1. Investigate thoroughly the underground features of a shaft in order to select the most practical closure method.

After reviewing both past and current methods for closing mine shafts, backfilling is the preferred method of sealing shafts which open into cavities that are less than 20 feet high.

If the cavity is greater then 20 feet high, other suggested methods are a concrete cap, a concrete wedge, or a concrete plug.

2. Plug all open drill holes 10 inches in diameter or larger with concrete to a depth of 10 feet.

3. Begin discussions with the Environmental Protection Agency (EPA) to approve a Mine Shaft Closure Program that would have federal/state matching funds of 9:1.

These matching funds would be approved if the mine closures have a positive effect on water quality.

4. Secure state matching funds from the Legislature at $200,000 per year for 5 years.

5. Secure additional funding commitments from other agencies, groups, or individuals for closure of mine shafts and mine-related openings.

Coordinate a tri-state Congressional effort to help secure funding.

The timeline for completing Task 2: 5 years

The total cost to accomplish Task 2: $10 million.

Click On The Tar Creek Superfund Juggler'To Go Back To The Top Of These Documents

APPENDIX B

CLOSURE METHODS

Backfill Method

Definition:

On-site or imported soil material, gravel, rock or grout entirely filling the shaft from bottom to top using either dry or wet material placed by gravity or under pressure.

Pros:

Life span: Permanent

Degree of hazard elimination: Total

Maintenance: Maintenance-free

Construction safety: With proper equipment, workers’ exposure to the mine hazard is low.

Exposure to bad air is low with some conveyance methods.

Environmental concerns : If on-site material is used, spoil piles may be eliminated.

Design concerns : Generally low-tech or standard technology used (grout pumps).

Cost: Can be cheap if on-site material is used.

Cons:

Life span: NA

Degree of hazard elimination: NA

Maintenance: NA

Construction safety: Workers must be protected from falling into the shaft.

Shaft collars are often unstable.

Environmental concerns : Source material must be reclaimed.

Backfill material must be benign.

Design concerns : Backfill material must fill the entire shaft.

False plugs must be avoided.

Heavy equipment access is necessary.

Cost: May be expensive if grout or imported material is required.

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Backfill Examples with Costs

State of Missouri - DNR Land Reclamation Program(Lead and Zinc Mines)

Logan Shaft #1

On-site “Bull Rock” was screened (greater than 4" and less than 24") and used to fill the shaft to within 40 feet of the surface.

The remainder of the hole was filled with a bull rock/chat mix and then mounded.

Size: 10 x 12 x 160 ft.

Condition: Open, water-filled

Date Completed: April 2000

Cost: $14,190



Logan Shaft #3

Shot rock (limestone) and crushed stone were brought in from off-site to fill the shaft.

Size: 20 x 30 x 190 ft.

Condition: Open, water-filled

Date Completed: December 1997

Cost: $15,659



Magers Shaft

The shaft was partially backfilled with rock, but the rock kept settling.

Therefore, a reinforced concrete cap was used.

Size: 10 x 10 x 185 ft.

Condition: Open, water-filled

Date Completed: November 1997

Cost: $24,990

State of Missouri (Coal mine)



Cainsville Shaft

Regarding mine features before closure, the mine shaft was water-filled to within 40 feet of the ground surface.

Shot rock (from off-site) was conveyed to the mine opening due to the instability around the shaft.

The mine shaft was totally filled using the shot rock.

Size: 15 x 14 x 480 ft.

Condition: Open, water-filled

Date Completed: October 1995

Cost: $62,991



State of Oklahoma - Oklahoma Conservation Commission (Coal Mines)

Steckelberg Mine Shaft

The open shaft had very stable concrete cribbing. Off-site rock (208 tons) was placed in the bottom of the shaft.

On-site fill material was then used to complete the shaft closure.

Size: 11 x 9 x 77 ft.

Condition: Open, dry

Date Completed: July 1999

Cost: $10,120


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Howe Mine Shaft

Several loads of off-site rock were used to establish a base.

On-site fill material was then used to fill the shaft.

The reason the cost for this closure was lower than others in the area was that the fill material was within 30 feet of the shaft.

Size: 10 x 10 x 292 ft.

Condition: Open, water-filled

Cost: $3,150

Date Completed: October 1992



Le Fevers (Turnipseed) Mine Shaft

Several loads of off-site rock were used to establish a base.

On-site fill material was then used to fill the shaft.

The on-site fill material had to be hauled a long distance, therefore the cost is considerably higher than other mine shaft closures.

Size: 6 x 6 x 62 ft.

Condition: Open, water-filled

Date Completed: November 1994

Cost: $3,900


Witteville Mine Shaft

Several loads of off-site rock were used to establish a base.

On-site material was then used to fill the shaft.

Size: 8 x 8 x 30 ft.

Condition: Open, water-filled

Date Completed: October 1992

Cost: $3,400


State of Wyoming

Abandoned Mine Lands Division of the Department of Environmental Quality (Iron-ore Mines)

Sunrise West Shafts

The 23 vertical shafts were all dry with solid rock bottoms.

All the shafts were filled with on-site material.

Size: 4 to 6 ft. x 9½ to 10 ft. x 3½ to 67 ft.

Condition: Open, dry

Date Completed: May - 1997


Cost: $316. 67

(9 shafts that were less than 10 ft. deep)

$513.33

(6 shafts that were 10 to 20 ft. deep)

$712.50

(8 shafts that were greater than 20 ft. deep)

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State of Indiana

Division of Reclamation Indiana Department of Natural Resources (Coal Mines)

Mine Shaft/Subsidence 633 (Project E23-122)

All trash and junk was removed from the shaft and hauled to a landfill.

A base was excavated to a depth of 50 feet before the shaft was filled.

On-site concrete rubble no larger than 24 inches was used as first fill in the shaft.

Off-site gravel was used to fill the shaft.

A 3-foot soil cover was mounded over the gravel.

Size: 10 x 15 x 50 to 100 ft.

Condition: Open, water-filled

Date Completed: early 1990s

Cost: $62,649


Mine Shaft/Subsidence 621 (Project E23-122)

Water was pumped from the shaft.

All trash was removed from the shaft.

A base was excavated to a depth of 25 feet before the shaft was filled.

Off-site riprap was used to fill the shaft.

Size: 10 x 15 x 50 to 100 ft.

Condition: Open, water-filled

Date Completed: early 1990s

Cost: $16,718


Mine Shaft/Subsidence Site 570

It was intended that the filled openings would continue to accept run-off water, therefore it was important that only revetment riprap be used in the initial filling of the shaft.

The riprap fill was left exposed to allow the filled areas to continue to accept run-off water.

Size: 8 x 8 x 50 to 100 ft.

Condition: Open, water-filled

Date Completed: early 1990s

Cost: $21,744


Source:

Indiana Department of Natural Resources

Example of Backfill Method

Source:

Indiana Department of Natural Resources

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Concrete Cap Method

Definition:

A structural concrete cap either cast in place or using precast panels and beams.

Pros

Life span: Permanent (100 years)

Degree of hazard elimination: Total

Maintenance: None required

Construction safety: Workers do not need to work in the shaft.

Environmental concerns : Minimal site disturbance.

Design concerns : Can prefab panels for standardized closures. Minimal site-specific engineering required.

Cost: Relatively low cost

Cons

Life span: NA

Degree of hazard elimination: NA

Maintenance: NA

Construction safety: NA

Environmental concerns : Prevents bat access

Design concerns:

Need competent rock to bear slab.

Cap must be large enough to overlap all sides of shaft.

Doesn’t prevent collapse of sidewalls.

Need access for concrete trucks or prefab panels.

Cost: NA

Concrete Cap Examples with Costs

State of Oklahoma

Grand Gateway Economic Development Association and the Oklahoma Department of Environmental Quality (Lead and Zinc Mines)

Shaft 00-03

The shaft had concrete cribbing, in good condition, that extended 50 feet below ground surface to just above the water level in the shaft.

The water level in the shaft was about 60 feet below ground surface.

A re-enforced, precast concrete cap (4,000 psi concrete with ½ inch diameter rebar at 1-foot spacing) was transported to the site and placed over

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the shaft using a track hoe.

Chat and soil were then placed on the sides of the cap to close any gaps between the cap and the shaft.

Size: 5 x 7 x more than 100 ft.

Condition: Open, water-filled

Date Completed: January 2000

Cost: $2,000


State of Oklahoma

Oklahoma Conservation Commission (Coal Mines)

Milby-Dow Shaft

A concrete cap (12in. thick x 26ft. x 24ft.) was poured in place using fin. rebar on 12in. centers.

The concrete cylinder test was 4,000 psi after 28 days.

Size: 12 x 14 x 350 ft.

Condition: Open, dry

Date Completed: March 1984

Cost: $14,988


State of Colorado

Colorado Abandoned Mine Program (Precast Panels on Coal and Noncoal Mines)

Panels were preconstructed in five different weights and sizes:

5 x 5 ft., weighing 2,000 lbs.

3 x 12 ft., weighing 3,000 lbs.

5 x 10 ft., weighing 4,000 lbs.

6 x 12 ft., weighing 6,000 lbs.

3 x 18 ft., weighing 6,000 lbs.

The surface of the ground was excavated to competent bedrock and leveled to form a footing.

Low foundation areas, if present, were filled with gravel or waste rock to form a level footing or pad.

Concrete footings were constructed for sites where the foundation surface was lacking or was incompetent.

Panels were placed directly on the bedrock, gravel, or concrete footings with at least 2 feet of overlap.

For larger openings, the narrower panels were often used as supportive beams.

Two of the narrower panels were placed at each end of the opening, and one was placed across the middle of the opening.

The wider panels were then placed over the panel beams.

Panels were connected to each other using steel tie bars.

The weight of the panels was usually sufficient for anchoring.

But in situations where the ground is sloped greater than 15 degrees, the panels can be anchored with rebar embedded and grouted into the bedrock (Colorado - 1993).

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When shaft openings were large, one or more epoxy resin or tar coated steel beams were placed across the opening and secured to the footings with concrete.

Panels were placed over the steel beams perpendicularly with at least 2 feet of overlap beyond the shaft edge to provide a reliable foundation.

Cost for precast panels vary depending on the size of the opening and other site conditions but typically range from about $3,000 to $7,000 (1993).

Concrete Plug Method

Definition:

Concrete and rock plug formed over caved material or temporary forms.

Pros

Life span: Permanent (100 years)

Degree of hazard elimination: Total

Maintenance: None

Construction safety: No hazard to workers if no form work is required.

Environmental concerns : Disturbs only a small area around shaft.

Design concerns :
Provides support of sidewalls of shaft near surface.

Plug remains functional should cave material below plug fails.

Cost: Low to moderate cost.


Cons

Life span: NA

Degree of hazard elimination: NA

Maintenance: NA

Construction safety: May require workers to construct a bulkhead inside shaft with unstable sidewalls and hazardous atmospheres.

Environmental concerns : NA

Design concerns : Bulkhead must be constructed in competent rock.

Cost: Can be high if shoring required to safely install bulkhead.

Concrete Plug Examples with Costs

State of Oklahoma Grand Gateway Economic Development Association and the Oklahoma Department of Environmental Quality (Lead and Zinc Mines)

Shaft 00-01

The water in the mine shaft was 50 feet below the ground surface.

Soil around the shaft was excavated to approximately 8 feet in diameter.

A MTM 8.5 cubic yard concrete mixing drum (7.52 feet in diameter) was placed in the open shaft using a track hoe.

Concrete (8.5 cubic yards of 3,500 psi concrete) was then placed in the drum.

Boulders

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were placed inside the drum.

The sealed shaft was covered with adjacent chat and soil.

The area was graded in order for the surface water to drain away from the sealed shaft.

Size: 5 x 7 x greater than 100ft.

Condition: Open, water-filled, wooden cribbing

Date Completed: January 2000

Cost: $7,000


State of Oklahoma Ottawa Reclamation Authority (Lead and Zinc Mines)

In the 1980s several open mine shafts were closed using either wooden, cube-shaped frames filled with concrete or concrete mixer bodies that were also filled with concrete.

The plugs were then pushed into the open shafts at an approximate cost of $2,500 to $3,500 a piece.

U.S. Department of the Interior

Office of Surface Mining (Coal Mines)

Lawson No. 10 Mine Shaft

This open shaft was located in the state of Washington.

Logs were used as a temporary bulkhead.

The concrete plug was formed using soil/rock.

The depth of the plug and thickness of the concrete was designed to be in competent rock.

Size: 6 x 6 x more than 400 ft.

Condition: Open, dry

Date Completed: September 1999

Cost: $29,019.16


Wedge Method

Definition:

Steel cone or wedge fabricated on-site and filled with concrete.

Pros

Life span: Permanent (100 years)

Degree of hazard elimination: Total

Maintenance: None

Construction safety: Wedge can be fabricated remotely and lifted into shaft.

No workers in shaft.

Environmental concerns : Small surface disturbance if competent rock near surface.

Design concerns : Concrete and wedge can be placed with helicopter in remote locations.

Cost: NA

Cons

Life span: NA

Degree of hazard elimination:

Maintenance: NA

Construction safety: NA

Environmental concerns : Large excavation if competent rock greater than 15 feet deep.

Design concerns: Need competent rock to bear wedge form or increase size of structure on unconsolidated material.

Either need access for steel and concrete trucks, or use helicopters to fly in materials.

Cost: Relatively expensive


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Wedge Examples with Costs

U.S. Department of the Interior

Office of Surface Mining (Coal Mines)

Tiger Mountain/Ravensdale Project

A concrete-filled wedge was used to close the mine shaft in Kings County, Washington.

The project manager said this was a maximum size for using a wedge.

This cost was low due to several factors.

Today’s cost would probably be twice as high, unless several closures were bid in one contract.

Size: 14 x 14 x more than 400 ft.

Condition: Open, dry

Completed Date: July 1996

Cost: $13,000


U.S. Department of the Interior

Bureau of Mines (Lead and Zinc)

Galena, Kansas Demonstration Project

The inverted pyramid-shaped forms, fabricated from steelplate, were designed so that the inverted base would be larger, by 4 feet on a side, than the approximate size of the shaft opening at the surface residuum-solid rock interface.

After the surface openings of the shafts were trimmed with a backhoe, the steel forms, complete with reinforcing, were lowered into the openings and filled with concrete.

The remaining portions of the openings above the filled wedge were backfilled to slightly above the surrounding surface level with on-site waste rock and soil.

Size: 11 shafts that were roughly square and ranged from 4 to 8 feet.

Condition: Open, water-filled

Completed Date: 1985

Cost: Approximately $10,000 per shaft


Source: U.S. Department of the Interior, Office of Surface Mining

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Polyurethane Foam (PUF) Plug Method

Definition:

Two-part polyurethane foam plug formed in place and covered with earth or waste rock.

A detailed description can be found in “Shaft Closures Using Polyurethane Foam,”

Proceedings:

Symposium of Evolution of Abandoned Mine Land Technologies, Riverton, WY, June 14-16, 1989.

Pros

Life span: Permanent

Degree of hazard elimination: Total

Maintenance: Maintenance-free

Construction safety: Workers can install closure from ground level.

Environmental concerns : Once mixed, PUF is inert. Can be installed in historic structures without damaging them.

Design concerns : Can accommodate poor access situations. Can be used as formwork for concrete closures.

Cost: Installation costs are relatively low.

Cons

Life span: Fairly new technique with only about 10 years of history.

Degree of hazard elimination: NA

Maintenance: Potential for vandalism if cover material removed.

Construction safety: Exposure to falling because of necessity to work around collar of shaft.

Exposure to toxic materials and fumes.

Environmental concerns : Unmixed chemicals are toxic. Exposed PUF will support combustion and will degrade in ultraviolet light.

Design concerns : Installation procedures are critical to closure success.

Cost: Material expense is high.


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PUF Examples with Costs

State of Wyoming

Abandoned Mine Lands Division of the Department of Environmental Quality (Hardrock Mines)

Red Boy Mine West Shaft

There were two interconnected vertical shafts.

One of the shafts had wood cribbing that had to be preserved.

The shafts were also inhabited by Townsend’s Big Eared Bats.

The shaft was closed with approximately 100 cubic yards of polyurethane foam (PUF).

Two 36-inch HDPE culverts with bat grates were placed in the shafts and encased in PUF.

Size: 5 x 7 x 70 ft. (Two shafts)

Condition: Open, dry

Date Completed: August 1996

Cost: $40,045


Red Boy East Shaft

This shaft also had wood cribbing.

The shaft was closed with approximately 15.5 cubic yards of PUF, followed by a concrete cap and on-site fill material.

Size: 5 x 7 x 30 ft.

Condition: Open, dry

Date Completed: August 1996

Cost: $2,725


Red Boy Shaft No. 3

This shaft was closed using approximately 45 cubic yards of PUF, followed by a concrete cap and on-site fill material.

Size: 9 x 13 x 25 ft. Example of PUF Plug Method

Condition: Open, dry

Date Completed: August 1996

Cost: $10,530


Source:U.S. Department of the Interior, Bureau of Mines

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Hollow Core Plug Method

Definition:

Wedge- or cone-shaped concrete plug with a rectangular opening in the center.

Pros

Life span: Permanent

Degree of hazard elimination: Total

Maintenance: Generally maintenance-free

Construction safety: NA

Environmental concerns : Minimal disturbance away from shaft.

Design concerns : Accommodates unstable shaft collars by settling down/jamming as collapse occurs. Allows access to and ventilation of mine workings if necessary.

Cost: NA

Cons

Life span: NA

Degree of hazard elimination: NA

Maintenance: Cap/grate over opening may be vandalized.

Construction safety: Exposure to falling and collapsing shaft collars. Must work down in the shaft to install formwork.

Environmental concerns : NA

Design concerns : Requires reinforced formwork to accommodate massive concrete.

Cost: Fairly high


Hollow Core Plug Examples with Costs

U.S. Department of the Interior

Bureau of Mines

“Closure Methods For Inactive and Abandoned Mine Openings,” December 1995

The U.S. Bureau of Mines report indicated that the states of Colorado and Wyoming construct hollow core concrete shaft plugs.

These types of plugs are hollow in the center but use supportive concrete structures or corrugated metal pipes to stabilize shafts located in unconsolidated material or that have unstable shaft walls.

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In the Wyoming plug, a corrugated pipe is placed in the shaft to support the shaft walls.

A steel plate cap is welded to the top of the pipe, and the plug is poured on top of the pipe.

The surface of the plug is backfilled over.

A vent pipe can be added to this design if needed.

The average cost (1989) for the Wyoming plug with pipe is $3,800.


Example of Hollow Core Method

Colorado constructs a hollow core plug where permanent wood formworks are placed in the center of the shaft, rocks are placed to hold the formwork steady, and concrete is poured between the form-work and the sides of the shaft walls creating supportive footings.

A concrete slab, either precast or poured-in-place, is placed over the footings to close the opening.

Average cost (1992) for the Colorado hollow core shaft plug is $7,800.


Source:

U.S. Department of the Interior, Bureau of Mines

Example of Hollow Core Method

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APPENDIX C

POTENTIAL FUNDING SOURCES FOR CLEANUP

OF THE TAR CREEK SUPERFUND AREA

Environmental Protection Agency (EPA)

The information for most of this review came from the Environmental Protection Agency (EPA) web site located at www.epa.gov/superfund/whatissf/cercla.htm.

The mining waste in the site contains lead and other hazardous substances as defined by the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), 42 U.S.C. §§9601 to 9675, also known as the Superfund law.

Mining waste at the Site contains CERCLA hazardous substances, but the waste is not a hazardous waste under the Resource Conservation and Recovery Act (RCRA), Subtitle C.

The mining wastes at the site are solid waste from the extraction, beneficiation, and processing of ores and minerals that are excluded from regulation as a hazardous waste under RCRA, Subtitle C, according to 40 CFR §261.4(b)(7).

This exclusion was based on the Bevill Amendment to RCRA. However, chat does fall under the authority of Superfund since it contains CERCLA hazardous substances.

Although chat is not regulated by federal hazardous waste management laws (i.e., RCRA, Subtitle C) designed to prevent releases into the environment,

Superfund authorizes EPA to cleanup material like chat that is contaminated with hazardous substances.

Under Superfund, the term “release” means any spilling, leaking, pumping, pouring, emitting, emptying, discharging, injecting, escaping, leaching, dumping, or disposing into the environment (including the abandonment or discarding of barrels, containers, and other closed receptacles containing any hazardous substance or pollutant or contaminant).

CERCLA Overview

Congress enacted CERCLA, commonly known as Superfund, on December 11, 1980.

This law created a tax on the chemical and petroleum industries and provided broad federal authority to respond directly to releases or threatened releases of hazardous substances that may endanger public health or the environment.

Over five years $1.6 billion was collected and the tax went to a trust fund for cleaning up abandoned or uncontrolled hazardous waste sites.

CERCLA:

Established prohibitions and requirements concerning closed and abandoned hazardous waste sites.

Provided for liability of persons responsible for releases of hazardous waste at these sites.

Established a trust fund to provide for cleanup when no responsible party could be identified.

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The law authorizes two kinds of response actions:

Short-term removals where actions may be taken to address releases or threatened releases requiring prompt response.

Long-term remedial response actions that permanently and significantly reduce the dangers associated with releases or threats of releases of hazardous substances that are serious but not immediately life threatening.

These actions can be conducted only at sites listed on EPA's National Priorities List (NPL).

CERCLA also enabled the revision of the National Oil and Hazardous Substances Pollution Contingency Plan, more commonly called the National Contingency Plan or NCP.

The NCP provided the guidelines and procedures needed to respond to releases and threatened releases of hazardous substances, pollutants, or contaminants.

The NCP also established the NPL.

The National Contingency Plan is the federal government's blueprint for responding to both oil spills and hazardous substance releases.

The NCP is the result of efforts to develop a national response capability and promote overall coordination among the hierarchy of responders and contingency plans.

CERCLA was amended by the Superfund Amendments and Reauthorization Act (SARA) on October 17, 1986.

SARA reflected EPA's experience in administering the complex Superfund program during its first six years and made several important changes and additions to the program.

SARA:

Stressed the importance of permanent remedies and innovative treatment technologies in cleaning up hazardous waste sites.

Required Superfund actions to consider the standards and requirements found in other state and federal environmental laws and regulations.

Provided new enforcement authorities and settlement tools.

Increased state involvement in every phase of the Superfund program.

Increased the focus on human health problems posed by hazardous waste sites.

Encouraged greater citizen participation in making decisions on how sites should be cleaned up.

Increased the size of the trust fund to $8.5 billion.

CERCLA covers all environmental media - air, surface water, ground water, and soils.

It also can apply to any type of industrial, commercial, or noncommercial facility regardless of whether there are specific regulations affecting that type of facility or how that facility might affect the environment.

These are called applicable or relevant and appropriate requirements (ARARs) of other environmental laws.

CERCLA §104 (42 U.S.C. §9604) authorizes the federal government to respond to releases of hazardous substances and pollutants or contaminants into the environment.

CERCLA §105 (42 U.S.C. §9605) requires EPA identify uncontrolled or abandoned hazardous waste sites and to prioritize them for cleanup.

The high priority sites are placed on a NPL, enabling EPA to use Trust Fund monies to clean up the sites.

The Tar Creek Superfund Site was placed on the NPL on September 8, 1983.

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CERCLA §111 (Title 42 U.S.C. §9611) allows the Hazardous Substances Trust Fund monies to be used for any necessary costs incurred as a result of cleaning up a site.

The state must match this with 10 percent.

CERCLA §118 (Title 42 U.S.C. §9618) places a high priority for drinking water supplies where the release of hazardous substances or pollutants or contaminants has resulted in the closing of drinking water wells or has contaminated a principal drinking water supply.

CERCLA §123 (Title 42 U.S.C. §9623) allows for reimbursement to local governments affected by a release or threatened release at any facility.

The monies will be paid for any expenses incurred in carrying out temporary emergency measures necessary to prevent or mitigate injury to human health or the environment associated with the release or threatened release of any hazardous substance or pollutant or contaminant.

Additional federal environmental laws that the Environmental Protection Agency (EPA) uses to carry out its work are as follows:

1938 Federal Food, Drug, and Cosmetic Act

1947 Federal Insecticide, Fungicide, and Rodenticide Act

1948 Federal Water Pollution Control Act (also known as the Clean Water Act)

1955 Clean Air Act

1965 Shoreline Erosion Protection Act

1965 Solid Waste Disposal Act

1970 National Environmental Policy Act

1970 Pollution Prevention Packaging Act

1970 Resource Recovery Act

1971 Lead-Based Paint Poisoning Prevention Act

1972 Coastal Zone Management Act

1972 Marine Protection, Research, and Sanctuaries Act

1972 Ocean Dumping Act

1973 Endangered Species Act

1974 Safe Drinking Water Act

1974 Shoreline Erosion Control Demonstration Act

1975 Hazardous Materials Transportation Act

1976 Resource Conservation and Recovery Act

1976 Toxic Substances Control Act

1977 Surface Mining Control and Reclamation Act

1978 Uranium Mill-Tailings Radiation Control Act

1980 Asbestos School Hazard Detection and Control Act

1980 Comprehensive Environmental Response, Compensation, and Liability Act

1982 Nuclear Waste Policy Act

1984 Asbestos School Hazard Abatement Act

1986 Asbestos Hazard Emergency Response Act

1986 Emergency Planning and Community Right to Know Act

1988 Indoor Radon Abatement Act

1988 Lead Contamination Control Act

1988 Medical Waste Tracking Act

1988 Ocean Dumping Ban Act

1988 Shore Protection Act

1990 National Environmental Education Act

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Oklahoma Department of Environmental Quality (DEQ)

The Waste Management Division of the Oklahoma Department of Environmental Quality has the responsibility to carry out activities as required by State of Oklahoma Environmental Quality Code §27 A-2-6-105 and the CERCLA laws.

These programs provide for the cleanup of contaminated sites when public health or the environment are threatened by improperly handled or abandoned hazardous substances. The following pertinent sections of the State of Oklahoma Environmental Quality Code were provided by DEQ.

The creation of the Oklahoma Department of Environmental Quality can be found in §27A-2-3- 101 of the State of Oklahoma Environmental Quality Code.

§27A-2-3-101

A. There is hereby created the Department of Environmental Quality.

B. Within its jurisdictional areas of environmental responsibility, the Department of Environmental Quality, through its duly designated employees or representatives, shall have the power and duty to:

1. Perform such duties as required by law; and

2. Be the official agency of the State of Oklahoma, as designated by law, to cooperate with federal agencies for point source pollution, solid waste, hazardous materials, pollution, Superfund, water quality, hazardous waste, radioactive waste, air quality, drinking water supplies, waste water treatment and any other program authorized by law or executive order.

The enforcement concerning the restriction of the use of chat is based upon the public nuisance law, which can be found in the water quality section of the State of Oklahoma Environmental Quality Code §27A-2-6-105. It is entitled “Pollution of state air, land or waters--Order to cease.”

§27A-2-6-105

A. It shall be unlawful for any person to cause pollution of any waters of the state or to place or cause to be placed any wastes in a location where they are likely to cause pollution of any air, land or waters of the state. Any such action is hereby declared to be a public nuisance.

B. If the Executive Director finds that any of the air, land or waters of the state have been, or are being, polluted, the Executive Director shall make an order requiring such pollution to cease within a reasonable time, or requiring such manner of treatment or of disposition of the sewage or other polluting material as may in his judgment be necessary to prevent further pollution.

It shall be the duty of the person to whom such order is directed to fully comply with the order of the Executive Director. Some of the funding available from the State of Oklahoma can be found in State of Oklahoma Environmental Quality Code §27A-2-7-121 and §27A-2-10-802.

§27A-2-7-121

E. All fees and other monies received by the Department pursuant to the provisions of this section shall be expended solely for the purposes specified in this section.

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1. Ten percent (10%) of the fees collected from an off-site hazardous waste facility pursuant to the provisions of this section shall be deposited to the credit of the Special Economic Development Trust Funds.

The funds for the Trusts accruing pursuant to the provisions of this section shall be distributed to each Trust established in proportion to the fees generated by the off-site hazardous waste facilities within the Trust area.

2. The Department shall expend monies received pursuant to the provisions of this section for one or more of the following purposes:

A. the administration of the provisions of the Oklahoma Hazardous Waste Management Act,

B. the development of an inventory of hazardous wastes currently produced in Oklahoma and management needs for the identified wastes,

C. the implementation of information exchange, technical assistance, public information, and educational programs,

D. the development and encouragement of waste reduction plans for Oklahoma waste generators, or

E. increased inspection of hazardous waste facilities which may include full time inspectors at off-site hazardous waste facilities.

F. To the extent that fees received pursuant to this section shall exceed the purposes specified in subsection E of this section, the Department shall only expend such funds for one or more of the following purposes:

1. Contributions required from the state pursuant to the federal Comprehensive Environmental Response, Compensation and Liability Act for remediation or related action upon a site within the state;

2. Response, including but not limited to containment and removal, to emergency situations involving spillage, leakage, emissions or other discharge of hazardous waste or hazardous waste constituents to the environment where a responsible party cannot be timely identified or found or compelled to take appropriate emergency action to adequately protect human health and the environment;

3. State-funded remediation of sites contaminated by hazardous waste or hazardous waste constituents so as to present a threat to human health or the environment, to the extent that a responsible party cannot be timely identified or found or compelled to take such action, or is unable to take such action;

4. Costs incurred in pursuing an enforcement action to compel a responsible party to undertake appropriate response or remedial actions, or to recover from a responsible party monies expended by the state, as described in paragraphs 1 through 3 of this subsection; or

5. Financial assistance to municipalities or counties for the purposes and under the conditions specified in Section 2-7-305 of this title.

§27A-2-10-802

A. 1. Owners or operators of landfill disposal sites which are not generator owned and operated nonhazardous industrial waste monofills shall install scales by January 1, 1996.

Such scales shall be installed on or within five (5) miles of the landfill disposal site and shall be tested and certified as required by Section 5-61e of Title 2 of the Oklahoma Statutes relating to the authority of the Board of Agriculture to test annually the standards

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of weights and measures used by any city or county within the state and to approve if found to be correct.

B. 1. Except as otherwise provided by this subsection, on and after January 1, 1996:

a. owners and operators of landfill disposal sites which receive an average of less than one hundred (100) tons of solid waste per operating day shall assess a fee of One Dollar and fifty cents ($1.50) per ton of solid waste received for disposal.

A total of fifty cents ($.50) per ton of such fee shall be retained by the owner or operator and used exclusively for capital improvement to their facilities and for the projects required pursuant to the Oklahoma Solid Waste Management Act or the disposal site's permit for such period of time necessary to recoup a capital investment, plus the interest costs expended in purchasing the scales, of a total of Forty Thousand Dollars ($40,000.00)

b. when the owner or operators have recouped a capital investment of the total specified in subparagraph a of this paragraph, the fee to be assessed shall be One Dollar and twenty-five cents ($1.25) per ton of solid waste received for disposal.

At such time, for a return with remittance filed on or before the due date, the owner or operator may deduct and retain ten percent (10%) of the fees collected, and

c. records documenting the projects and use of the funds shall be included with each return.

2. a. Owners and operators of landfill disposal sites which receive an average of more than one hundred (100) tons of solid waste per operating day shall assess a fee of One Dollar and fifty cents ($1.50) per ton of solid waste received for disposal, retaining twenty-five cents ($0.25) per ton for a period of time necessary to recoup a capital investment, plus the interest costs expended in purchasing the scales, of Forty Thousand Dollars ($40,000.00)

At the end of such period the fee shall revert to One Dollar and twenty-five cents ($1.25) per ton. For a return with remittance filed on or before the due date, the owner or operator may deduct and retain ten percent (10%) of the fees collected.

b. Records documenting the capital investment and the use of the funds shall be included with each return.

C. 1. The Department shall expend funds collected pursuant to the provisions of this section solely for the administration and enforcement of the provisions of the Oklahoma Solid Waste Management Act and for the development of solid waste technical assistance programs, solid waste public environmental education programs and educational curricula, solid waste studies, development of a statewide solid waste plan, solid waste recycling and litter prevention programs, and other environmental improvements.

5. a. The Department, in conjunction with the Corporation Commission, the Oklahoma Energy Resources Board and the Oklahoma Conservation Commission, may develop a plan to use suitable portions of the solid waste stream to reclaim Oklahoma lands damaged by oil and gas exploration and production or by surface mining activities.

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The United States Army Corps of Engineers (COE)

Section 22

Planning Assistance to States (PAS) Program of The Water Resources Development Act of 1974. The PAS Program is part of a group of laws that authorizes the Corps of Engineers’ involvement in water resource studies.

The program was authorized by the Water Resources Development Act of 1974 and gives the Corps the authority to use its technical expertise in water and related resource management to help states and Native American tribes with their water resource problems. The program is funded annually (maximum of $10 million), and funds are distributed on a priority basis.

Each state or tribe can receive up to $500,000 annually.

Federal funds are matched equally with non-federal funds provided by the study sponsor. Cost sharing is arranged through letter agreements signed by the Corps District Engineer and the head of the sponsoring agency. In Oklahoma the Corps works through the Oklahoma Water Resources Board and in Kansas through the Kansas Water Office.

The Corps also works with Native American tribes but have only had one tribal PAS study to date due to limited PAS funds. Study purposes are varied under the PAS Program and have included evaluations of water and waste-water systems, port development on the navigation system, design studies on water supply lakes, and economic and environmental evaluation of proposed projects. PAS studies do not lead to federal construction projects. An environmental evaluation may be helpful to determine if this project is eligible for funding due to environmental concerns.

Section 206

Aquatic Ecosystem Restoration of The Water Resources Development Act of 1996. The Aquatic Ecosystem Restoration Program may be applicable in areas where acid mine drainage (AMD) exists.

This section authorizes the Corps to carry out aquatic ecosystem restoration projects if they will improve environmental quality, are in the public interest, and are cost-effective. To be funded a project must be for restoration of aquatic ecosystem structure and function.

This will usually include manipulation of the hydrology in and along bodies of water, including wetlands and riparian areas. No relationship to an existing Corps project is required. To start the process the local sponsor sends the Corps a letter of request. That letter would not obligate the local sponsor to any financial outlay.

The Corps’ first effort would be the completion of a fully federally-funded preliminary restoration plan. If the environmental restoration project is approved for implementation, the feasibility study, plans and specs, and construction costs would be included as part of the total project modification cost to be shared 65 percent federal and 35 percent non-federal.

Usually, the non-federal sponsor would be responsible for the operation, repair, replacement, rehabilitation, and maintenance costs of the project. The local sponsor would provide its share of the project costs prior to the award of a construction contract.

The Abandoned Mine Restoration Act of 1999 (pending legislation).

106th CONGRESS H. R. 2753

1st Session

To authorize the Secretary of the Army to carry out a program for the restoration of abandoned mine sites.

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IN THE HOUSE OF REPRESENTATIVES

August 5, 1999

Mr. GIBBONS introduced the following bill; which was referred to the Committee on Resources, and in addition to the Committee on Transportation and Infrastructure, and Commerce, for a period to be subsequently determined by the Speaker, in each case for consideration of such provisions as fall within the jurisdiction of the committee concerned

A BILL To authorize the Secretary of the Army to carry out a program for the restoration of abandoned mine sites.

Be it enacted by the Senate and House of Representatives of the United States of America in Congress assembled,

SECTION 1. SHORT TITLE.

This Act may be cited as the ‘Abandoned Mine Restoration Act of 1999’.

SEC. 2. DEFINITIONS

In this Act, the following definitions apply:

1) NON-FEDERAL ENTITIES - The term ‘non-Federal entities’ includes nonprofit and private entities.

2) PROGRAM - The term ‘program’ means the program authorized under section 3(a).

3) SECRETARY - The term ‘Secretary’ means the Secretary of the Army.

SEC. 3. RESTORATION OF ABANDONED MINE SITES PROGRAM.

a) IN GENERAL - Subject to the requirements of this section, the Secretary may carry out a program to assist stewards of lands owned by the United States and non-Federal entities to address environmental and water quality problems caused by drainage and related activities from abandoned, inactive, and post-production noncoal mines. The program shall be managed by the head of the Sacramento District Office of the Corps of Engineers.

b) CONSULTATION - The Secretary shall coordinate actions taken under the program with appropriate Federal, State, and local agencies. Any project conducted under the program on lands owned by the United States shall be undertaken in consultation with the head of the Federal entity with administrative jurisdiction over the lands.

c) ASSISTANCE -

1) TYPES OF ASSISTANCE

In carrying out the program, the Secretary may provide technical, planning, design, restoration, remediation, and construction assistance to Federal and non-Federal entities for the purpose of carrying out projects to address problems described in subsection (a).

2) REQUIREMENT FOR ASSISTANCE

The Secretary may only provide assistance for a project under the program, if the Secretary determines that the project –

A) will improve the quality of the environment and is in the public interest; and

(B) is cost-effective.

(d) SPECIFIC MEASURES - Assistance may be provided under the program in support of a Federal or non-Federal project for the following purposes:

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1) Response, control, and remediation of hazardous, toxic, and radioactive waste and improvement of the quality of the environment associated with an abandoned, inactive, or post-production noncoal mine, if the Secretary finds that such activities are integral to carrying out the environmental restoration project.

2) Restoration and protection of streams, rivers, wetlands, and other waterbodies and all ecosystems degraded, or with the potential to become degraded, by drainage from an abandoned, inactive, or post-production noncoal mine.

3) Demonstration of treatment technologies, including innovative and alternative technologies, to minimize or eliminate adverse environmental effects associated with an abandoned, inactive, or post-production noncoal mine.

4) Demonstration of management practices to address environmental effects associated with an abandoned, inactive, or post-production noncoal mine.

5) Remediation and restoration of an abandoned, inactive, or post-production noncoal mine site for public health or safety purposes.

6) Expedite the closure, remediation, or restoration of an abandoned, inactive, or postproduction noncoal mine to minimize adverse impacts to the environment.

e) COST-SHARING -

1) IN GENERAL

Except as provided by paragraph (2), the Federal share of the cost of a project carried out under the program shall be 65 percent of such cost.

2) PROJECTS ON FEDERAL LANDS

With respect to projects carried out under the program on Federal lands, the Federal share of the cost of the project shall be 100 percent of such cost.

f) CREDITS

For purposes of subsection (e), a non-Federal entity shall receive credit toward the non-Federal share of the cost of a project –

1) for all lands, easements, rights-of-way, and relocations, but not to exceed 25 percent of total project cost;

2) for design and construction services and other in-kind work;

3) for grants and the value, as determined by the Secretary, of work performed on behalf of the non-Federal entity by State and local agencies; and

4) for such costs as are incurred by the non-Federal entity in carrying out studies and any preconstruction, engineering, or design activities required for any construction to be conducted under the project, if the Secretary determines that such activities are integral to the project.

g) GRANTS AND REIMBURSEMENTS

1) GRANTS

The Federal share of the cost of a project under the program may be provided in the form of grants to the non-Federal entity or direct reimbursements to the non- Federal entity of project costs.

2) REIMBURSEMENTS

Subject to the availability of appropriations, the Secretary may reimburse a non-Federal interest an amount equal to the estimate of the Federal share, without interest, of the cost of any work (including work associated with studies, planning, design, and construction) carried out by the non-Federal entity otherwise made eligible for non-Federal assistance under this section.

3) REIMBURSEMENTS FOR CONSTRUCTION WORK

Reimbursements for construction work by a non-Federal entity as part of a project under the program may be made only –

A) if, before initiation of construction of the project, the Secretary approves the plans for construction of the project by the non-Federal entity;

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B) if the Secretary finds, after a review of studies and design documents prepared pursuant to this section, that construction of the project meets the requirements in subsection (d); and

C) if the Secretary determines that the work for which reimbursement is requested has been performed in accordance with applicable permits and approved plans.

h) OPERATION AND MAINTENANCE

The non-Federal share of operation and maintenance costs for a project carried out under the program shall be 100 percent, except that, in the case of a project undertaken on Federal lands, the Federal agency with management responsibility for the lands shall be responsible for all operation and maintenance costs.

i) EFFECT ON AUTHORITY OF SECRETARY OF THE INTERIOR

Nothing in this section shall affect the authority of the Secretary of the Interior under the Mining Law of 1872 or title IV of the Surface Mining Control and Reclamation Act of 1977 (30 U.S.C. 1231 et seq.).

j) COST LIMITATION

Not more than $10,000,000 of the amounts appropriated to carry out this section may be allotted for projects in a single locality, but the Secretary may accept funds voluntarily contributed by the non-Federal or Federal entity for the purpose of expanding the scope of the services requested by the non-Federal or Federal entity.

k) LIMITATION ON ACTIONS

Notwithstanding any other provision of law, the Secretary or any State or political subdivision (including any local district) which has implemented or will implement any remedial action which is consistent with a State and Environmental Protection Agency approved remediation plan, and any State approved modification thereof, at an abandoned mine site and adjacent lands to provide water quality protection, shall not be treated, based on actions taken consistent with the plan, to be –

1) the owner or operator of the site, or arranger or transporter for disposal;

2) responsible for any discharge or release of pollutants, contaminants, or hazardous substances on or from the abandoned mine site or adjacent lands, including discharges or releases which have been affected by the activities of the remedial action; or

3) subject to any enforcement action pursuant to Federal law, except for violations involving gross negligence.

In this subsection, the term ‘gross negligence’ means reckless, willful, or wanton misconduct.

l) WESTERN UNIVERSITIES MINE-LAND RECLAMATION AND RESTORATION CONSORTIUM

The Secretary may provide assistance to the Western Universities Mine-Land Reclamation and Restoration Consortium, which includes the University of Nevada, the New Mexico Institute of Mining and Technology, the University of Idaho, and the University of Alaska, for the purposes of carrying out the purposes of the program.

m) AUTHORIZATION OF APPROPRIATIONS

There is authorized to be appropriated to carry out this section $45,000,000 for fiscal years beginning after September 30, 1999.

Office of Surface Mining (OSM)

The Surface Mining Control and Reclamation Act of 1977 (PL 95-87) is the most comprehensive legislation for the elimination of abandoned mine land that affects the health and safety of the public. This law is administered by the U.S. Department of the Interior’s Office of Surface Mining (OSM) through annual grants to states and tribes.

Title IV, Abandoned Mine Reclamation (AML), of PL 95-87 dictates how the AML activities are carried out. Sections 401 through 403 provide information about the AML Trust Fund, reclamation fee, and objectives of the Trust Fund. These sections will provide a basic understanding on how and why the AML program was funded.

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TITLE IV – ABANDONED MINE RECLAMATION

ABANDONED MINE RECLAMATION FUND AND PURPOSES

SEC. 401.

a) There is created on the books of the Treasury of the United States a trust fund to be known as the Abandoned Mine Reclamation Fund (hereinafter referred to as the "fund") which shall be administered by the Secretary of the Interior.

State abandoned mine reclamation funds (State funds) generated by grants from this title shall be established by each State pursuant to an approved State program.

b) The fund shall consist of amounts deposited in the fund, from time to time derived from –

1) the reclamation fees levied under section 402;

2) any user charge imposed on or for land reclaimed pursuant to this title, after expenditures for maintenance have been deducted;

3) donations by persons, corporations, associations, and foundations for the purposes of this title;

4) recovered moneys as provided for in this title; and

5) interest credited to the fund under subsection (e).

c) Moneys in the fund may be used for the following purposes:

1) reclamation and restoration of land and water resources adversely affected by past coal mining, including but not limited to reclamation and restoration of abandoned surface mine areas, abandoned coal processing areas, and abandoned coal refuse disposal areas;

sealing and filling abandoned deep mine entries and voids; planting of land adversely affected by past coal mining to prevent erosion and sedimentation;

prevention, abatement,treatment, and control of water pollution created by coal mine drainage including restoration of stream beds, and construction and operation of water treatment plants;

prevention,abatement, and control of burning Sec. 401 coal refuse disposal areas and burning coal in situ;

prevention, abatement, and control of coal mine subsidence;

and establishment of selfsustaining,individual State administered programs to insure private property against damages caused by land subsidence resulting from underground coal mining in those States which have reclamation plans approved in accordance with section 503 of this Act:

Provided, That funds used for this purpose shall not exceed $3,000,000 of the funds made available to any State under section 402(g)

1) of this Act;

2) for transfer on an annual basis to the Secretary of Agriculture for use under section 406;

3) acquisition and filling of voids and sealing of tunnels, shafts, and entryways under section 409;

4) acquisition of land as provided for in this title;

5) enforcement and collection of the reclamation fee provided for in section 402 of this title;

6) studies, research, and demonstration projects by the Department of the Interior to such extent or in such amounts as are provided in appropriation Acts with public and private organizations, conducted in accordance with section 3501 of the Omnibus Budget Reconciliation Act of 1986 conducted for the purposes of this title;

7) restoration, reclamation, abatement, control, or prevention of adverse effects of coal mining which constitutes an emergency as provided for in this title;

8) grants to the States to accomplish the purposes of this title;

9) administrative expenses of the United States and each State to accomplish the

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purposes of this title;

10) for use under section 411;

11) for the purpose of section 507(c), except that not more than $10,000,000 shall annually be available for such purpose;

12) for the purpose described in section 402(h); and

13) all other necessary expenses to accomplish the purposes of this title.

d) Moneys from the fund shall be available for the purposes of this title, only when appropriated therefor, and such appropriations shall be made without fiscal year limitations.

e) The Secretary of the Interior shall notify the Secretary of the Treasury as to what portion of the fund is not, in his judgement, required to meet current withdrawals. The Secretary of the Treasury shall invest such portion of the fund in public debt securities with maturities suitable for the needs of such fund and bearing interest at rates determined by the Secretary of the Treasury, taking into consideration current market yields on outstanding marketable obligations of the United States of comparable maturities. The income on such investments shall be credited to, and form a part of, the fund.

RECLAMATION FEE

SEC. 402.

a) All operators of coal mining operations subject to the provisions of this Act shall pay to the Secretary of the Interior, for deposit in the fund, a reclamation fee of 35 cents per ton of coal produced by surface coal mining and 15 cents per ton of coal produced by underground mining or 10 per centum of the value of the coal at the mine, as determined by the Secretary, whichever is less, except that the reclamation fee for lignite coal shall be at a rate of 2 per centum of the value of the coal at the mine, or 10 cents per ton, whichever is less.

b) Such fee shall be paid no later than thirty days after the end of each calendar quarter beginning with the first calendar quarter occurring after the date of enactment of this Act, and ending September 30, 2004, after which time the fee shall be Sec. 402 established at a rate to continue to provide for the deposit referred to in subsection (h).

c) Together with such reclamation fee, all operators of coal mine operations shall submit a statement of the amount of coal produced during the calendar quarter, the method of coal removal and the type of coal, the accuracy of which shall be sworn to by the operator and notarized. Such statement shall include an identification of the permittee of the surface coal mining operation, any operator in addition to the permittee, the owner of the coal, the preparation plant, tipple, or loading point for the coal, and the person purchasing the coal from the operator.

The report shall also specify the number of the permit required under section 506 and the mine safety and health identification number. Each quarterly report shall contain a notification of any changes in the information required by this subsection since the date of the preceding quarterly report. The information contained in the quarterly reports under this subsection shall be maintained by the Secretary in a computerized database. (d)

1) Any person, corporate officer, agent or director, on behalf of a coal mine operator, who knowingly makes any false statement, representation or certification, or knowingly fails to make any statement, representation or certification required in this section shall, upon conviction, be punished by a fine of not more than $10,000, or by imprisonment for not more than one year, or both.

2) The Secretary shall conduct such audits of coal production and the payment of fees under this title as may be necessary to ensure full compliance with the provisions of this title. For purposes of performing such audits the Secretary (or any duly designated officer, employee, or representative of the Secretary) shall, at the reasonable times, upon request,

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have access to, and may copy, all books, papers, and other documents of any person subject to the provisions of this title. The Secretary may at any time conduct audits of any surface coal mining and reclamation operation, including without limitation, tipples and preparation plants, as may be necessary in the judgment of the Secretary to ensure full and complete payment of the fees under this title.

e) Any portion of the reclamation fee not properly or promptly paid pursuant to this section shall be recoverable, with statutory interest, from coal mine operators, in any court of competent jurisdiction in any action at law to compel payment of debts.

f) All Federal and State agencies shall fully cooperate with the Secretary of the Interior in the enforcement of this section. Whenever the Secretary believes that any person has not paid the full amount of the fee payable under subsection (a) the Secretary shall notify the Federal agency responsible for ensuring compliance with the provisions of section 4121 of the Internal Revenue Code of 1986.

(g)

1) Except as provided in subsection (h), moneys deposited into the fund shall be allocated by the Secretary to accomplish the purposes of this title as follows:

( A) 50 percent of the reclamation fees collected annually in any State (other than fees collected with respect to Indian lands) shall be allocated annually by the Secretary to the State, subject to such State having each of the following:

i) An approved abandoned mine reclamation program pursuant to section 405.

ii) Lands and waters which are eligible pursuant to section 404 (in the case of a State not certified under section 411(a)) or pursuant to section 411(b) (in the case of a State certified under section 411(a)).

B) 50 percent of the reclamation fees collected annually with respect to Indian lands shall be allocated annually by the Secretary to the Indian tribe having jurisdiction over such lands, subject to such tribe having each of the following:

i) an approved abandoned mine reclamation program pursuant to section 405.

ii) Lands and waters which are eligible pursuant to section 404 (in the case of an Indian tribe not certified under section 411(a)) or pursuant to section 411(b) (in the case of a tribe certified under section 411(a)).

C) The funds allocated by the Secretary under this paragraph to States and Indian tribes shall only be used for annual reclamation project construction and program administration grants.

D) To the extent not expended within 3 years after the date of any grant award under this paragraph, such grant shall be available for expenditure by the Secretary in any area under paragraph (2), (3), (4), or (5).

2) 20 percent of the amounts available in the fund in any fiscal year which are not allocated under paragraph (1) in that fiscal year (including that interest accruing as provided in section 401(e) and including funds available for reallocation pursuant to paragraph (1)(D)), shall be allocated to the Secretary only for the purpose of making the annual transfer to the Secretary of Agriculture under section 401(c)(2).

3) Amounts available in the fund which are not allocated to States and Indian tribes under paragraph (1) or allocated under paragraphs (2) and (5) are authorized to be expended by the Secretary for any of the following:

A) For the purpose of section 507(c), either directly or through grants to the States, subject to the limitation contained in section 401(c)(11).

B) For the purpose of section 410 (relating to emergencies).

C) For the purpose of meeting the objectives of the fund set forth in section 403(a) for eligible lands and waters pursuant to section 404 in States and on Indian lands

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where the State or Indian tribe does not have an approved abandoned mine reclamation program pursuant to section 405.

D) For the administration of this title by the Secretary.

4)(A) Amounts available in the fund which are not allocated under paragraphs (1), (2), and (5) or expended under paragraph (3) in any fiscal year are authorized to be expended by the Secretary under this paragraph for the reclamation or drainage abatement of lands and waters within unreclaimed sites which are mined for coal or which were affected by such mining, wastebanks, coal processing or other coal mining processes and left in an inadequate reclamation status.

B) Funds made available under this paragraph may be used for reclamation or drainage abatement at a site referred to in subparagraph (A) if the Secretary makes either of the following findings:

i) A finding that the surface coal mining operation occurred during the period beginning on August 4, 1977, and ending on or before the date on which the Secretary approved a State program pursuant to section 503 for a State in which the site is located, and that any funds for reclamation or abatement which are available pursuant to a bond or other form of financial guarantee or from any other source are not sufficient to provide for adequate reclamation or abatement at the site.

ii) A finding that the surface coal mining operation occurred during the period beginning on August 4, 1977, and ending on or before the date of enactment of this paragraph, and that the surety of such mining operator became insolvent during such period, and as of the date of enactment of this paragraph, funds immediately available from proceedings relating to such insolvency, or from any financial guarantee or other source are not sufficient to provide for adequate reclamation or abatement at the site.

C) In determining which sites to reclaim pursuant to this paragraph, the Secretary shall follow the priorities stated in paragraphs (1) and (2) of section 403(a). The Secretary shall ensure that priority is given to those sites which are in the immediate vicinity of a residential area or which have an adverse economic impact upon a local community.

D) Amounts collected from the assessment of civil penalties under section 518 are authorized to be appropriated to carry out this paragraph.

E) Any State may expend grants made available under paragraphs (1) and (5) for reclamation and abatement of any site referred to in subparagraph (A) if the State, with the concurrence of the Secretary, makes either of the findings referred to in clause (i) or

ii) of subparagraph (B) and if the State determines that the reclamation priority of the site is the same or more urgent than the reclamation priority for eligible lands and waters pursuant to section 404 under the priorities stated in paragraphs (1) and (2) of section 403(a).

F) For the purposes of the certification referred to in section 411(a), sites referred to in subparagraph (A) of this paragraph shall be considered as having the same priorities as those stated in section 403(a) for eligible lands and waters pursuant to section 404. All sites referred to in subparagraph (A) of this paragraph within any State shall be reclaimed prior to such State making the certification referred to in section 411(a).

5) The Secretary shall allocate 40 percent of the amount in the fund after making the allocation referred to in paragraph (1) for making additional annual grants to States and Indian tribes which are not certified under section 411(a) to supplement grants received by such States and Indian tribes pursuant to paragraph (1)(C) until the priorities stated in

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paragraphs (1) and (2) of section 403(a) have been achieved by such State or Indian tribe. The allocation of such funds for the purpose of making such expenditures shall be through a formula based on the amount of coal historically produced in the State or from the Indian lands concerned prior to August 3, 1977. Funds allocated or expended by the Secretary under paragraphs (2), (3), or (4) of this subsection for any State or Indian tribe shall not be deducted against any allocation of funds to the State or Indian tribe under paragraph (1) or under this paragraph.

6) Any State may receive and retain, without regard to the 3-year limitation referred to in paragraph (1)(D), up to 10 percent of the total of the grants made annually to such State under paragraphs (1) and (5) if such amounts are deposited into either – (A) a special trust fund established under State law pursuant to which such amounts (together with all interest earned on such amounts) are expended by the State solely to achieve the priorities stated in section 403(a) after September 30, 1995, or (B) an acid mine drainage abatement and treatment fund established under State law as provided in paragraph (7).

7)(A) Any State may establish under State law an acid mine drainage abatement and treatment fund from which amounts (together with all interest earned on such amounts) are expended by the State to implement, in consultation with the Soil Conservation Service, acid mine drainage abatement and treatment plans approved by the Secretary. Such plans shall provide for the comprehensive abatement of the causes and treatment of the effects of acid mine drainage within qualified hydrologic units affected by coal mining practices.

B) The plan shall include, but shall not be limited to, each of the following:

i) An identification of the qualified hydrologic unit.

ii) The extent to which acid mine drainage is affecting the water quality and biological resources within the hydrologic unit.

iii) An identification of the sources of acid mine drainage within the hydrologic unit.

iv) An identification of individual projects and the measures proposed to be undertaken to abate and treat the causes or effects of acid mine drainage within the hydrologic unit.

v) The cost of undertaking the proposed abatement and treatment measures.

vi) An identification of existing and proposed sources of funding for such measures.

vii) An analysis of the cost-effectiveness and environmental benefits of abatement and treatment measures.

C) The Secretary may approve any plan under this paragraph only after determining that such plan meets the requirements of this paragraph. In conducting an analysis of the items referred to in clauses (iv), (v), and (vii) the Director of the Office of Surface Mining shall obtain the comments of the Director of the United States Bureau of Mines.

In approving plans under this paragraph, the Secretary shall give a priority to those plans which will be implemented in coordination with measures undertaken by the Secretary of Agriculture under section 406.

D) For purposes of this paragraph, the term ‘qualified hydrologic unit’ means a hydrologic unit -

i) in which the water quality has been significantly affected by acid mine drainage from coal mining practices in a manner which adversely impacts biological resources; and

ii) which contains lands and waters which are -

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I) eligible pursuant to section 404 and include any of the priorities stated in paragraph (1), (2), or (3) of section 403(a); and

II) proposed to be the subject of the expenditures by the State (from amounts available from the forfeiture of bonds required under section 509 or from other State sources) to mitigate acid mine drainage.

8) Of the funds available for expenditure under this subsection in any fiscal year, the Secretary shall allocate annually not less than $2,000,000 for expenditure in each State, and for each Indian tribe, having an approved abandoned mine reclamation program pursuant to section 405 and eligible lands and waters pursuant to section 404 so long as an allocation of funds to such State or such tribe is necessary to achieve the priorities stated in paragraphs (1) and (2) of section 403(a).

h)(1) In the case of any fiscal year beginning on or after October 1, 1995, with respect to which fees are required to be paid under this section, the Secretary shall, as of the beginning of such fiscal year and before any allocation under subsection (g), make the transfer provided in paragraph (2).

2) The Secretary shall transfer from the fund to the United Mine Workers of America Combined Benefit Fund established under section 9702 of the Internal Revenue Code of 1986 for any fiscal year an amount equal to the sum of –

A) the amount of the interest which the Secretary estimates will be earned and paid to the Fund during the fiscal year, plus

B) the amount by which the amount described in subparagraph (A) is less than $70,000,000.

3)(A) The aggregate amount which may be transferred under paragraph (2) for any fiscal year shall not exceed the amount of expenditures which the trustees of the Combined Fund estimate will be debited against the unassigned beneficiaries premium account under section 9704(e) of the Internal Revenue Code of 1986 for the fiscal year of the Combined Fund in which the transfer is made.

B) The aggregate amount which may be transferred under paragraph (2)(B) for all fiscal years shall not exceed an amount equivalent to all interest earned and paid to the fund after September 30, 1992, and before October 1, 1995.

4) If, for any fiscal year, the amount transferred is more or less than the amount required to be transferred, the Secretary shall appropriately adjust the amount transferred for the next fiscal year.

OBJECTIVES OF FUND

SEC. 403.

a) Expenditure of moneys from the fund on lands and water eligible pursuant to section 404 for the purposes of this title, except as provided for under section 411, shall reflect the following priorities in the order stated:

1) the protection of public health, safety, general welfare, and property from extreme danger of adverse effects of coal mining practices;

2) the protection of public health, safety, and general welfare from adverse effects of coal mining practices;

3) the restoration of land and water resources and the environment previously degraded by adverse effects of coal mining practices including measures for the conservation and development of soil, water (excluding channelization), woodland, fish and wildlife, recreation resources, and agricultural productivity;

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4) the protection, repair, replacement, construction, or enhancement of public facilities such as utilities, roads, recreation, and conservation facilities adversely affected by coal mining practices; and

5) the development of publicly owned land adversely affected by coal mining practices including land acquired as provided in this title for recreation and historic purposes, conservation, and reclamation purposes and open space benefits.

b)(1) Any State or Indian tribe not certified under section 411(a) may expend up to 30 percent of the funds allocated to such State or Indian tribe in any year through the grants made available under paragraphs (1) and (5) of section 402(g) for the Sec. 403 purpose of protecting, repairing, replacing, constructing, or enhancing facilities relating to water supply, including water distribution facilities and treatment plants, to replace water supplies adversely affected by coal mining practices.

2) If the adverse effect on water supplies referred to in this subsection occurred both prior to and after August 3, 1977, or as the case may be, the dates (and under the criteria) set forth under section 402(g)(4)(B) section 404 shall not be construed to prohibit a State or Indian tribe referred to in paragraph (1) from using funds referred to in such paragraph for the purposes of this subsection if the State or Indian tribe determines that such adverse effects occurred predominantly prior to August 3, 1977, or as the case may be, the dates (and under the criteria) set forth under section 402(g)(4)(B).

c) For the purposes of assisting in the planning and evaluation of reclamation projects pursuant to section 405, and assisting in making the certification referred to in section 411(a), the Secretary shall maintain an inventory of eligible lands and waters pursuant to section 404 which meet the priorities stated in paragraphs (1) and (2) of subsection (a).

Under standardized procedures established by the Secretary, States and Indian tribes with approved abandoned mine reclamation programs pursuant to section 405 may offer amendments to update the inventory as it applies to eligible lands and waters under the jurisdiction of such States or tribes. The Secretary shall provide such States and tribes with the financial and technical assistance necessary for the purpose of making inventory amendments.

The Secretary shall compile and maintain an inventory for States and Indian lands in the case when a State or Indian tribe does not have an approved abandoned mine reclamation program pursuant to section 405. On a regular basis, but not less than annually, the projects completed under this title shall be so noted on the inventory under standardized procedures established by the Secretary.

Oklahoma Conservation Commission (OCC)

The Oklahoma Conservation Commission (OCC) is responsible for administering the reclamation of abandoned mine land (AML) in Oklahoma that threatens the health and safety of the public. Oklahoma’s AML Reclamation Program is in accordance with Title 45, Sections 740.1 through 740.7 of the Oklahoma Statutes.

The federal legislation that the OCC must adhere to in administering the AML Program is The Surface Mining Control and Reclamation Act of 1977 (PL 95-87).

Section 409 of PL 95-87 would allow the OCC to expend AML Trust Funds to reclaim noncoal mine hazards, such as lead/zinc, if they endanger the life and property of the public. The Governor must request the funs from the Secretary of the Interior.

SEC. 409 (a) The Congress declares that voids, and open and abandoned tunnels, shafts, and entryways resulting from any previous mining operation, constitute a hazard to the public health or safety and that surface impacts of any underground or surface mining operation may

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degrade the environment. The Secretary, at the request of the Governor of any State, or the governing body of an Indian tribe, is authorized to fill such voids, seal such abandoned tunnels, shafts, and entryways, and reclaim surface impacts of underground or surface mines which the Secretary determines could endanger life and property, constitute a hazard to the public health and safety, or degrade the environment. State regulatory authorities are authorized to carry out such work pursuant to an approved abandoned mine reclamation program.

b) Funds available for use in carrying out the purpose of this section shall be limited to those funds which must be allocated to the respective States or Indian tribes under the provisions of paragraphs (1) and (5) of section 402(g).

c)(1) The Secretary may make expenditures and carry out the purposes of this section in such States where requests are made by the Governor or governing body of an Indian tribe for those reclamation projects which meet the priorities stated in section 403(a)(1), except that for the purposes of this section the reference to coal in section 403(a)(1) shall not apply.

2) The provisions of section 404 shall apply to this section, with the exception that such mined lands need not have been mined for coal.

3) The Secretary shall not make any expenditures for the purposes of this section in those States which have made the certification referred to in section 411(a).

d) In those instances where mine waste piles are being reworked for conservation purposes, the incremental costs of disposing of the wastes from such operations by filling voids and sealing tunnels may be eligible for funding providing that the disposal of these wastes meets the purposes of this section.

e) The Secretary may acquire by purchase, donation, easement, or otherwise such interest in land as he determines necessary to carry out the provisions of this section.

Natural Resources Conservation Service (NRCS)

The U.S. Department of Agriculture’s Natural Resources Conservation Service (NRCS) is responsible for the reclamation of rural lands affected by past mining practices. Section 406 of The Surface Mining Control and Reclamation Act of 1977 (PL 95-87) established the procedures and funding mechanism.

SEC. 406.

a) In order to provide for the control and prevention of erosion and sediment damages from unreclaimed mined lands, and to promote the conservation and development of soil and water resources of unreclaimed mined lands and lands affected by mining, the Secretary of Agriculture is authorized to enter into agreements of not more than ten years with landowners (including owners of water rights), residents, and tenants, and individually or collectively, determined by him to have control for the period of the agreement of lands in question therein, providing for land stabilization, erosion, and sediment control, and reclamation through conservation treatment, including measures for the conservation and development of soil, water (excluding stream channelization), woodland, wildlife, and recreation resources, and agricultural productivity of such lands. Such agreements shall be made by the Secretary with the owners, including owners of water rights, residents, or tenants (collectively or individually) of the lands in question.

b) The landowner, including the owner of water rights, resident, or tenant shall furnish to the Secretary of Agriculture a conservation and development plan setting forth the proposed land uses and conservation treatment which shall be mutually agreed by the Secretary of Agriculture and the landowner, including owner of water rights, resident, or tenant to be needed on the lands

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for which the plan was prepared. In those instances where it is determined that the water rights or water supply of a tenant, landowner, including owner of water rights, resident, or tenant have been adversely affected by a surface or underground coal mine operation which has removed or disturbed a stratum so as to significantly affect the hydrologic balance, such plan may include proposed measures to enhance water quality or quantity by means of joint action with other affected landowners, including owner of water rights, residents, or tenants in consultation with appropriate State and Federal agencies.

c) Such plan shall be incorporated in an agreement under which the landowner, including owner of water rights, resident, or tenant shall agree with the Secretary of Agriculture to effect the land uses and conservation treatment provided for in such plan on the lands described in the agreement in accordance with the terms and conditions thereof.

d) In return for such agreement by the landowner, including owner of water rights, resident, or tenant, the Secretary of Agriculture is authorized to furnish financial and other assistance to such landowner, including owner of water rights, resident. or tenant, in such amounts and subject to such conditions as the Secretary of Agriculture determines are appropriate in the public interest for carrying out the land use and conservation treatment set forth in the agreement.

Grants made under this section, depending on the income-producing potential of the land after reclaiming, shall provide up to 80 per centum of the cost of carrying out such land uses and conservation treatment on not more than one hundred and twenty acres of land occupied by such owner, including water rights owners, residents, or tenant, or on not more than one hundred and twenty acres of land which has been purchased jointly by such landowners, including water rights owners, residents, or tenants, under an agreement for the enhancement of water quality or quantity or on land which has been acquired by an appropriate State or local agency for the purpose of implementing such agreement; except the Secretary may reduce the matching cost share where he determines that (1) the main benefits to be derived from the project are related to improving offsite water quality, offsite esthetic values, or other offsite benefits, and

2) the matching share requirement would place a burden on the landowner which would probably prevent him from participating in the program: Provided, however, That the Secretary of Agriculture may allow for land use and conservation treatment on such lands occupied by any such owner in excess of such one hundred and twenty acre limitation up to three hundred and twenty acres, but in such event the amount of the grant to such landowner to carry out such reclamation on such lands shall be reduced proportionately.

Notwithstanding any other provision of this section with regard to acreage limitations, the Secretary of Agriculture may carry out reclamation treatment projects to control erosion and improve water quality on all lands within a hydrologic unit, consisting of not more than 25,000 acres, if the Secretary determines that treatment of such lands as a hydrologic unit will achieve greater reduction in the adverse effects of past surface mining practices than would be achieved if reclamation was done on individual parcels of land.

e) The Secretary of Agriculture may terminate any agreement with a landowner including water rights owners, operator, or occupier by mutual agreement if the Secretary of Agriculture determines that such termination would be in the public interest, and may agree to such modification of agreements previously entered into hereunder as he deems desirable to carry out the purposes of this section or to facilitate the practical administration of the program authorized herein.

f) Notwithstanding any other provision of law, the Secretary of Agriculture, to the extent he deems it desirable to carry out the purposes of this section, may provide in any agreement hereinunder for (1) preservation for a period not to exceed the period covered by the agreement and an equal period thereafter of the cropland, crop acreage, and allotment history applicable to

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land covered by the agreement for the purpose of any Federal program under which such history is used as a basis for an allotment or other limitation on the production of such crop; or (2) surrender of any such history and allotments.

g) The Secretary of Agriculture shall be authorized to issue such rules and regulations as he determines are necessary to carry out the provisions of this section.

h) In carrying out the provisions of this section, the Secretary of Agriculture shall utilize the services of the Soil Conservation Service.

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BIBLIOGRAPHY

“AML Design Workshop – Dangerous Openings Student Notebook, ” U.S. Department of the Interior, Office of Surface Mining, Silverton, CO, August 1997.

A.V. I. Professional Corportation, “Final Report – AML Project 16B-III: Red Boy Mine Project, Fremont County,” Wyoming Department of Environmental Quality, Cheyenne, WY, January 1997.

Closure Methods for Inactive and Abandoned Mine Openings, U.S. Department of the Interior, Bureau of Mines Intermountain Field Operations Center, December 1995.

Dressel, W. M., and John S. Volosin, “Inverted Pyramid-Shaped Plugs for Closing Abandoned Mine Shafts – Galena, KS Demonstration Project,” Bureau of Mines Information Circular 8998, U.S. Department of the Interior, Washington, D.C., 1985.

Luza, Kenneth V., “Stability Problems Associated with Abandoned Underground Mines in the Picher Field, Northeastern Oklahoma,” Oklahoma Geological Survey Circular 88, University of Oklahoma Press, Norman, OK, 1986.

Rushworth, Peter, David L. Bucknam, and David H. Scriven, “Shaft Closures Using Polyurethane Foam,” Proceedings: Symposium of Evolution of Abandoned Mine Land Technologies, Riverton, WY, June 14-16, 1989.

Simpson, David G., and Michael Kuhns, “Reclamation of Abandoned Coal Mine Shafts Safety Considerations,” Proceedings: Symposium of Evolution of Abandoned Mine Land Technologies, Riverton, WY, June 14-16, 1989.

Spectrum Engineering, “Contract Close-out Report – AML Project 10-V: Sunrise West Shafts and Adits,” Wyoming Department of Environmental Quality, Cheyenne, WY, July 1997.

Spectrum Engineering, “West Butte HMO Project, DEQ - AMRB No. 94-009, Final Report,” Montana Department of Environmental Quality, Helena, MT, December 1995.

“Standard Specifications for Abandoned Mine Reclamation Construction,” Montana Department of State Lands, Abandoned Mine Reclamation Bureau, January 1991.

“Study of Stability Problems and Hazard Evaluation of the Kansas Portion of the Tri-State Mining Area,” U.S. Department of the Interior, Bureau of Mines, Washington D.C., January 1983.

Weidman, Samuel, C.F. Williams, and C.O. Anderson, “The Miami-Picher Zinc-Lead District,” Oklahoma Geological Survey Bulletin 56, 1932.

Click On The Tar Creek Superfund Juggler'To Go Back To The Top Of These Documents

Governor Frank Keating’s
Tar Creek Superfund Task Force
Water Quality Subcommittee
Task 1 Report
Surface & Ground Water Monitoring

July 26, 2000

Executive Summary

The Water Quality Subcommittee respectfully provides the following findings:

Tar Creek’s water quality does not meet the Habitat Limited Aquatic Community Use specified in Oklahoma’s 1998 Water Quality Standards.

Sources of acid mine water and metallic contaminants to Tar Creek include:

Discrete discharges of acid mine water

Leachate and run-off from chat piles

Stream sediments

Diffuse groundwater discharge primarily from the Boone Aquifer

The quality of acid mine seepage water has improved and although the quantity of acid mine water seeping or flowing from identifiable locations has remained unchanged, the concentrations of the contaminants has decreased.

The acidity of Tar Creek’s water has decreased, but data for metals and other water quality parameters indicate no improvement in water quality.

Metals in sediments within streams and lakes to which Tar Creek is tributary may constitute a current or future threat to water quality.

The Boone Aquifer is persuasively contaminated with acidic and metals contaminated water.

Contaminant water in the Boone Aquifer is a continuing threat to uncontaminated water in the Roubidoux Aquifer, a sole source of drinking water.

Drinking water supplies within the Tar Creek site have shown no test data that exceeds primary drinking water standards, but have displayed test data that exceeds secondary drinking water standards.

Based on existing information and studies, additional data is required to identify, design, and implement potential treatment systems and/or other remedial measures to address acid mine drainage, surface water sources, and groundwater sources of contamination in the Tar Creek Superfund area. The Water Quality Subcommittee recommends the following actions to be implemented and considered:

Tar Creek Water Quality Sampling - The DEQ will extend the OWRB and USGS historical studies.

The goal of this study will be to determine the current quality of the water and to provide additional data to help in the identification of trends.Quapaw Tribe of Oklahoma and USGS-These groups will be conducting monthly sampling of Spring River, Tar Creek, and Beaver Creek to determine the extent of possible contamination, through a cooperative agreement with EPA under the Clean Water Act Section 106.

DEQ and USGS Groundwater Investigation-These groups will participate in a joint investigation of the groundwater in the Boone Chert formation to identify the age of the water so that appropriate remediation activities can be developed.

OWRB BUMP Monitoring-The OWRB will monitor two locations on the Spring River and Neosho River previously sampled by the OSDH between 1979 and 1984. It will also assess water quality in Grand Lake to determine eutrophic state and trends, as well as document use support.

Current monitoring programs of Spring River and Grand Lake should be strengthened and coordinated to acquire the quality data with a minimum of time and manpower extended.

Oklahoma State Environmental Agencies should work cooperatively to develop a long-term water quality monitoring program to maximize limited monitoring resources.

We recommend that fish be collected and analyzed to determine if fish flesh are contaminated by heavy metals and document the potential impact to human health.

About three years of additional surface water monitoring data are required to identify, design, and implement potential treatment systems of the surface water in the Tar Creek area.

Introduction

The Tar Creek Superfund Site is located in the northeastern portion of Ottawa County, Oklahoma. The site is a former lead and zinc mining area and is the Oklahoma portion of the Tri-State mining district of northeastern Oklahoma, southeastern Kansas, and southwestern Missouri.

Mining began in Ottawa County in the early 1900’s and continued until the 1960’s. The Boone Formation was the source of the metal ore and is also an aquifer.

As such the mining operations pumped large volumes of water from the mine workings until mining ceased at which time the aquifer and hence the mines, began refilling. As water filled the mines, the native sulfide minerals, which had been oxidized by exposure to air, dissolved, creating acid mine water.

By 1979, water levels had increased to the point that the acid mine water began discharging at the surface from several locations, severely impacting Tar Creek.

In 1980 the Governor of the State of Oklahoma established the Tar Creek Task Force to investigate the discharges; the Oklahoma Water Resources Board (OWRB) was designated as the lead State Agency.

In 1981, the site was proposed to the National Priorities List (NPL). The Environmental Protection Agency (EPA) provided funding to the State of Oklahoma to conduct a Remedial Investigation and Feasibility Study (RI/FS) through a cooperative Assistance Agreement with the Oklahoma State Department of Health (OSDH), the lead State Superfund Agency. OSDH contracted with OWRB to perform the investigations.

The site was listed on the NPL in 1983, making the top ten sites in the nation.

EPA signed a Record of Decision (ROD) for the site on June 6, 1984

The ROD addressed two concerns :

1) the surface water degradation by the discharge of acid mine water; and

2) the threat of contamination of the Roubidoux Aquifer, the regional water supply, by downward migration of acid mine water from the overlying Boone Aquifer through abandoned wells connecting the two.

The remedy provided for the elimination or reduction of the discharge of acid mine water by preventing recharge of the Boone Aquifer. This would presumably lower the water levels as discharge continued, eventually eliminating the discharge. Recharge was to be prevented by utilizing diking and diversion structures (i.e., berms were constructed and plugs installed) to stop the surface water of Tar Creek from entering the two collapsed mine shafts in Kansas which were identified as the main inflow points.

A mine shaft was plugged in Oklahoma and a berm was constructed to divert Lytle Creek away from possible inflow points. Additionally, the remedy called for preventing the downward migration of acid mine water into the Roubidoux Aquifer by plugging 66 abandoned wells. During remediation, an additional 17 wells were identified and plugged, bringing the total to 83 wells. Construction activities as described in the ROD were concluded on December 22, 1986.

After Action monitoring was initiated in 1987 with monitoring of surface water sites, acid mine water discharges, and mine water levels to assess the effectiveness of the diking and diversion work.

To assess the effectiveness of the well plugging operations water samples from 21 deep Roubidoux wells located both inside and outside the mining area were collected and analyzed in 1991 and 1992. After Action Monitoring continues to assess if the Roubidoux Aquifer has been contaminated by the overlying acid mine water in the Boone with the following activities:

1) discrete sampling of five wells identified as being impacted by mine water,

2) with drilling and sampling of five new wells constructed using state of the art technology, and

3) through the review of water quality data obtained from public water supply system annual reports.

In April 1994 the EPA issued their first Five Year Review in which they reported:

1) the diversion and diking structures were operating as designed but acid mine water discharges continued unabated;

2) water level in the Boone is not statistically different indicating acid mine water discharging to Tar Creek has not been reduced;

3) the concentrations of metals in the acid mine water discharges appears to be reducing;

4) that stream water continues to be severely impacted; and since the downgraded water quality standards assigned to Tar Creek (in 1985 OWRB lowered the designated beneficial uses of Tar Creek to habitat limited aquatic community and secondary body contact recreation) are protective of human health, then no further remedial action is recommended for the surface water.

In summary, the OU1 remedy was mostly ineffective in mitigating the environmental degradation of the surface waters of Tar Creek drainage Basin. Additionally, the 1994 Five Year Review recommended an investigation should be conducted to evaluate the impact of mining wastes i.e., chat piles and floatation ponds, on human health and the environment and whether additional remedial action is warranted.

These types of wastes were not significantly investigated during the Tar Creek OU1 Remedial Investigation, as the focus at that time was on water quality.

Additional information on mining wastes on the land surface was provided by EPA Region 7 prior to the first Five Year Review of 1994. Investigations of the Cherokee County Superfund Site, which represents the Kansas portion of the Tri-State mining district, indicated that mining wastes in Kansas contain elevated concentrations of lead (as high as 13,000 ppm) and cadmium (as high a s 540 ppm).

Also, the Indian Health Service informed EPA that 34% of the 192 Native American children tested had blood lead levels in excess of the 10 ug/dL standard.

From August 1994 through July 1995, EPA conducted sampling of soils in High Access Areas (e.g., day care centers, school yards, and playgrounds) and residential properties to determine the nature and extent of contamination of the residential areas of the site.

This site assessment data was the basis for the Baseline Human Health Risk Assessment (BHHRA) issued in August 1996 and the Residential RI Report issued in January 1997.

The releases of heavy metal contamination associated with the mining wastes deposited on the surface of the ground (i.e., chat poles and floatation ponds) have been termed Operable Unit 2 (OU2).


A second ROD was signed on August 27, 1997, which addresses the residential areas of OU2

Remedial actions of residential areas of OU2 began in June 1996 as a removal action and continued in January 1998 as a remedial action.

Approximately 1,600 lead contaminated residential yards will be remediated. An additional 500 properties have been identified for remediation.

The BHHRA for residential areas identified lead in soil as the only site related chemical of concern and identified oral ingestion of lead contaminated soil as the only significant exposure pathway.

It predicted 21 % of the children in Picher would have elevated Blood lead levels (above 190 ug/dL) and set the clean up level for lead at 500 ppm. A blood lead survey conducted in Picher in 1995 by the OSDH found a percentage of children with elevated blood lead levels similar to that predicted by the BLHHRA.

Later surveys conducted in August 1996 and September 1996 found that 38.3 percent (31 of 81) of the children tested in Picher had blood lead concentrations exceeding 10 ug/dL, that 62.5 percent (10 of 16) of the children tested in Cardin had blood lead concentrations exceeding 10 ug/dL (10 of 16), and that 13.4 percent (nine of 67) of the children tested in Quapaw had blood lead levels which exceeded 10 ug/dL.

These are actual measured values of lead in children’s blood and not just predictions. These findings contrast sharply with the statewide average blood lead concentration in children of 2 percent reported by OSDH. Preliminary data being gathered by the University of Oklahoma Health Sciences Center show that in conjunction with EPA’s remediation efforts the percentage of children with elevated blood lead levels at the Site is beginning to decrease.

The EPA issued the second Five Year Review report in April 2000. It reported that although the environmental components of the Water Quality Standards are not being met (i.e., certain numerical and narrative water quality criteria including metals toxicity to aquatic life, pH, DO, and aesthetics are being violated), this does not pose a human health threat. The available data indicate:

1) levels of lead in sediments in Tar Creek,

2) metals and pH levels for dermal contact,

3) metals levels for ingestion of water while swimming, and

4) metals levels in fish flesh are generally below levels of concern for protection of human health. Since the criterion in the OU1 ROD for further remedial actions (i.e., human health risk not adequately mitigated) has not been triggered no further remedial action is recommended. The report did indicated additional monitoring may be needed in order to confirm that contamination levels have not worsened and stated that in the future EPA will review the need for updated monitoring of the contamination to Tar Creek for human health impacts.

In February 2000, a task force was created by Governor Frank Keating to investigate issues related to the Tar Creek Superfund Site in Ottawa County, Oklahoma. This report was prepared by the Water Quality Subcommittee and is being submitted to the Governor’s Task Force.

Active members of the Subcommittee include

Earl Hatley (Co-Chair, Quapaw Tribe of Oklahoma)

Glen Jones (Co-Chair, Oklahoma Department of Environmental Quality)

Bill Andrews (United States Geological Survey)

David Cates (Oklahoma Department of Environmental Quality)

Kent Curtis (Inter-Tribal Environmental Council)

J. Berton Fisher (Gardere and Wynne, L.L.P)

Meredith Garvin (Quapaw Tribe of Oklahoma)

Ron Jarman (Roberts/Schornick & Associates, Inc.)

Gene Lilly (US Army Corp of Engineers)

Bob Nairn (University of Oklahoma)

Sharon Robbins (Oklahoma Department of Environmental Quality)

John H. Roberts (U.S. Army Corps of Engineers)

and Derek Smithee (Oklahoma Water Resources Board)

The Task Force designated two tasks to the Water Quality Subcommittee.

The first duty assigned was compiling available data on water quality,

determining what additional data is needed,

and drafting a proposal outlining future necessary monitoring.

This subcommittee will also compile information on treatment alternatives to remove contaminants;

evaluate the feasibility of constructed wetlands,

diversion techniques,

methods of lowering the water table,

and other alternatives;

review the work conducted by the OWRB;

draft a proposal for each alternative that includes a scope of work,

timeline,

resource needs,

and potential sources of funding for the project;

estimate the degree of water quality improvement;

and measure resources for evaluating project effectiveness.

This report will address the concerns of the first task.

The focus will be on surface water and ground water, which are interrelated, but will be addressed separately.

Chronological Monitoring Information

Historical data from the United States Geological Survey (USGS), EPA, OWRB, OSDH, and the Department of Environmental Quality (DEQ) have been collected and compiled into an Access database.

This database contains raw data for the various water quality monitoring activities undertaken by these agencies in the Tar Creek Area. Copies of this data are provided on the computer disk attached at the end of the report.

Due to discrepancies in sampling sites and the sampled parameters, additional analyses could not be undertaken on the data as one large data set. The comments made about the historical data in this report are based on the available historical monitoring data and consideration of the conclusions reached by the original sampling agencies

Surface Water - Streams and Lakes

Based on a decrease in acidity of water, an evaluation of Tar Creek water quality data shows slow, incremental improvement in water quality within the time frame of the data. The other parameters showed no marked improvement.

Although this improvement has not resulted in Tar Creek meeting it's Habitat Limited Aquatic Community Use specified in Oklahoma's 1998 Water Quality Standards (WQS) (OWRB, OAC 785:45), it does indicate that improvements are possible.

Water quality information from the Spring River and Neosho River show elevated levels of metals, but data is insufficient to conduct rigorous statistical analyses. Spring River and parts of Grand Lake are currently listed on Oklahoma's 303(d) list as impaired by metals.

A 1992 study of the impacts of heavy metals on Grand Lake showed the aquatic community to be little affected by these heavy metals. However, metals sediment contamination on Grand Lake remains a concern because as Grand Lake continues to become more eutrophic (resulting in reducing conditions and lower pH), metals in the sediment could once again become biologically available.

Available monitoring data indicate contaminant concentration in Tar Creek’s water column due to acid mine drainage and tailing pile leachate may be decreasing (Appendix B, Tables 1-8).

However, the EPA notes in the Five-Year Review that water quality at downstream location sites 20 and 22 (see Appendix A, Figure A) indicates average constituent concentrations of many metals have increased. This may indicate an increased volume of discharge or dissolution of metals into the water column from stream bed sediments as mentioned above.

However, it is difficult to explain why some constituents are decreasing while others are increasing. Additional monitoring is needed to confidently establish the existence of any surface water trends.

Nonetheless, the Habitat Limited Aquatic Community beneficial use assigned to Tar Creek in Oklahoma’s WQS are not being met based upon currently available data.

In particular, the statewide numerical criteria for the toxic substances cadmium, lead, and zinc, and the pH standard applicable to all fishery classifications, including the habitat-limited classification for Tar Creek, are not being met.

The OWRB Beneficial Use Monitoring Program (BUMP) monitors sites across Oklahoma (two sampling locations are on the Spring and Neosho Rivers). The intent of BUMP is to determine if the beneficial uses established for waters at the sites are being met, or are threatened or impaired.

Data collected through BUMP and monitoring activities by other state agencies are then subjected to a standardized use support determination rule (called a Use Support Assessment Protocol, or USAP), to document use support.

Those waters with impaired beneficial uses are then listed on the Oklahoma 303(d) list of impaired waters and a Total Maximum Daily Load (TMDL) determination is initiated by DEQ. A TMDL quantifies the allowable contaminant load a water body can receive and still meet its beneficial uses.

The 1998 303(d) list specifies that Tar Creek, the Neosho River, Spring River and Grand Lake are all impaired by metals contamination. Monitoring is currently underway or proposed at all four water bodies by OWRB, Oklahoma Conservation Commission (OCC) and DEQ to confirm or refute these historical listings, but insufficient data is yet to be collected to satisfy the minimum data requirements for evaluation using the USAP.

Specific to Grand Lake, a cooperative study by Oklahoma State University and the OWRB found metals contamination of the sediments of Grand Lake - especially in the upper end near Twin Bridges.

Results of this study, however, indicated that these metals were strongly sorbed to the sediments, and generally unavailable to impact human health and aquatic life.

As Grand Lake continues to become more enriched through eutrophication, and strongly stratify during the summer, metals dissolution into the water column may begin to occur as previously stated.

No information could be found related to the impact of human health and the consumption of fish from within the basin. It is recognized that metals generally do not bioaccumulate metals in flesh as readily as other substances, particularly some pesticides; but a lack of monitoring data for zinc, lead and cadmium in fish flesh needs to be resolved (Appendix B, Tables 9-13).

While WQS do provide human health protection criteria to allow for consumption of fish flesh, no standardized program currently exists in streams to evaluate lead and zinc concentrations. The lake sampling program is also inadequate.

Acid Mine Discharges

The available monitoring data indicates that overall the contaminant concentrations in the acid mine discharges have decreased since completion of initial remedial action (see Appendix B, Tables 14-18).

Diversion and diking activity of the two major surface water inflow points was directed at reducing water inflow into the mines by approximately 75 percent, thereby eliminating or reducing acid mine discharges by a significant amount.

Available monitoring data summarized in the EPA’s 1994 Five-Year Review indicates that although the diversion and diking remedy was successful in preventing surface water inflow at these two locations, and although it has been successful in reducing the temporary rise in water in response to a given precipitation event, the remedy did not significantly reduce the surface discharges of acid mine water. (Note: The 2000 Five-Year Review is now available; however, the report is based on data obtained prior to the 1994 Review. No additional data was referenced in the 2000 Review.)

A 1983 study by the OWRB of the pollutants in the mine discharges indicated complex chemical responses occur during periods of inflow of oxygenated surface water. The negative correlation between iron and zinc concentrations in the major discharges supports the contention that continued acid mine water production may be occurring (OWRB, 1983).

The acid mine drainage has had a severe impact on Tar Creek, causing numerous exceedances of Oklahoma’s WQS. As a result, the beneficial uses assigned to Tar Creek, including aesthetics and habitat limited aquatic community are not being achieved.

Most of the biota in the creek have disappeared, and red stains caused by precipitation of ferric hydroxide dot the banks and bridge abutments. Lead, zinc, cadmium, and iron from the mines contaminate the sediments in Tar Creek. However, concentrations of these metals in both water and sediment near the mouth of Tar Creek are much less than further upstream.

The impact of Tar Creek on the aesthetics of Neosho River is evident from the red stains observed on cliffs and bridge abutments, although, except for zinc, no water quality criteria exceedances have been detected. Within the scope of currently available data, the sediments of the Neosho River do not appear to be impacted by the acid mine contamination. Within the scope of the data reviewed, no beneficial uses assigned to the Neosho River are impaired by the Tar Creek discharge.

Sediment

From the data it is observed that iron concentrations increased by an order of magnitude downstream from acid mine discharges (see Appendix B, Table 19). Above the discharges, the average iron concentration in the sediment is 4743 milligram/kilogram. Below the discharges, the average concentration is 67,742 milligram/kilogram.

However, the data is erratic, and it is difficult to draw any conclusions as to the effects of the remediation. The Health Affects Subcommittee of the initial Tar Creek Task Force concluded that sediments provide an effective long-term sink for metals and should effectively remove them from most biological processes.

However, this conclusion is not supported by decisions and actions taken by the Department of Interior and the National Oceanographic and Atmospheric Agency in Natural Resource Damage Act claims in the United States.

Tailings Piles

The analytical results of the water sample collected at two tailing piles indicate waters flowing at these sites have a low pH and contain high concentrations of various heavy metals (see Appendix B, Tables 20-22).

These metals are leached out as a result of dissolution of sphalerite and galena by sulfuric acid that is formed by oxidation of pyrite and/or marcasite present in tailings piles.

Of these metals, those that are less soluble will tend to precipitate after the pH is increased due to dilution. The highly soluble metals, including zinc and cadmium, will remain in solution allowing them to reach the receiving streams.

3) The majority of the tailing piles in the Picher Mining Field are situated within the Tar Creek drainage basin. The impact of acid mine drainage and tailings piles drainage has not been adequately independently assessed. The adverse effects of tailings piles runoff on Tar Creek and its tributaries may be masked by the discharges of highly contaminated acid mine water from the flooded underground mines.

One study (OWRB, 1983) measured the leachate rate at two large chat piles and estimated the contaminant loading to Tar Creek from all tailings piles in the basin (Appendix B, Tables 15-17).

This study concluded that the metals loading to Tar Creek from tailings piles is insignificant compared to the loading contributed by underground mine discharges of acid mine water. However, upon abatement of the mine discharges, mineralized tailings piles runoff to surface waters of the area could have a significant impact on aquatic organisms.

Ground Water

Hydrology and Geology

Detailed descriptions of the geology and hydrology of the area are provided in the following paragraphs. Topography of the area is generally a relatively flat prairie. Elevations range from approximately 775 to 900 feet above mean sea level. The region is drained by Tar Creek and Lytle Creek, which combine and flow into the Neosho River.

Bedrock in the Tar Creek area dips to the northwest at 15 to 20 feet per mile, with abrupt local variations caused by folding and faulting. In descending order the stratigraphy of the Tar Creek area and hydrogeologic significance (modified after McKnight and Fischer, 1970; and Reed, Schoff, and Branson, 1955) are as follows:

Pennsylvanian age Strata

Krebs Group: Consists of zero to 200 feet of gray to black fissile shale with some thin coal and sandstones and is present in the western and northwestern parts of Ottawa County but missing in the eastern portion of the county. Where present, the Krebbs Group forms a probable aquitard over the underlying Boone aquifer.

Mississippian age Strata

Boone Formation: Consists of 350 to 400 feet of bluish gray to light gray limestone and gray to white chert. The Boone Formation is also known as the Keokuk and Reed Springs Formations.

The Oklahoma State Department of Health (OSDH) has mapped the Keokuk and Reed Springs Formations as a principle bedrock ground water resource in northeastern Oklahoma (Johnson, 1983).

Ground water movement in the Boone Formation is primarily through fractures and solution cavities. The Boone Formation is also known as the Boone aquifer in northeastern Oklahoma and yields good quality water outside the mining area.

Devonian and Mississippian age Strata

Chattanooga Shale: consists of zero to 50 feet of black shale near the boundary between Devonian and Mississippian Periods. It is absent in most of the mining area. Where present, the Chattanooga Shale forms a probable aquitard restricting ground water movement between the overlying Boone aquifer and underlying Ordovician Strata. Deep wells in the area are usually uncased below the Chattanooga Shale.

Ordovician age Strata

Cotter Dolomite: consists of approximately 165 feet of dolomite and dolomitic limestones with oolitic, opalescent chert lenses and very fine grained sandy zones. The Cotter may contribute some water to deep wells, but its yield is unknown.

Jefferson City Dolomite: consists of 270 to 340 feet of dolomite with 10 to 50 percent brown chert. The rate at which groundwater can be produced from the Jefferson City Dolomite is unknown. Measured vertical permeability from core samples of the Cotter and Jefferson City Dolomites ranged between 3.1 x 10-7 to 9.6 x 10-9 cm/s (Encon, 1982).

A few "healed" fractures (containing secondary deposits of carbonate mineral) were visually detected in the cores. These facts suggest that downward migration of mine water from the Boone to the Roubidoux through the intervening strata would be extremely slow.

Roubidoux Formation: consists of 105 to 180 feet of cherty dolomite with two or three layers of sandstone which are 15 to 30 feet thick. The Roubidoux Formation is a major producer of groundwater in the area and yields up to 600 gallons per minute. Most of the water is produced from a few relatively thin, highly permeable sandstone zones.

The majority of the formation is lithologically very similar to the Cotter and Jefferson City Dolomites (having laboratory-measured porosity in the range of 0.025 to 0.09 and horizontal permeability from cores in the lower range mentioned in the paragraph above). The formation boundaries are very difficult to distinguish visually. The formation tops and bottoms may be determined using acid residual analyses where a grab sample of the formation is dissolved in acid, and the residual amount of silica defines the formation location.

The fact that the Boone Aquifer was contaminated by mining activities in the Tar Creek Superfund site has been documented by several episodes of sampling and analyses from mine shafts and cased holes to the Boone. The USGS conducted the first monitoring study in 1970’s before acid mine water discharges began (Playton et al, 1980).

The OWRB conducted a monitoring project in the 1980’s where mine shafts and cased wells were sampled (Appendix B, Tables 23-25). The USGS and the OWRB again sampled mine shafts during the late 1980’s

After the acid mine water began discharging the OWRB sampled the seeps for water quality and quantity of discharges. The water level in the Boone was also monitored on a daily basis during the 1970s and 1980s at the Blue Goose mine. These continuous water levels were exponentially correlated to total discharges measured only occasionally at the mine seeps (Parkhurst, 1985). The contaminant loading from the mine seeps was calculated as the average discharge times the average concentrations measurements, the number of discharge measurements being much greater than the concentration measurements

(Appendix B, Tables 26-29).

Over ten years during the 1980s, the mine discharges have contributed more than 10 tons of cadmium, 9,000 tons of iron, 22 tons of lead, 1,700,000 tons of sulfate, and 13,000 tons of zinc to Tar Creek (OWRB, April 1991).The monitored mine discharges have only contributed about fifteen percent of the contaminant loading to Tar Creek. Even though only about half the known discharges were monitored it is evident that there are other sources of contaminant metals loading to Tar Creek.

The OWRB (1991) concluded that either there are many unknown discharges of acid mine water, or much of the loading is due to surface sources (such as tailings pile leachate or resuspension). Since the metals loading from the mine tailings is relatively small (OWRB, 1983), the unknown loading sources may be discharges of acid mine water directly to groundwater feeding Tar Creek.

One major water quality concern is if the Roubidoux Aquifer, the primary source of drinking water in Ottawa County, has been contaminated by mining activities (Appendix B, Table 30-34).

Studies conducted by the USGS determined that sulfate is the dominant anion in the mine waters, and iron and zinc are dominant cations indicative of contamination. Relatively large concentrations of cadmium, fluoride, and lead have been analyzed in some mine waters. Water in the Boone Aquifer has a tendency to move downward into the Roubidoux Aquifer because of a higher hydraulic head.

The water can move through pores and fractures in rocks or by way of leaky well casings. About 100 wells were dug into the Roubidoux Aquifer to supply water for milling operations. Two abandoned wells have displayed the movement of water flow from the Boone Aquifer to the Roubidoux Aquifer at a rate of up to 2 gallons/minute. The EPA and DEQ continue to locate and plug any abandoned wells in the mining area that penetrate the Roubidoux Aquifer.

Public water supply wells in the cities of Commerce, Quapaw, and Picher have experienced problems due to mine water entering the wells through leaks in the casings or through the grout seals of the wells (Appendix D, Tar Creek PWS Summaries).

Between July 1981 and October 1982, two wells in Commerce had an increase in concentrations of sulfate, iron, zinc, and dissolved solids. The water quality returned to acceptable limits for public supply after repairing the well casings. A large iron concentration and low pH in a Quapaw well forced the abandonment and plugging of the water supply well in July 1981.

Past studies of the Roubidoux Aquifer in Picher between 1942 and 1951 have shown low concentrations of sulfate, usually only about 16 milligrams/liter. However, samples taken from 1981 to 1982 revealed sulfate concentrations ranging from 47 to 92 milligrams/liter. This dramatic rise suggests that the Roubidoux has been impacted by mine water. A slight increase in iron concentration was also discovered in the samples, but no other trace elements showed increased concentrations.

The water quality of the Roubidoux wells at Picher and Quapaw is of significantly poorer quality than at Miami, Commerce, and Cardin with respect to total hardness, iron, sulfate, and zinc (Appendix B, Tables 30-34). The mean concentration of iron exceeds the secondary drinking water standard at Picher and Quapaw.

Additional sampling was conducted on public water supply wells from the Roubidoux Aquifer located both inside and outside the mining area in 1991 and 1992. This Phase I After Action Monitoring showed that five wells in Picher, Quapaw, and Commerce fail secondary drinking water standards. However, these wells still meet primary drinking water standards including iron and sulfate.

Since the 1994 Review, discrete samples of Roubidoux water have been taken from the five public water supply wells that showed signs of being impacted by infiltration of acid mine water. Tentative (incomplete) analysis indicates that acid mine water is infiltrating through inadequate casings, and this infiltration is the source of the contamination. Water sampled from the new monitoring well in Picher, with state of the art casing, indicates the Roubidoux water quality is good, meeting both primary and secondary drinking water standards.

The most likely route by which the acid mine water could reach the Roubidoux Formation from the Boone Formation is by direct access through the active and abandoned deep wells. However, downward migration from the mine workings through the Chattanooga Shale(if present), Cotter Dolomite and Jefferson City Formations is possible, even though core testing showed intervening layers to have low permeability and that chemical reactions between the acid mine water and the aquifer material would tend to cause precipitation of the contaminant metals.

Decline of static water levels has been observed in the deep aquifers over the last 40 years. Water levels are expected to continue to decline as long as pumping continues. If the head differential is great enough, downward migration of contaminated water through fractures from the Boone into the Roubidoux is possible.

The EPA and the DEQ are currently conducting "After Action Monitoring" of the site to determine if the Remedial Actions conducted have been protective of human health, or if more corrective action is warranted. Future Superfund activities include continued ‘After Action Monitoring” and plugging of abandoned deep wells on the Roubidoux.

Under the completed and previously mentioned Phase I of the Tar Creek Ground Water Monitoring Project (TCGWMP) samples from eleven Roubidoux water supply wells inside the mining area and ten Roubidoux wells outside the mining area. Phase I wellhead sampling results prompted the DEQ to suspect that five of the wells inside the mining area are being impacted by acid mine water.

These wells produce water with elevated concentrations of iron, zinc, and sulfate over background levels in the Roubidoux aquifer outside the mining area (DEQ Technical Memorandum, 1993). The DEQ and EPA concluded that the five municipal wells were producing water exceeding secondary drinking water standards for iron, sulfate and zinc, and that these wells were impacted by acid mine water.

Phase II of the TCGWMP is being conducted to determine if the poor quality of drinking water is due to acid mine water infiltrating directly into the Roubidoux aquifer from the Boone formation, or if the acid mine water is getting into the groundwater through the deteriorated casings in the municipal wells. Inflatable packers were set in four of the municipal wells, and a PVC casing was installed in the fifth well. In addition, a monitor well was completed in the Roubidoux aquifer. Discrete water samples from the five municipal wells and the monitor well continue to be collected, analyzed and evaluated.

The purpose of Phase II

Supplemental of the TCGWMP is to install four additional monitor wells in the Roubidoux aquifer for the collection of ground water samples. To establish representative Roubidoux monitoring sites, the wells will be constructed like typical public water supply wells of the area and may be used by the cities (Picher, Cardin, Quapaw, or Commerce) for drinking water supply should the water quality of the wells prove to be acceptable.

Proposed and Recommended Monitoring Activity

There are five initial monitoring activities already scheduled to be conducted during the Summer of 2000 to provide additional information so that appropriate decisions can be made regarding the quality and treatment of the surface and ground water in the Tar Creek Area These monitoring activities will be done cooperatively with other state and federal partners to reduce duplication. It will also be submitted to the Water Quality Monitoring Council for review and comment. These are as follows:

Activity 1: Tar Creek Water Quality Sampling

The DEQ has initiated steps to provide some additional monitoring to give an updated picture of water quality in the Tar Creek Basin. The complete work plan is attached as Appendix D. Previous field surveys of sixteen sediment and water collection sites in the Grand River Drainage Basin (consisting of Tar Creek, Beaver Creek, Neosho River, and Spring River) have been conducted by the USGS of the U.S. Department of Interior between 1983 and 1985. The DEQ will extend the OWRB and USGS historical studies. The goal of this study will be to determine the current quality of the water and to provide additional data to help in the identification of trends.

The DEQ has identified three additional sites that will also be used for sample collection and analysis. Historical data concerning monitored parameters, physical conditions, and chemical conditions of surface waters in the basin from the OSDH, OWRB, and DEQ will be used as baseline information. The sample collection and analysis project will attempt to determine water quality changes since the USGS study, identify trends for the changes, and establish Tar Creek’s impact on water in Grand Lake.

A Total Maximum Daily Load (TMDL) will be established using the data from the sixteen OWRB sites and the 3 additional sites added by the DEQ. The TMDL concerns the content of acid mine discharge in a stream. The amount of point and nonpoint contaminant load that can exist in a stream safely without harming the designated use of the stream will be determined.

High flow and low flow events from three sites will be monitored over the course of one year. The flow rates will be incorporated into the TMDL model and may provide clues and evaluate the source of metals within the basin. A statistically valid sampling plan to accurately quantify water quality in the Tar Creek Basin will be developed using the Data Quality Objectives (DQO) process. The initial samples will be tested for iron, lead, zinc, cadmium, and other metals. Any metals that occur in high quantities will be sampled monthly for the course of one year.

Sediment and water samples will be collected from the Grand River Drainage Basin. It is believed that most metals in acid mine water will precipitate out of water and into Tar Creek sediments providing an effective long term sink for metals and effectively removing them from most biological processes.

Activity 2: Quapaw Tribe of Oklahoma & USGS Monitoring

The Quapaw Tribe of Oklahoma and USGS will be conducting monthly sampling of Spring River, Tar Creek, and Beaver Creek to determine the extent of possible contamination, through a cooperative agreement with EPA under the Clean Water Act Section 106.

The Quapaw Tribe of Oklahoma retains ownership of almost 80 percent of the land that is underlain with mines. The Tribe has discovered 79 point-source discharges of chemicals listed on the Toxic Release Inventory.

The Spring River flows through this land. The Water Quality Monitoring Program will sample at two stations along the Spring River. In addition, Tar Creek and Beaver Creek will be examined to determine the extent of possible impact.

The Tribal Ecologist, along with support from the EPA, will conduct monthly sampling for total dissolved solids, nitrates, phosphorus, nutrients, bacteria, metals, and the Biological Oxygen Demand. In accordance with the Quapaw Tribe contract, the USGS will aid in collecting and analyzing samples on a quarterly (sampling for bacteria, nutrients, and metals) and a semi-annual basis (total organics, perchlorate, and MTBE) so that it can be determined whether or not the Spring River, Tar Creek, and Beaver Creek are meeting the standards for criteria pollutants as established by the OWRB.

The Quapaw Water Quality Assurance Project Plan (QAPP) outlines specifically the work plan for this monitoring. Requests for a copy of the QAPP should be made to the Quapaw Tribe.

Activity 3: DEQ & USGS Groundwater Investigation

The groundwater in the Tar Creek area will be studied through a joint effort between the USGS and ODEQ (see Appendix D). This study will attempt to determine rates of movement of groundwater through the Picher Mining District by age dating the groundwater with chlorofluorocarbons (CFC’s).

The proposed project would provide State Officials with updated information about groundwater flow directions and rates of recharge in the Boone Chert of the Picher Mining District. These data will be useful in estimating areas of contribution to contaminated streams draining the District and identifying the age of the water so that appropriate remediation activities can be developed.

Activity 4: OWRB BUMP Monitoring

Through its Beneficial Use Monitoring Program (BUMP) the OWRB monitors two locations on the Spring River and Neosho River previously sampled by the Oklahoma State Department of Health between 1979 and 1984 as part of the historical Ambient Trend Monitoring Program. It also assesses water quality in Grand Lake to determine trophic state and water quality trends, as well as document beneficial use support.

The OWRB will continue to monitor surface water in the Tar Creek area to the extent that legislative financial support continues. Specific permanent monitoring stations on the Neosho River at Conners Bridge west of Commerce and the Spring River at Devils Prominade (East of Quapaw) will continue to be monitored monthly .

Grand Lake will be monitored every other year quarterly to document water quality trends, trophic status and beneficial use support. The OWRB also publishes an annual report documenting results of the BUMP.

Results of 1998 and 1999 BUMP sampling indicated that the overall water quality of the Neosho River at Conners Bridge and Spring River near Quapaw is relatively good. The following is a brief excerpt from the OWRB 1999 Draft BUMP Final Report to the Oklahoma Legislature outlining the results of water quality monitoring efforts at the two sites.

Neosho River near Connor Bridge Station AT185010 is a permanent ambient trend monitoring station located on the Neosho River in Oklahoma. Situated in the central portion of Ottawa County, the site was established south southeast of the city of Miami off of State Highway 137 on County Road E0145 at Connor Bridge.

The station is positioned near the terminal end of stream segment 121600040010 and is classified within the Grand Lake 8 digit HUC watershed (11070206). Water enters the stream system from several tributaries including Tar Creek and Hudson Creek, among others.

This station on the Neosho River has been active for all water quality variables since November of 1998. The following assessment of beneficial uses is based on the required 10 months of data collected from January through October of 1999. For purposes of reporting, this station is representative of the Neosho River from the confluence of an unnamed tributary above the city of Miami, Oklahoma (-94.9116, 36.8757) downstream to confluence of the Neosho River with Grand Lake (-94.7866, 36.7919).

As per Appendix A, Table 1 of OAC 785:45, this water quality management segment is assigned the following designated beneficial uses:

1) Public and Private Water Supply (PPWS),

2) Warm Water Aquatic Community—Fish and Wildlife Propagation (WWAC),

3) Agriculture—Class I Irrigation (AG), and

4) Primary Body Contact—Recreation (PBCR).

The PPWS beneficial use support could not be determined due to an insufficient number of fecal coliform and metals samples. The WWAC beneficial use is not supported. Of the ten (10) turbidity samples (Figure 112), three (3) samples (or 30%) exceeded the numerical criteria of 50.

Of the ten (10) pH samples (Figure 111), two (2) samples (or 20%) exceeded the screening level of 9.0 units. Dissolved oxygen (Figure 110) data collected during the same period met the criteria prescribed in the WWAC beneficial use.

There is insufficient data to assess the WWAC beneficial use for metals. The AG beneficial use is supported for total dissolved solids (TDS), chlorides, and sulfates (Figure 113). Although the TDS sample standard is exceeded 6 (six) times and the TDS yearly mean standard is not met by the geometric mean, these numbers are still below the prescribed minimum TDS value of 750 mg/L.

The PBCR beneficial use can not be determined due to an insufficient number of fecal coliform, E. coli and enterococci samples (Figure 114). This segment of the Neosho River is not nutrient-threatened.

Only two (2) of the ten (10) total phosphorus concentrations (or 20%) and none of the ten (10) nitrate/nitrite concentrations were above the prescribed thresholds of 0.36 mg/L and 5.00 mg/L, respectively (Figure 115). Furthermore, the station is light-limited due to a mean turbidity of 48 NTU.

Spring River near Quapaw

Station AT188000 is a permanent ambient trend monitoring station located on Spring River in Oklahoma. Situated in the north central portion of Ottawa County, the site was established east-southeast of the city of Quapaw off of State Highway 137 on County Road E0050.

The station is positioned near the midpoint of stream segment 121600070010 and is classified within the Spring River 8 digit HUC watershed (11070207).

Water enters the stream system from Kansas and from several tributaries including Five Mile Creek, Devil’s Hollow Creek, Warren Branch Creek, and Flint Branch Creek, among others.

This station on the Spring River has been active for all water quality variables since November of 1998. The following assessment of beneficial uses is based on the required 10 months of data collected from January through October of 1999. For purposes of reporting, this station is representative of the Spring River from the confluence of Bluff Creek (-94.7118, 36.9988) downstream to confluence of the Spring River with the Salt Fork of the Arkansas River (- 94.7342, 36.8322).

As per Appendix A, Table 1 of OAC 785:45, this water quality management segment is assigned the following designated beneficial uses:

1) Public and Private Water Supply (PPWS),

2) Cool Water Aquatic Community—Fish and Wildlife Propagation (CWAC),

3) Agriculture—Class I Irrigation (AG), and

4) Primary Body Contact—Recreation (PBCR).

The PPWS beneficial use support can not be determined due to an insufficient number of fecal coliform and metals samples. The CWAC beneficial use is not supported. Of the ten (10) turbidity samples (Figure 130), ten (10) samples (or 100%) exceeded the numerical criteria of 10.

Dissolved oxygen (Figure 128) and pH (Figure 129) data collected during the same period met the criteria prescribed in the CWAC beneficial use.

There is insufficient data to assess the CWAC beneficial use for metals. The AG beneficial use is supp